Method for the Preparation of Microcellular Polyurethane Elastomers
    3.
    发明申请
    Method for the Preparation of Microcellular Polyurethane Elastomers 有权
    微孔聚氨酯弹性体的制备方法

    公开(公告)号:US20140374976A1

    公开(公告)日:2014-12-25

    申请号:US14369011

    申请日:2012-12-27

    申请人: SKC Co., Ltd.

    摘要: This invention relates to a method of preparing a microcellular polyurethane elastomer by reacting naphthalene diisocyanate with a polyol to prepare a prepolymer containing an isocyanate (NCO) group, followed by mixing the prepared polyurethane prepolymer with a plasticizer, water, an emulsifier and the like, and then foaming the prepolymer blend to prepare a polyurethane elastomer, wherein the emulsifier is a mixture of (a) a compound selected from the group consisting of 2,4-toluene diisocyanate, 2,6-toluene diisocyanate, 2,4-diphenylmethane diisocyanate, 4,4′-diphenylmethane diisocyanate, hexamethylene diisocyanate, 1,4′-cyclohexane diisocyanate and mixtures thereof, and (b) a C2-10 hydrocarbon having a molecular weight of 500 or less with two to four hydroxyl groups, or mixtures thereof. The method of the invention can optimize the viscosity and properties of the prepolymer resulting from the reaction of naphthalene diisocyanate with a polyol, thus improving processability.

    摘要翻译: 本发明涉及一种通过使萘二异氰酸酯与多元醇反应制备含有异氰酸酯(NCO)基团的预聚物,然后将制备的聚氨酯预聚物与增塑剂,水,乳化剂等混合来制备微孔聚氨酯弹性体的方法, 然后使预聚物共混物发泡以制备聚氨酯弹性体,其中乳化剂是(a)选自2,4-甲苯二异氰酸酯,2,6-甲苯二异氰酸酯,2,4-二苯基甲烷二异氰酸酯,2,4-二苯基甲烷二异氰酸酯 ,4,4'-二苯基甲烷二异氰酸酯,六亚甲基二异氰酸酯,1,4'-环己烷二异氰酸酯及其混合物,和(b)分子量为500以下,具有2〜4个羟基的C2-10烃或其混合物 。 本发明的方法可以优化由萘二异氰酸酯与多元醇反应得到的预聚物的粘度和性能,从而提高加工性能。