公开(公告)号：US20130317165A1

公开(公告)日：2013-11-28

申请号：US13895556

申请日：2013-05-16

申请人： Sachiko MORIMOTO ,  Hirofumi YAMASHITA ,  Naoya YABUUCHI

发明人： Sachiko MORIMOTO ,  Hirofumi YAMASHITA ,  Naoya YABUUCHI

IPC分类号： C09D133/26

CPC分类号： C09D133/26 ,  C08F220/18 ,  C09D133/04 ,  C09D133/08 ,  C08L33/26 ,  C08F2220/1866 ,  C08F220/56 ,  C08F220/58 ,  C08F220/20 ,  C08F220/06

摘要： The object of the present disclosure is to provide a crosslinked resin fine particle which has a particle diameter small enough to be used suitably for the purpose of viscosity control and can be produced inexpensively. Crosslinked resin fine particles obtained by reacting a vinyl monomer composition comprising: 5 to 50% by weight of a (meth)acrylamide-based monomer (A), 5 to 50% by weight of a crosslinkable unsaturated monomer (B), and 10 to 90% by weight of a (meth)acrylate having an alkyl group containing 8 to 24 carbon atoms (C) in an organic solvent, and having a number average particle diameter of 10 to 250 nm.

摘要翻译： 本公开的目的是提供一种交联树脂微粒，其粒径足够小以适于用于粘度控制的目的，并且可以廉价地生产。 通过使包含5〜50重量％的（甲基）丙烯酰胺系单体（A）和5〜50重量％的交联性不饱和单体（B）的乙烯基单体组合物反应而得到的交联树脂微粒，10〜 90重量％的在有机溶剂中具有碳原子数为8〜24的烷基（C）的（甲基）丙烯酸酯，数均粒径为10〜250nm。

公开(公告)号：US20140187710A1

公开(公告)日：2014-07-03

申请号：US14141933

申请日：2013-12-27

申请人： Yumiko HAYASHI ,  Sachiko MORIMOTO ,  Manabu YAMAOKA ,  Naoya YABUUCHI

发明人： Yumiko HAYASHI ,  Sachiko MORIMOTO ,  Manabu YAMAOKA ,  Naoya YABUUCHI

IPC分类号： C09D143/02

CPC分类号： C09D133/066 ,  C08L31/00 ,  C08L31/02 ,  C08L31/06 ,  C08L33/062 ,  C08L33/064 ,  C08L33/066 ,  C08L33/14 ,  C08L2312/06

摘要： The object of the present disclosure is to provide a method for producing a crosslinked polymer by radical polymerization of a monomer composition, by which method a desired crosslinked polymer can be produced in a high solid content with good productivity (also at a low production cost), and a crosslinked polymer obtained by the production method and a coating composition containing the same. A method for producing a crosslinked polymer having a weight average molecular weight of 15000 to 200000, the method comprising step [I] of obtaining a crosslinked polymer (A) by conducting polymerization of a monomer composition comprising 2 to 30% by weight of a polyfunctional methacrylate having 2 to 4 functional groups (a) and 98 to 70% by weight of one or more polymerizable monomers selected from the group consisting of monofunctional (meth)acrylates, (meth)acrylic acid, and monofunctional vinyl aromatic compounds (b) in an organic solvent in the presence of a radical polymerization initiator in a temperature region where the radical polymerization initiator comes to have a half-life of 4 to 18 minutes.

摘要翻译： 本公开的目的是提供一种通过单体组合物的自由基聚合制备交联聚合物的方法，通过该方法，可以以高生产率（也以低生产成本）生产高固含量的所需交联聚合物， ，以及通过该制造方法得到的交联聚合物和含有该交联聚合物的涂料组合物。 一种重均分子量为15000〜200000的交联聚合物的制造方法，其特征在于，包括通过聚合含有2〜30重量％的多官能团的单体组合物来获得交联聚合物（A）的步骤[I] 具有2〜4个官能团（a）的甲基丙烯酸酯和98〜70重量％的选自单官能（甲基）丙烯酸酯，（甲基）丙烯酸和单官能乙烯基芳族化合物（b））中的一种或多种可聚合单体 在自由基聚合引发剂存在下，在自由基聚合引发剂的半衰期为4〜18分钟的温度范围内的有机溶剂。

公开(公告)号：US20110257273A1

公开(公告)日：2011-10-20

申请号：US13084127

申请日：2011-04-11

申请人： Naoya YABUUCHI ,  Hirofumi YAMASHITA ,  Koji MORITA ,  Yasunori MIWA

发明人： Naoya YABUUCHI ,  Hirofumi YAMASHITA ,  Koji MORITA ,  Yasunori MIWA

IPC分类号： A61K8/85 ,  C09D167/02 ,  C07C69/54 ,  C09D133/08 ,  C08G63/91 ,  C09D11/10 ,  C08G63/16 ,  C08G18/00

CPC分类号： C08G63/12 ,  C08G18/4063 ,  C08G18/4241 ,  C08G18/6212 ,  C08G18/6254 ,  C08G18/672 ,  C08G63/52 ,  C08L33/066 ,  C09D5/02 ,  C09D11/104 ,  C09D167/02 ,  C09D175/16 ,  C09J167/02 ,  C08L2666/04 ,  C08G18/42

摘要： A low-molecular-weight polyester resin which can elasticize a resin suitably and can be used for various purposes, various resins obtained by using the resin, and the purposes thereof. The polyester resin is obtained by polymerizing a monomer composition containing 10 to 90 weight % of a linear dicarboxylic acid and/or diol having at least 8 carbon atoms (I), 5 to 80 weight % of a branched dicarboxylic acid and/or diol having at least 4 carbon atoms (II-1) and/or 2 to 40 weight % of at least one polyfunctional monomer (II-2) selected from the group consisting of polyols, polycarboxylic acids and hydroxycarboxylic acids having 3 or more functional groups respectively and which has the number average molecular weight of 500 to 5000 and is amorphous.

摘要翻译： 可以适当地使树脂弹性化并可用于各种目的的低分子量聚酯树脂，通过使用树脂获得的各种树脂及其用途。 聚酯树脂通过聚合含有10至90重量％的具有至少8个碳原子的直链二羧酸和/或二醇（I），5至80重量％的支链二羧酸和/或二醇的单体组合物，其具有 至少4个碳原子（II-1）和/或2至40重量％的至少一种选自多元醇，多元羧酸和具有3个或更多个官能团的羟基羧酸的多官能单体（II-2）和 其数均分子量为500〜5000，为无定形。