摘要:
The carrier of the present invention includes at least 85 wt percent alpha alumina, at least 0.06 wt percent SiO2 and no more than 0.04 wt percent Na2O. The carrier has a water absorption no greater than 0.35 g/g and a ratio of water absorption (g/g) to surface area (m2/g) no greater than 0.50 g/m2. Another aspect of the invention is a catalyst for the epoxidation of olefins which comprises the above described carrier and silver dispersed thereon, where the carrier has a monomodal, bimodal or multimodal pore distribution and where the quantity of silver is between 5 and 50 wt %, relative to the weight of the catalyst. A reactor system for the epoxidation of olefins is also disclosed.
摘要翻译:本发明的载体包括至少85wt%的α氧化铝,至少0.06wt%的SiO 2和不超过0.04wt%的Na 2 O. 载体的吸水率不大于0.35g / g,吸水率(g / g)与表面积(m2 / g)不大于0.50g / m 2。 本发明的另一方面是用于烯烃环氧化的催化剂,其包含分散在其上的上述载体和银,其中载体具有单峰,双峰或多峰孔分布,并且其中银的量为5至50重量% 相对于催化剂的重量。 还公开了用于烯烃环氧化的反应器系统。
摘要:
A carrier having at least three lobes, a first end, a second end, a wall between the ends and a non-uniform radius of transition at the intersection of an end and the wall is disclosed. A catalyst comprising the carrier, silver and promoters deposited on the carrier and useful for the epoxidation of olefins is also disclosed. A method for making the carrier, a method for making the catalyst and a process for epoxidation of an olefin with the catalyst are also disclosed.
摘要:
A carrier having at least three lobes, a first end, a second end, a wall between the ends and a non-uniform radius of transition at the intersection of an end and the wall is disclosed. A catalyst comprising the carrier, silver and promoters deposited on the carrier and useful for the epoxidation of olefins is also disclosed. A method for making the carrier, a method for making the catalyst and a process for epoxidation of an olefin with the catalyst are also disclosed.
摘要:
The carrier of the present invention includes at least 85 wt percent alpha alumina, at least 0.06 wt percent SiO2 and no more than 0.04 wt percent Na2O. The carrier has a water absorption no greater than 0.35 g/g and a ratio of water absorption (g/g) to surface area (m2/g) no greater than 0.50 g/m2. Another aspect of the invention is a catalyst for the epoxidation of olefins which comprises the above described carrier and silver dispersed thereon, where the carrier has a monomodal, bimodal or multimodal pore distribution and where the quantity of silver is between 5 and 50 wt/%, relative to the weight of the catalyst. A reactor system for the epoxidation of olefins is also disclosed.
摘要翻译:本发明的载体包括至少85wt%的α氧化铝,至少0.06wt%的SiO 2和不超过0.04wt%的Na 2 O. 载体的吸水率不大于0.35g / g,吸水率(g / g)与表面积(m2 / g)不大于0.50g / m 2。 本发明的另一方面是用于环氧化烯烃的催化剂,其包含分散在其上的上述载体和银,其中载体具有单峰,双峰或多峰孔分布,并且其中银的量为5至50重量% ,相对于催化剂的重量。 还公开了用于烯烃环氧化的反应器系统。
摘要:
A carrier having at least three lobes, a first end, a second end, a wall between the ends and a non-uniform radius of transition at the intersection of an end and the wall is disclosed. A catalyst comprising the carrier, silver and promoters deposited on the carrier and useful for the epoxidation of olefins is also disclosed. A method for making the carrier, a method for making the catalyst and a process for epoxidation of an olefin with the catalyst are also disclosed.
摘要:
A carrier having at least three lobes, a first end, a second end, a wall between the ends and a non-uniform radius of transition at the intersection of an end and the wall is disclosed. A catalyst comprising the carrier, silver and promoters deposited on the carrier and useful for the epoxidation of olefins is also disclosed. A method for making the carrier, a method for making the catalyst and a process for epoxidation of an olefin with the catalyst are also disclosed.
摘要:
A carrier having at least three lobes, a first end, a second end, a wall between the ends and a non-uniform radius of transition at the intersection of an end and the wall is disclosed. A catalyst comprising the carrier, silver and promoters deposited on the carrier and useful for the epoxidation of olefins is also disclosed. A method for making the carrier, a method for making the catalyst and a process for epoxidation of an olefin with the catalyst are also disclosed.