TWO STAGE GAS-GAS MIXER
    2.
    发明申请

    公开(公告)号:US20200156025A1

    公开(公告)日:2020-05-21

    申请号:US16582129

    申请日:2019-09-25

    Abstract: A device for mixing two gas streams, the device includes: an inner pipe, wherein: the inner pipe is arranged substantially concentrically within an outer pipe and forms an annulus between an outer diameter of the inner pipe and an inner diameter of the outside pipe; the inner pipe is closed at a downstream end; and the inner pipe comprises a plurality of perforations; and the outer pipe, wherein: a downstream end of the outer pipe extends into a reactor; the outer pipe is closed at the downstream end; and the downstream end of the outer pipe comprises a plurality of perforations. The mixed gas stream can enter the reactor. The reactor can be an Oxidative Coupling of Methane (OCM) reactor.

    A Process for Oxidative Conversion of Methane to Ethylene

    公开(公告)号:US20190389788A1

    公开(公告)日:2019-12-26

    申请号:US16481790

    申请日:2018-01-29

    Abstract: A process for producing ethylene and syngas comprising reacting, via OCM, first reactant mixture (CH4&O2) in first reaction zone comprising OCM catalyst to produce first product mixture comprising ethylene, ethane, hydrogen, CO2, CO, and unreacted methane; introducing second reactant mixture comprising first product mixture to second reaction zone excluding catalyst to produce second product mixture comprising ethylene, ethane, hydrogen, CO, CO2, and unreacted methane, wherein a common reactor comprises both the first and second reaction zones, wherein ethane of second reactant mixture undergoes cracking to ethylene, wherein CO2 of second reactant mixture undergoes hydrogenation to CO, and wherein an amount of ethylene in the second product mixture is greater than in the first product mixture; recovering methane stream, ethane stream, CO2 stream, ethylene stream, and syngas stream (CO&H2) from the second product mixture; and recycling the ethane stream and the carbon dioxide stream to second reaction zone.

    Method for Producing Hydrocarbons by Oxidative Coupling of Methane with a Heavy Diluent
    8.
    发明申请
    Method for Producing Hydrocarbons by Oxidative Coupling of Methane with a Heavy Diluent 审中-公开
    通过甲烷与重稀释剂的氧化偶联生产碳氢化合物的方法

    公开(公告)号:US20170057889A1

    公开(公告)日:2017-03-02

    申请号:US15241244

    申请日:2016-08-19

    CPC classification number: C07C2/84 Y02P20/582 C07C11/04

    Abstract: A method for producing C2 hydrocarbons comprising (a) introducing a reactant mixture to a reactor comprising a catalyst, wherein the reactant mixture comprises CH4, O2 and a heavy diluent, and wherein the reactant mixture is characterized by a bulk CH4/O2 molar ratio; (b) allowing the reactant mixture to contact a surface of the catalyst and react via an oxidative coupling of CH4 (OCM) reaction to form a product mixture, wherein the reactant mixture is characterized by a local CH4/O2 molar ratio on the catalyst surface, wherein the local CH4/O2 molar ratio is greater than the bulk CH4/O2 molar ratio, wherein the product mixture comprises C2 hydrocarbons, and wherein a selectivity to C2 hydrocarbons is increased by at least about 1% when compared to a selectivity of an otherwise similar OCM reaction conducted in the absence of the heavy diluent; and (c) recovering the product mixture from the reactor.

    Abstract translation: 一种生产C 2烃的方法,包括(a)将反应物混合物引入到包含催化剂的反应器中,其中反应物混合物包含CH 4,O 2和重稀释剂,并且其中反应物混合物的特征在于体积CH 4 / O 2摩尔比; (b)允许反应物混合物与催化剂的表面接触并通过CH 4(OCM)反应的氧化偶合反应以形成产物混合物,其中反应混合物的特征在于催化剂表面上的局部CH 4 / O 2摩尔比 ,其中所述局部CH 4 / O 2摩尔比大于本体CH 4 / O 2摩尔比,其中所述产物混合物包含C 2烃,并且其中与C 2烃的选择性相比,对C 2烃的选择性增加至少约1% 否则在没有重稀释剂的情况下进行相似的OCM反应; 和(c)从反应器中回收产物混合物。

    OCM CATALYST COMPOSITION HAVING IMPROVED STABILITY AND CARBON EFFICIENCY

    公开(公告)号:US20230030055A1

    公开(公告)日:2023-02-02

    申请号:US17785216

    申请日:2020-11-10

    Abstract: The invention relates to a composition containing a catalyst having high catalytic stability for conducting oxidative coupling of methane (OCM) at high carbon efficiency, while improving both methane and oxygen conversion. Particularly, the inventive catalyst is a metal oxide supported catalyst, which contains an alkali metal promoter and a mixed metal oxide component having at least one alkali earth metal and at least one rare earth metal. The metal oxide support is selected in a manner, such that at least a portion of the metal oxide support is capable of reacting with at least a part or whole of the alkali metal promoter under conditions of calcination during catalyst preparation. The invention further provides a method for preparing such a metal oxide supported catalyst composition, using a calcination process. Additionally, the invention further describes a process for producing C2+ hydrocarbons, using such a catalyst composition.

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