Abstract:
Bi-functional lubricant additives exhibiting dispersant and V.I. improving properties are obtained by the Mannich Condensation of an oxidized long-chain high molecular weight amorphous copolymer of essentially ethylene and propylene having a number average molecular weight of at least about 10,000 and at least 140 pendant methyl groups per 1,000 chain carbon atoms, with a formaldehyde yielding reactant and a primary or secondary amine or polyamine, said reactants being employed in the molar ratio of from about 1:2:2 to about 1:20:20, respectively.
Abstract:
Lubricant additives exhibiting dispersant and viscosity-index (V.I.) improving properties are obtained by the amination of oxidized high molecular weight amorphous copolymers of essentially ethylene and propylene having a number average molecular weight of from about 1,500 to about 200,000 or more, and at least about 150 pendant methyl groups per 1,000 chain carbon atoms, with a primary or secondary aliphatic amine or polyamine, said reactants being employed in the molar ratio of from about 1:2 to about 1:20, respectively; the aminated oxidized copolymers having a number average molecular weight in the range of from about 1,500 to about 20,000 exhibit excellent dispersancy properties, while those having a number average molecular weight of at least about 20,000 exhibit bi-functional dispersancy and V.I. improving properties.
Abstract:
ORGANOPHOSPORUS PRODUCTS OF THE REACTION OF ONE MOL OF DIETHYL PHOSPHITE AND ABOUT 0.5-2 MOLS OF AN OXIDIZED POLYMER OBTAINED BY TREATING A C2-4 POLYMER, HAVING A MOLECULAR WEIGHT OF ABOUT 250-5000, WITH AIR IN THE PRESENCE OF A CATALYTIC AMOUNT OF MANGANOUS CARBONATE AT ABOUT 130-180*C. FOR ABOUT 20-60 HOUTRS, ARE USEFUL AS ASHLESS WEAR INHIBITORS IN LUBRICATING OIL COMPOSITIONS.