Catalytic polymerization process
    5.
    发明授权
    Catalytic polymerization process 有权
    催化聚合工艺

    公开(公告)号:US06624261B1

    公开(公告)日:2003-09-23

    申请号:US09125467

    申请日:1998-08-19

    IPC分类号: C08F200

    摘要: This invention relates to a process for controlling the architecture of copolymers of at least two unsaturated monomers, made by free-radical polymerization in the presence of a cobalt-containing chain transfer agent, including the control of molecular weight, degree of branching and vinyl end group termination, by varying at least one of the variables of molar ratio of monomers, their relative chain transfer constants, polymerization temperature and degree of conversion and amount of cobalt chain transfer agent; and polymers made thereby.

    摘要翻译: 本发明涉及在含钴链转移剂存在下,通过自由基聚合制备的至少两种不饱和单体的共聚物结构的方法,包括分子量,支化度和乙烯基端基的控制 通过改变单体摩尔比的变量,它们的相对链转移常数,聚合温度和转化度和钴链转移剂量的至少一个变量来进行组终止; 和由此制成的聚合物。

    Initiation of polymerization by hydrogen atom donation
    10.
    发明授权
    Initiation of polymerization by hydrogen atom donation 失效
    通过氢原子引发聚合反应

    公开(公告)号:US07022792B2

    公开(公告)日:2006-04-04

    申请号:US10802024

    申请日:2004-03-16

    IPC分类号: C08F120/06

    摘要: This invention relates to the polymerization of vinylically-unsaturated monomers in the presence of a chain transfer catalysts where the polymerization process is initiated with hydrogen gas or a hydrogen atom donor rather than conventional free radical initiators. This invention further relates to an improved process for the polymerization of vinylically-unsaturated monomers in the presence of a chain transfer catalysts where the polymerization process is initiated with hydrogen gas.

    摘要翻译: 本发明涉及在链转移催化剂存在下乙烯基不饱和单体的聚合,其中聚合方法由氢气或氢原子给体而不是常规的自由基引发剂引发。 本发明还涉及一种在链转移催化剂存在下乙烯基不饱和单体聚合的改进方法,其中聚合过程由氢气引发。