公开(公告)号：US3658722A

公开(公告)日：1972-04-25

申请号：US3658722D

申请日：1969-06-27

Applicant: SOLVAY

Inventor： DELBOUILLE ANDRE ,  DERROITTE JEAN-LOUIS

IPC: C08F4/64 ,  C08F4/68 ,  C08F4/70 ,  C08F10/00 ,  C08F3/06

CPC classification number: C08F10/00 ,  C08F4/637 ,  C08F4/613 ,  C08F4/634

Abstract: HIGHLY ACTIVE CATALYSTS FOR THE POLYMERIZATION OF OLEFINS RESULT FROM THE COMBINATION OF AN ORGANOMETALLIC COMPOUND AND A COMPLEX OBTAINED BY REACTING A HALOGENATING AGENT AND A TRANSITION METAL COMPOUND SELECTED FROM THE HALIDES, OXYHALIDES, HALOALKOXIDES, OXYALKOXIDES AND ALKOXIDES OF THE METALS OF GROUPS IVB, VB AND VIB OF THE PERIODIC TABLE WITH A SOLID SUPPORT COMPRISED OF AN OXYGENATED COMPOUND OF A BIVALENT METAL WHICH IS SUBSTANTIALLY ANHYDROUS AND IS SUBSTANTIALLY FREE OF HYDROXYL GROUPS.

公开(公告)号：US3901863A

公开(公告)日：1975-08-26

申请号：US31274472

申请日：1972-12-06

Applicant: SOLVAY

Inventor： BERGER EUGENE ,  DERROITTE JEAN-LOUIS

IPC: C08F4/00 ,  C08F4/42 ,  C08F4/60 ,  C08F4/68 ,  C08F10/00 ,  C08F1/42

CPC classification number: C08F10/00 ,  C08F2410/03 ,  C08F2410/04 ,  C08F4/695 ,  C08F4/6555 ,  C08F4/6355 ,  C08F4/6385 ,  C08F4/70

Abstract: The present invention relates to the method of polymerizing olefinic monomers utilizing a solid catalyst composition comprising a solid catalytic complex and an activator, to the resultant high impact resistant polymers, to the method of making such catalytic complex, and to the catalytic complex; said catalytic complex comprising the reaction product of an organic oxygenated compound of a metal of groups Ia, IIa, IIb, IIIb, IVb, VIIa, and VIII of the Periodic Table, an organic oxygenated transition compound of a transition metal of groups IVa, Va, and VIa of the Periodic Table, and an aluminium halide.

公开(公告)号：US3883492A

公开(公告)日：1975-05-13

申请号：US79083269

申请日：1969-01-13

Applicant: SOLVAY

Inventor： DELBOUILLE ANDRE ,  DERROITTE JEAN-LOUIS

IPC: C08F4/00 ,  C08F4/20 ,  C08F4/42 ,  C08F4/60 ,  C08F4/62 ,  C08F4/68 ,  C08F10/00 ,  C08F1/56 ,  B01J11/84

CPC classification number: C08F10/00 ,  C08F4/613 ,  C08F4/634 ,  C08F4/637

Abstract: Polymerization and copolymerization of olefins are carried out in the presence of a catalyst obtained by reacting in the liquid phase a transition metal compound with a solid support comprised of a divalent metallic hydroxide and then activating the resulting complex with an organometallic compound.

Abstract translation: 烯烃的聚合和共聚在通过在液相中使过渡金属化合物与由二价金属氢氧化物组成的固体载体反应而获得的催化剂存在下进行，然后用有机金属化合物活化所得的络合物。

公开(公告)号：US3600367A

公开(公告)日：1971-08-17

申请号：US3600367D

申请日：1967-02-21

Applicant: SOLVAY

Inventor： DELBOUILLE ANDRE ,  DERROITTE JEAN-LOUIS

IPC: C08F291/00 ,  C08F3/02 ,  C08F15/04

CPC classification number: C08F291/00 ,  Y10S526/903 ,  Y10S526/904 ,  C08F210/00

Abstract: OLEFINS ARE POLYMERIZED AND COPOLYMERIZED IN THE PRESENCE OF A CATALYST CONSTITUTED OF THE REACTION PRODUCT OF ONE OR MORE TRANSITION METAL COMPOUNDS, AND A MACROMOLECULAR COMPOUND CONTAINING CARBON-CARBON DOUBLE BONDS IN ITS MOLECULE AND AN ACTIVATOR WHICH IS A METAL, A HYDRIDE OR AN ORGANO-METALLIC COMPOUND OF METALS OF GROUPS I TO III OF THE PERIODIC TABLE.