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    Polycarbonate polyol compositions and methods
    1.
    发明授权
    Polycarbonate polyol compositions and methods 有权
    聚碳酸酯多元醇组合物和方法

    公开(公告)号：US08247520B2

    公开(公告)日：2012-08-21

    申请号：US12994544

    申请日：2009-09-08

    申请人： Scott D. Allen ,  Geoffrey W. Coates ,  Anna E. Cherian ,  Chris A. Simoneau ,  Alexei A. Gridnev ,  Jay J. Farmer

    发明人： Scott D. Allen ,  Geoffrey W. Coates ,  Anna E. Cherian ,  Chris A. Simoneau ,  Alexei A. Gridnev ,  Jay J. Farmer

    IPC分类号： C08G63/02 ,  C08G63/00

    CPC分类号： C08G64/34 ,  C08G18/44 ,  C08G64/0208

    摘要： In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having two or more sites that can initiate polymerization. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of —OH end groups and a high percentage of carbonate linkages. The compositions are further characterized in that they contain polymer chains having an embedded polyfunctional moiety linked to a plurality of individual polycarbonate chains.

    摘要翻译： 一方面，本公开内容涵盖用于CO 2和环氧化物共聚的聚合体系，其包括1）包含具有永久性配体组的金属配位化合物和至少一种作为聚合引发剂的配体的催化剂，和2）链转移剂 具有两个或更多个可引发聚合的位点。 在第二方面，本发明包括使用本发明聚合体系合成聚碳酸酯多元醇的方法。 在第三方面，本公开内容包括聚碳酸酯多元醇组合物，其特征在于聚合物链具有高百分比的-OH端基和高百分比的碳酸酯键。 组合物的特征还在于它们含有聚合物链，其具有与多个单独的聚碳酸酯链连接的嵌入的多官能部分。

    POLYCARBONATE POLYOL COMPOSITIONS AND METHODS
    2.
    发明申请
    POLYCARBONATE POLYOL COMPOSITIONS AND METHODS 有权
    聚碳酸酯多元醇组合物和方法

    公开(公告)号：US20110230580A1

    公开(公告)日：2011-09-22

    申请号：US12994544

    申请日：2009-09-08

    申请人： Scott D. Allen ,  Geoffrey W. Coates ,  Anna E. Cherian ,  Chris A. Simoneau ,  Alexei A. Gridnev ,  Jay J. Farmer

    发明人： Scott D. Allen ,  Geoffrey W. Coates ,  Anna E. Cherian ,  Chris A. Simoneau ,  Alexei A. Gridnev ,  Jay J. Farmer

    IPC分类号： C07C69/96 ,  C07D493/04 ,  C08G65/26 ,  C08G18/00 ,  C09D175/04 ,  B01J31/02

    CPC分类号： C08G64/34 ,  C08G18/44 ,  C08G64/0208

    摘要： In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having two or more sites that can initiate polymerization. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of —OH end groups and a high percentage of carbonate linkages. The compositions are further characterized in that they contain polymer chains having an embedded polyfunctional moiety linked to a plurality of individual polycarbonate chains.

    摘要翻译： 一方面，本公开内容涵盖用于CO 2和环氧化物共聚的聚合体系，其包括1）包含具有永久性配体组的金属配位化合物和至少一种作为聚合引发剂的配体的催化剂，和2）链转移剂 具有两个或更多个可引发聚合的位点。 在第二方面，本发明包括使用本发明聚合体系合成聚碳酸酯多元醇的方法。 在第三方面，本公开内容包括聚碳酸酯多元醇组合物，其特征在于聚合物链具有高百分比的-OH端基和高百分比的碳酸酯键。 组合物的特征还在于它们含有聚合物链，其具有与多个单独的聚碳酸酯链连接的嵌入的多官能部分。

    POLYCARBONATE POLYOL COMPOSITIONS AND METHODS
    4.
    发明申请
    POLYCARBONATE POLYOL COMPOSITIONS AND METHODS 有权
    聚碳酸酯多元醇组合物和方法

    公开(公告)号：US20130244864A1

    公开(公告)日：2013-09-19

    申请号：US13584989

    申请日：2012-08-14

    申请人： Scott D. Allen ,  Geoffrey W. Coates ,  Anna E. Cherian ,  Chris A. Simoneau ,  Alexei A. Gridnev ,  Jay J. Farmer

    发明人： Scott D. Allen ,  Geoffrey W. Coates ,  Anna E. Cherian ,  Chris A. Simoneau ,  Alexei A. Gridnev ,  Jay J. Farmer

    IPC分类号： C08G64/02

    CPC分类号： C08G64/34 ,  C08G18/44 ,  C08G64/0208

    摘要： In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having two or more sites that can initiate polymerization. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of —OH end groups and a high percentage of carbonate linkages. The compositions are further characterized in that they contain polymer chains having an embedded polyfunctional moiety linked to a plurality of individual polycarbonate chains.

    摘要翻译： 一方面，本公开内容涵盖用于CO 2和环氧化物共聚的聚合体系，其包括1）包含具有永久性配体组的金属配位化合物和至少一种作为聚合引发剂的配体的催化剂，和2）链转移剂 具有两个或更多个可引发聚合的位点。 在第二方面，本发明包括使用本发明聚合体系合成聚碳酸酯多元醇的方法。 在第三方面，本公开内容包括聚碳酸酯多元醇组合物，其特征在于聚合物链具有高百分比的-OH端基和高百分比的碳酸酯键。 组合物的特征还在于它们含有聚合物链，其具有与多个单独的聚碳酸酯链连接的嵌入的多官能部分。

    Polycarbonate polyol compositions and methods
    6.
    发明授权
    Polycarbonate polyol compositions and methods 有权
    聚碳酸酯多元醇组合物和方法

    公开(公告)号：US08470956B2

    公开(公告)日：2013-06-25

    申请号：US13584992

    申请日：2012-08-14

    申请人： Scott D. Allen ,  Geoffrey W. Coates ,  Anna E. Cherian ,  Chris A. Simoneau ,  Alexei A. Gridnev ,  Jay J. Farmer

    发明人： Scott D. Allen ,  Geoffrey W. Coates ,  Anna E. Cherian ,  Chris A. Simoneau ,  Alexei A. Gridnev ,  Jay J. Farmer

    IPC分类号： C08G64/00 ,  C08G63/02

    CPC分类号： C08G64/34 ,  C08G18/44 ,  C08G64/0208

    摘要： In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having two or more sites that can initiate polymerization. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of —OH end groups and a high percentage of carbonate linkages. The compositions are further characterized in that they contain polymer chains having an embedded polyfunctional moiety linked to a plurality of individual polycarbonate chains.

    摘要翻译： 一方面，本公开内容涵盖用于CO 2和环氧化物共聚的聚合体系，其包括1）包含具有永久性配体组的金属配位化合物和至少一种作为聚合引发剂的配体的催化剂，和2）链转移剂 具有两个或更多个可引发聚合的位点。 在第二方面，本发明包括使用本发明聚合体系合成聚碳酸酯多元醇的方法。 在第三方面，本公开内容包括聚碳酸酯多元醇组合物，其特征在于聚合物链具有高百分比的-OH端基和高百分比的碳酸酯键。 组合物的特征还在于它们含有聚合物链，其具有与多个单独的聚碳酸酯链连接的嵌入的多官能部分。

    Synthesis of terminally unsaturated oligomers
    8.
    发明授权
    Synthesis of terminally unsaturated oligomers 失效
    末端不饱和低聚物的合成

    公开(公告)号：US5587431A

    公开(公告)日：1996-12-24

    申请号：US426517

    申请日：1995-04-21

    申请人： Alexei A. Gridnev ,  Steven D. Ittel

    发明人： Alexei A. Gridnev ,  Steven D. Ittel

    IPC分类号： C08F6/00 ,  C08F2/38 ,  C08F4/80 ,  C08F12/12 ,  C08F20/10 ,  C08F20/42 ,  C08F297/00

    CPC分类号： C08F2/38 ,  Y10S525/91

    摘要： This invention relates to a method for preparing compositions comprising terminally unsaturated polymers of low molecular weight, referred to as oligomers or macromonomers. In particular, a first oligomer composition is obtained by free radical polymerization of a reaction mixture comprising monomers. Terminally unsaturated oligomers in the first oligomer composition, or a selected portion of the composition, are reinitiated into free radicals in order to continue their oligomerization to a desired endpoint. The process is useful for preparing an oligomer composition having a controlled degree of polymerization. The process is also useful for preparing block copolymers. Such oligomer compositions or block polymers are useful for preparing engineered or structured polymers used in making various end products, including plastics, coatings, films, and dispersants.

    摘要翻译： 本发明涉及一种制备包含低分子量末端不饱和聚合物（称为低聚物或大分子单体）的组合物的方法。 特别地，通过包含单体的反应混合物的自由基聚合获得第一低聚物组合物。 将第一低聚物组合物中的末端不饱和低聚物或组合物的选定部分重新转化为自由基，以便将其低聚物继续到所需的终点。 该方法可用于制备具有受控聚合度的低聚物组合物。 该方法也可用于制备嵌段共聚物。 这种低聚物组合物或嵌段聚合物可用于制备用于制备各种最终产品（包括塑料，涂料，膜和分散剂）的工程化或结构聚合物。

    Catalysts for catalytic chain transfer
    9.
    发明授权
    Catalysts for catalytic chain transfer 失效
    用于催化链转移的催化剂

    公开(公告)号：US08053541B2

    公开(公告)日：2011-11-08

    申请号：US12715483

    申请日：2010-03-02

    申请人： Gregory A. Nikiforov ,  Alexei A. Gridnev

    发明人： Gregory A. Nikiforov ,  Alexei A. Gridnev

    IPC分类号： C08F118/02 ,  B01J31/18

    CPC分类号： C07F15/065 ,  C07F5/022 ,  C08F212/08 ,  C08F220/18 ,  C08F220/26 ,  C08F220/32

    摘要： Cobaloxime derivatives and methods of producing cobaloxime derivatives are disclosed herein. Methods of producing decolorized homo- and co-polymers through polymerization of monomers in presence of the cobaloxime derivatives and decolorization of the produced polymer by exposing the polymer to a sorbent and, optionally, a solvent are also disclosed herein.

    摘要翻译： 钴芴衍生物和生产钴ime ime衍生物的方法在本文中公开。 本发明还公开了通过在钴ime衍生物存在下聚合单体并通过将聚合物暴露于吸附剂和任选的溶剂而使生成的聚合物脱色来生产脱色的均聚物和共聚物的方法。