公开(公告)号：US09593295B2

公开(公告)日：2017-03-14

申请号：US14813565

申请日：2015-07-30

Applicant: Henkel AG & Co. KGaA ,  Studiengesellschaft Kohle mbH

Inventor： Christian Kropf ,  Nicole Bode ,  Danuta Bedrunka ,  Roberto Rinaldi ,  Hebert Jesus Estevez Rivera

IPC: C11D1/24 ,  C11D1/29 ,  C11D1/37 ,  C11D1/72 ,  C11D1/831 ,  C07C309/42 ,  C11D1/22 ,  C11D1/83 ,  C11D1/14

CPC classification number: C11D1/22 ,  C07C309/42 ,  C11D1/143 ,  C11D1/24 ,  C11D1/29 ,  C11D1/37 ,  C11D1/72 ,  C11D1/83 ,  C11D1/831

Abstract: The invention relates to surfactants of the formula (I), in which R1 stands for —H or —CH3; R2, R3, R4, R5, R6 independently stand for —H, —CH3, —CH2CH3, —CH2CH2CH3, —CH(CH3)2, —CH2CH2CH2CH3, —CH2CH(CH3)2, —CH(CH3)CH2CH3, —C(CH3)3, —OH, —OCH3, —OCH2CH3, —OCH2CH2CH3, —OCH(CH3)2, a linear or branched alkyl group containing 8 to 20 C atoms, or —SO3−X+; X+ stands for a monovalent cation or the nth part of an n-valent cation; exactly one radical R2, R3, R4, R5, R6 stands for —SO3−X+; and exactly one radical R2, R3, R4, R5, R6 stands for a linear or branched alkyl radical containing 8 to 20 C atoms.

Abstract translation: 本发明涉及式（I）的表面活性剂，其中R1代表-H或-CH3; R2，R3，R4，R5，R6独立代表-H，-CH3，-CH2CH3，-CH2CH2CH3，-CH（CH3）2，-CH2CH2CH2CH3，-CH2CH（CH3）2，-CH（CH3）CH2CH3，-C （CH 3）3，-OH，-OCH 3，-OCH 2 CH 3，-OCH 2 CH 2 CH 3，-OCH（CH 3）2，含有8〜20个碳原子的直链或支链烷基，或-SO 3 -X + X +代表一价阳离子或n价阳离子的第n部分; 正好一个基团R 2，R 3，R 4，R 5，R 6代表-SO 3 -X +; 并且正好一个基团R 2，R 3，R 4，R 5，R 6代表含有8至20个C原子的直链或支链烷基。

公开(公告)号：US20150274618A1

公开(公告)日：2015-10-01

申请号：US14434416

申请日：2013-10-04

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： Ferdi Schüth ,  Roberto Rinaldi ,  Niklas Meine ,  Jakob Hilgert

IPC: C07C29/141

CPC classification number: C07C29/141 ,  C07C29/132 ,  C07C31/26 ,  C07D307/20 ,  C13K1/02

Abstract: The present invention relates to a method for obtaining a high yield of sugar alcohols containing five to six carbon atoms from cellulose-containing materials. In a first step the starting materials (for example microcrystalline cellulose, alpha-cellulose, wood and cellulose-containing residues, such as sugar cane bagasse or wood shavings) and an acid are brought into close contact with the substrates by a impregnation carried out in the liquid or gaseous phase. In addition, in a second step the starting materials impregnated with acid and preferably dried are brought into contact by the action of mechanical energy, such that the cellulose-containing materials are degraded into water-soluble products. Subsequently, in a third step, sugar alcohols having five to six carbon atoms are obtained in a high yield and in high selectivity from the water-soluble products in aqueous solution by hydrolytic hydrogenation by means of a metal-containing catalyst under hydrogen pressure.

Abstract translation: 本发明涉及从含纤维素材料获得含有5至6个碳原子的高产率糖醇的方法。 在第一步中，通过浸渍进行初始材料（例如微晶纤维素，α-纤维素，木材和含纤维素的残渣，例如甘蔗渣或刨花）和酸与基底紧密接触 液相或气相。 此外，在第二步骤中，用酸浸渍并优选干燥的起始材料通过机械能的作用进行接触，使得含纤维素材料降解成水溶性产物。 随后，在第三步骤中，通过在氢气压力下通过含金属催化剂的水解氢化，从水溶液中的水溶性产物以高产率和高选择性获得具有5至6个碳原子的糖醇。

公开(公告)号：US09758731B2

公开(公告)日：2017-09-12

申请号：US14651033

申请日：2013-12-10

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： Roberto Rinaldi ,  Xingyu Wang

IPC: C07C1/20 ,  C10G3/00 ,  C10G45/02 ,  C10G45/28 ,  C10G45/30 ,  C10G49/20

CPC classification number: C10G3/52 ,  C10G3/45 ,  C10G3/47 ,  C10G3/50 ,  C10G45/02 ,  C10G45/28 ,  C10G45/30 ,  C10G49/20 ,  C10G2300/42 ,  C10G2400/30 ,  Y02P30/20

Abstract: The present invention discloses a process for the conversion of phenolics into aromatic hydrocarbons. In more detail, the present invention refers to a process for the selective hydrodeoxygenation of phenolic feeds into aromatic hydrocarbons, such as benzene, toluene, alkylbenzenes and others. The selective catalytic hydrodeoxygenation is performed in absence of external supply of molecular hydrogen.

公开(公告)号：US09206098B2

公开(公告)日：2015-12-08

申请号：US14434416

申请日：2013-10-04

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： Ferdi Schüth ,  Roberto Rinaldi ,  Niklas Meine ,  Jakob Hilgert

IPC: C07C29/141 ,  C07C31/26

CPC classification number: C07C29/141 ,  C07C29/132 ,  C07C31/26 ,  C07D307/20 ,  C13K1/02

Abstract: The present invention relates to a method for obtaining a high yield of sugar alcohols containing five to six carbon atoms from cellulose-containing materials. In a first step the starting materials (for example microcrystalline cellulose, alpha-cellulose, wood and cellulose-containing residues, such as sugar cane bagasse or wood shavings) and an acid are brought into close contact with the substrates by a impregnation carried out in the liquid or gaseous phase. In addition, in a second step the starting materials impregnated with acid and preferably dried are brought into contact by the action of mechanical energy, such that the cellulose-containing materials are degraded into water-soluble products. Subsequently, in a third step, sugar alcohols having five to six carbon atoms are obtained in a high yield and in high selectivity from the water-soluble products in aqueous solution by hydrolytic hydrogenation by means of a metal-containing catalyst under hydrogen pressure.

Abstract translation: 本发明涉及从含纤维素材料获得含有5至6个碳原子的高产率糖醇的方法。 在第一步中，通过浸渍进行初始材料（例如微晶纤维素，α-纤维素，木材和含纤维素的残渣，例如甘蔗渣或刨花）和酸与基底紧密接触 液相或气相。 此外，在第二步骤中，用酸浸渍并优选干燥的起始材料通过机械能的作用进行接触，使得含纤维素材料降解成水溶性产物。 随后，在第三步骤中，通过在氢气压力下通过含金属催化剂的水解氢化，从水溶液中的水溶性产物以高产率和高选择性获得具有5至6个碳原子的糖醇。

公开(公告)号：US20150337237A1

公开(公告)日：2015-11-26

申请号：US14813565

申请日：2015-07-30

Applicant: Henkel AG & Co. KGaA ,  Studiengesellschaft Kohle mbH

Inventor： Christian Kropf ,  Nicole Bode ,  Danuta Bedrunka ,  Roberto Rinaldi ,  Hebert Jesus Estevez Rivera

IPC: C11D1/22 ,  C11D1/37 ,  C11D1/831 ,  C11D1/29 ,  C07C309/42 ,  C11D1/24

CPC classification number: C11D1/22 ,  C07C309/42 ,  C11D1/143 ,  C11D1/24 ,  C11D1/29 ,  C11D1/37 ,  C11D1/72 ,  C11D1/83 ,  C11D1/831

Abstract: The invention relates to surfactants of the formula (I), in which R1 stands for —H or —CH3; R2, R3, R4, R5, R6 independently stand for —H, —CH3, —CH2CH3, —CH2CH2CH3, —CH(CH3)2, —CH2CH2CH2CH3, —CH2CH(CH3)2, —CH(CH3)CH2CH3, —C(CH3)3, —OH, —OCH3, —OCH2CH3, —OCH2CH2CH3, —OCH(CH3)2, a linear or branched alkyl group containing 8 to 20 C atoms, or —SO3−X+; X+ stands for a monovalent cation or the nth part of an n-valent cation; exactly one radical R2, R3, R4, R5, R6 stands for —SO3−X+; and exactly one radical R2, R3, R4, R5, R6 stands for a linear or branched alkyl radical containing 8 to 20 C atoms.

Abstract translation: 本发明涉及式（I）的表面活性剂，其中R1代表-H或-CH3; R2，R3，R4，R5，R6独立代表-H，-CH3，-CH2CH3，-CH2CH2CH3，-CH（CH3）2，-CH2CH2CH2CH3，-CH2CH（CH3）2，-CH（CH3）CH2CH3，-C （CH 3）3，-OH，-OCH 3，-OCH 2 CH 3，-OCH 2 CH 2 CH 3，-OCH（CH 3）2，含有8〜20个碳原子的直链或支链烷基，或-SO 3 -X + X +代表一价阳离子或n价阳离子的第n部分; 正好一个基团R 2，R 3，R 4，R 5，R 6代表-SO 3 -X +; 并且正好一个基团R 2，R 3，R 4，R 5，R 6代表含有8至20个C原子的直链或支链烷基。

公开(公告)号：US20140364599A1

公开(公告)日：2014-12-11

申请号：US14366772

申请日：2012-12-18

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： Ferdi Schüth ,  Roberto Rinaldi ,  Niklas Meine

IPC: C07H3/06

CPC classification number: C07H3/06

Abstract: A method is disclosed for the acid-catalyzed oligomerization of monosaccharides and/or disaccharides in which monosaccharides or disaccharides are subjected to a mechanical treatment in the presence of an inorganic and/or organic acid. During said process, a catalytic conversion of the monosaccharides or disaccharides takes place.

Abstract translation: 公开了用于在无机和/或有机酸存在下对单糖或二糖进行机械处理的单糖和/或二糖的酸催化低聚的方法。 在所述方法中，发生单糖或二糖的催化转化。