Crosslinked polyquinoxaline polymers
    2.
    发明授权
    Crosslinked polyquinoxaline polymers 失效
    交联聚羟基喹啉聚合物

    公开(公告)号:US3904584A

    公开(公告)日:1975-09-09

    申请号:US41151173

    申请日:1973-10-31

    申请人: TRW INC

    CPC分类号: C08G73/122 C08G73/0694

    摘要: Crosslinked polymers are produced by the reaction of a linear polyquinoxaline containing a pendant furan group with an aromatic olefinic end-capped compound. The polyquinoxaline polymers have an alicyclic endooxy linkage repeated throughout the polymer at the cross-linking sites where the furan end-capped constituent undergoes a Diels-Alder reaction with the aromatic olefinic endcapped crosslinking agent. Subsequently, the alicyclic endooxy linkage may be aromatized by the application of heat to produce a high performance polymer which is suitable for use in severe environments at temperatures up to 400*C.

    Process for forming watersoluble polyamides
    3.
    发明授权
    Process for forming watersoluble polyamides 失效
    形成水溶性聚酰胺的方法

    公开(公告)号:US3558562A

    公开(公告)日:1971-01-26

    申请号:US3558562D

    申请日:1967-11-21

    申请人: GRACE W R & CO

    发明人: KRAMM DAVID E

    IPC分类号: C08G69/38 C08G9/04

    CPC分类号: C08G69/38

    摘要: A SYNTHETIC LINEAR WATER-SOLUBLE POLYAMIDE IS FORMED BY THE REACTION OF EQUIMOLAR PROPORTIONS OF IMINODIACETONITRILE ANDFORMALDEHYDE IN THE PRESENCE OF AN ACID AND WATER TO FORM A POLYAMIDE WHICH IS WATERSOLUBLE IN THE BASE FORM OR THE ACID SALT FORM. THE POLYAMIDE CAN BE REACTED WITH ACRYLONITRILE, ACRYLAMIDE OR ACRYLIC ACID TO PUT A SUBSTITUENT ON THE SECONDARY AMINE NITROGEN. THE NITRILE OR THE AMIDE MAY BE HYDROLYZED TO THE ACID WHICH READILY FORMS SALTS. ALL PRODUCTS ARE WATER SOLUBLE.

    Process for cross-linking polyacetal copolymers with hydrozine or dicarboxylic acid hydrazides and product produced thereby
    6.
    发明授权
    Process for cross-linking polyacetal copolymers with hydrozine or dicarboxylic acid hydrazides and product produced thereby 失效
    用氢氯化物或二羧酸水合物交联聚合物共聚物的方法和生产的产品

    公开(公告)号:US3563955A

    公开(公告)日:1971-02-16

    申请号:US3563955D

    申请日:1969-01-07

    申请人: HOECHST AG

    CPC分类号: C08G2/30 C08G2/18

    摘要: A PROCESS FOR CROSS-LINKING POLYOXYALKYLENE COPOLYMERS HAVING PENDANT FREE ALDEHYDE GROUPS SPACED ALONG THE POLYMER CHAIN THEREOF WITH HYDRAZINE OR A DICARBOXYLIC ACID HYDRIZIDE OF THE FORMULA

    H2N-NH-CO-R-CO-NH-NH2

    WHEREIN R STANDS FOR AN ALKYLENE RADICAL OF 1 TO 20 CARBON ATOMS, A PHENYLENE OR NAPHTHYLENE RADICAL WHICH IS SUBSTITUTED BY (A)X AND/OR (B)Y, A BEING AN ALKYL GROUP OF 1 TO 6 CARBON ATOMS, X BEING 0 TO 4, Y BEING 0 TO 4 AND X+Y BEING SMALLER THAN 5, OR IN WHICH R STANDS, FOR A PHENYLENE AND/OR NAPHTHYLENE RADICAL WHICH IS OR ARE INTERRUPTED BY A SATURATED AND/OR UNSATURATED HYDROCARBON RAIDCAL WITH 1 TO 10 CARBON ATOMS, OR IN WHICH R IS A CYCLOALIPHATIC RADICAL OF 4 TO 7 CARBON ATOMS WHICH IS SUBSTITUTED BY (D)A AND/OR (E)B AND/OR (F)C, D BEING AN ALKYL GROUP OF 1 TO 6 CARBON ATOMS, E BEING AN ALKOXY GROUP OF 1 TO 6 CARBON ATOMS AND F BEING A PHENYL RADICAL, AND A BEING 0 TO 5, B BEING 0 TO 5 AND C BEING 0 TO 2, OR IN WHICH R IS A POLYACRYLIC ACID RADICAL. REPRESENTATIVE DICARBOXYLIC ACID DIHYDRAZIDES ARE ADIPIC ACID BISHYDRAZIDE, SEBACIC ACID BISHYDRAZIDE, POLYACRYLIC ACID HYDRAZIDE AND TEREPHTHALIC ACID BISHYDRAZIDE. THE CROSS-LINKING AGENT MAY BE USED TO THE EXTENT OF 0.01 TO 50% BY WEIGHT, BASED ON THE WEIGHT OF THE UNCROSS-LIKED POLYMER. BY USING SUCH CROSS-LINKING AGENTS, GOOD CONTROL OF MOLECULAR WEIGHT AND CONSEQUENTLY OF THE FLOW PROPERTIES OF THE CROSS-LINKED COPOLYMER ARE OBTAINED. THE CROSSLINKED POLYMERS ARE ALSO CLAIMED.

    Fatty alkyl succinate ester and succinimide modified copolymers of
ethylene and an alpha olefin
    8.
    发明授权
    Fatty alkyl succinate ester and succinimide modified copolymers of ethylene and an alpha olefin 失效
    乙烯和α-烯烃的脂肪烷基琥珀酸酯和琥珀酰亚胺改性的共聚物

    公开(公告)号:US4171273A

    公开(公告)日:1979-10-16

    申请号:US777243

    申请日:1977-03-14

    摘要: Fatty alkyl succinate ester and succinimide modified copolymers of ethylene and an alpha-olefin, such as an ethylene-propylene copolymer, are useful as shear stable viscosity index (VI) improvers, dispersants and pour point depressants in lubricating oils. Especially useful is the succinate ester of mixtures of primary n-alkanols containing about 12 to about 18 carbon atoms and the N-(3-dimethylaminopropyl) succinimide derivative of the copolymer of ethylene and an alpha-olefin, such as an ethylene-propylene copolymer. This succinate ester-succinimide derivative is prepared by reacting the copolymer in an aromatic solvent with maleic anhydride in the presence of a free radical initiator, then esterifying the anhydride with a fatty alcohol or mixtures thereof in the presence of an acidic catalyst and finally converting any unreacted anhydride and half esters to the succinimide by reaction with a polyamine containing a primary amine. Additive concentrates containing 5 to 30 wt. % of the copolymer derivative in a solvent facilitate the introduction of the additive into a lubricating oil blend.

    摘要翻译: 乙烯和α-烯烃(例如乙烯 - 丙烯共聚物)的脂肪酸烷基酯琥珀酸酯和琥珀酰亚胺改性共聚物可用作润滑油中的剪切稳定粘度指数(VI)改进剂,分散剂和倾点下降剂。 特别有用的是含有约12至约18个碳原子的初级n-链烷醇与乙烯和α-烯烃共聚物的N-(3-二甲基氨基丙基)琥珀酰亚胺衍生物如乙烯 - 丙烯共聚物的混合物的琥珀酸酯 。 该琥珀酸酯 - 琥珀酰亚胺衍生物通过使芳香族溶剂中的共聚物与马来酸酐在自由基引发剂存在下反应,然后在酸性催化剂的存在下,使酸酐与脂肪醇或其混合物酯化,最后将任何 通过与含有伯胺的多胺反应,将未反应的酸酐和半酯与琥珀酰亚胺反应。 含有5〜30wt。 在溶剂中的共聚物衍生物的%有利于将添加剂引入到润滑油混合物中。