公开(公告)号：US20240209160A1

公开(公告)日：2024-06-27

申请号：US18582837

申请日：2024-02-21

Applicant: STEPAN COMPANY

Inventor： Timothy A. BOEBEL ,  Xue Min DONG ,  E. Carolina ROJAS ,  Renee LUKA ,  Gary LUEBKE ,  Paul W. KNOX

IPC: C08J3/09 ,  A01N25/04 ,  A01N25/14 ,  A01N37/34 ,  A01N43/50 ,  A01N43/653 ,  A01N43/70 ,  C08G65/26 ,  C08L71/02 ,  C09D5/02

CPC classification number: C08J3/095 ,  A01N25/04 ,  A01N25/14 ,  A01N37/34 ,  A01N43/50 ,  A01N43/653 ,  A01N43/70 ,  C08G65/2609 ,  C08G65/2612 ,  C08G65/2624 ,  C08G65/2627 ,  C08G65/263 ,  C08G65/2636 ,  C08L71/02 ,  C09D5/022 ,  C09D5/027 ,  C08J2371/02 ,  C08J2421/02 ,  C08L2201/54

Abstract: Copolymers comprising recurring units of a phenyl glycidyl ether and alkylene oxides are disclosed. Some of the copolymers comprise a di- or polyfunctional nucleophilic initiator and recurring units of the phenyl glycidyl ether and an alkylene oxide. The di- or polyfunctional nucleophilic initiator is an alcohol, phenol, amine, thiol, thiophenol, sulfinic acid, or deprotonated species thereof. Other copolymers comprise a monofunctional nucleophilic initiator selected from thiols, thiophenols, aralkylated phenols, sulfinic acids, secondary amines, C10-C20 terpene alcohols, and deprotonated species thereof. Pigments dispersions comprising the copolymers are also disclosed. The copolymers meet the growing needs of the industry with their ease of manufacture, diverse structures, and desirable performance attributes for dispersing a wide range of organic and inorganic pigments. Agricultural applications for the copolymers are also disclosed.

公开(公告)号：US20200347245A1

公开(公告)日：2020-11-05

申请号：US16929420

申请日：2020-07-15

Applicant: STEPAN COMPANY

Inventor： David R. ALLEN ,  Marcos ALONSO ,  Mary BEDDAOUI ,  Randal J. BERNHARDT ,  Aaron BROWN ,  Scott DILLAVOU ,  Xue Min DONG ,  Wilma GORMAN ,  John C. HUTCHISON ,  Gary LUEBKE ,  Renee LUKA ,  Franz LUXEM ,  Andrew D. MALEC ,  Ronald A. MASTERS ,  Dennis S. MURPHY ,  Nicholas PENDLETON ,  Irma RYKLIN ,  Patti SKELTON ,  Brian SOOK ,  Chris SPAULDING ,  Krista TURPIN ,  Gregory WALLACE ,  Michael WIESTER ,  Patrick Shane WOLFE

IPC: C09D7/45 ,  A01N25/30 ,  A61K8/46 ,  C11D1/14 ,  C11D1/29 ,  B01F17/00 ,  C04B38/10 ,  C07C29/147 ,  C07C41/06 ,  C07C303/14 ,  C07C303/32 ,  C07C309/08 ,  C07C309/10 ,  C11D1/37 ,  C11D1/66

Abstract: Sulfate and sulfonate derivatives of unsaturated fatty alcohols, processes for making them, and methods of using them are disclosed. In one aspect, a monounsaturated fatty alcohol composition is made by reducing a metathesis-derived monounsaturated alkyl ester. The fatty alcohol composition is then converted to a sulfate or sulfonate derivative by one or more of alkoxylation, sulfation, sulfonation, and sulfitation. Of particular interest are the sulfate and ether sulfate derivatives. Microscopy studies indicate that the unsaturated sodium sulfates in particular have a lamellar phase that should enable formulation at high actives levels. Sulfate compositions comprising 40 to 60 wt. % of a monounsaturated fatty primary alcohol sulfate and 40 to 60 wt. % of a secondary hydroxyalkyl primary alcohol sulfate are also disclosed. The derivatives and sulfate compositions are valuable for many end-use applications, including, for example, agricultural dispersants, water-soluble herbicides, anionic emulsifiers for agricultural use, hard surface cleaners, light-duty liquid detergents, personal cleansers, gas well foamers for oilfield applications, laundry detergents, enhanced oil recovery compositions, latex paints, and specialty foams.

公开(公告)号：US20200255593A1

公开(公告)日：2020-08-13

申请号：US16836676

申请日：2020-03-31

Applicant: STEPAN COMPANY

Inventor： Timothy A. BOEBEL ,  Xue Min DONG ,  E. Carolina ROJAS ,  Renee LUKA ,  Gary LUEBKE

IPC: C08G65/26 ,  C08K3/013 ,  C08K5/00 ,  C08J3/05 ,  C08C2/00

Abstract: Polymers useful in formulating dispersing agents for pigments are disclosed. One such polymer can be made from a glycidyl intermediate. A nucleophilic initiator can be reacted with epichlorohydrin to produce a glycidyl intermediate. This intermediate is reacted with an aralkylated phenol to give a hydroxy-functional hydrophobe. Alkoxylation of the hydrophobe gives the desired polymer. In an alternative, approach, the polymer is made by reacting the nucleophilic initiator with an aralkylated phenol glycidyl ether to give the hydroxy-functional hydrophobe, which is then alkoxylated. Pigments dispersions comprising the polymers are also disclosed. The polymers meet the growing needs of the industry with their ease of manufacture, diverse structures, and desirable performance attributes for dispersing a wide range of organic and inorganic pigments. Agricultural applications for the polymers are also disclosed.

公开(公告)号：US20200223988A1

公开(公告)日：2020-07-16

申请号：US16836544

申请日：2020-03-31

Applicant: STEPAN COMPANY

Inventor： Timothy A. BOEBEL ,  Xue Min DONG ,  E. Carolina ROJAS ,  Renee LUKA ,  Gary LUEBKE ,  Paul W. KNOX

IPC: C08J3/09 ,  A01N25/04 ,  A01N25/14 ,  A01N43/70 ,  A01N37/34 ,  A01N43/50 ,  A01N43/653 ,  C09D5/02 ,  C08L71/02 ,  C08G65/26

Abstract: Copolymers comprising recurring units of a phenyl glycidyl ether and alkylene oxides are disclosed. Some of the copolymers comprise a di- or polyfunctional nucleophilic initiator and recurring units of the phenyl glycidyl ether and an alkylene oxide. The di- or polyfunctional nucleophilic initiator is an alcohol, phenol, amine, thiol, thiophenol, sulfinic acid, or deprotonated species thereof. Other copolymers comprise a monofunctional nucleophilic initiator selected from thiols, thiophenols, aralkylated phenols, sulfinic acids, secondary amines, C10-C20 terpene alcohols, and deprotonated species thereof. Pigments dispersions comprising the copolymers are also disclosed. The copolymers meet the growing needs of the industry with their ease of manufacture, diverse structures, and desirable performance attributes for dispersing a wide range of organic and inorganic pigments. Agricultural applications for the copolymers are also disclosed.