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    Amido-organoborate initiator systems
    1.
    发明申请
    Amido-organoborate initiator systems 失效
    酰胺 - 有机硼酸引发剂体系

    公开(公告)号：US20070083051A1

    公开(公告)日：2007-04-12

    申请号：US11544521

    申请日：2006-10-06

    申请人： Shaoguang Feng ,  Gary Jialanella ,  Peter Nickias ,  Toni Ristoski

    发明人： Shaoguang Feng ,  Gary Jialanella ,  Peter Nickias ,  Toni Ristoski

    IPC分类号： C07F5/02

    CPC分类号： C08F220/18 ,  C07F5/02 ,  C08F4/52 ,  C09J4/00 ,  C09J4/06 ,  Y10T428/31504 ,  Y10T428/31855 ,  Y10T428/31909 ,  Y10T428/31913 ,  Y10T428/31928

    摘要： In one embodiment, the invention is a system for initiating free radical polymerization comprising: a) in one part, one or more amido-borate compounds containing one or more anionic amido-borate moieties comprising an organoborate wherein the boron atom is bonded to a nitrogen atom of ammonia or an organic compound containing one or more nitrogen atoms, such as a hydrocarbyl amine, a hydrocarbyl polyamine, or an aromatic heterocycle containing one or more nitrogen atoms, and a cationic counter ion and b) in a second part, a liberating compound which reacts with the nitrogen atom(s) bound to the boron atom upon contact with the amido-borate to form an organoborane radical. In another embodiment, the invention is a two part polymerizable composition comprising in one part, one or more amido-borate compounds and in the second part, a liberating compound which reacts with the nitrogen atoms bound to the boron atom upon contact with the amido-borate to form an organoborane radical and one or more compounds capable of free radical polymerization. The first part may further comprise one or more compounds capable of free radical polymerization. This facilitates formulating compositions that have commercially desirable volumetric ratios of the two parts.

    摘要翻译： 在一个实施方案中，本发明是用于引发自由基聚合的系统，其包括：a）一部分，一种或多种含有一种或多种含有机硼酸盐的阴离子酰氨基硼酸盐部分的酰氨基硼酸盐化合物，其中硼原子与氮键合 原子的氨或含有一个或多个氮原子的有机化合物，例如烃基胺，烃基多胺或含有一个或多个氮原子的芳族杂环，以及阳离子抗衡离子，和b）在第二部分中， 在与酰氨基硼酸盐接触时与与硼原子结合的氮原子反应形成有机硼烷基的化合物。 在另一个实施方案中，本发明是两部分可聚合组合物，其一部分包含一种或多种酰氨基硼酸盐化合物，而在第二部分中，与氨基 - 硼酸盐接触时与氮原子结合的氮原子反应的释放化合物， 硼酸盐以形成有机硼烷基和一种或多种能够进行自由基聚合的化合物。 第一部分还可以包含一种或多种能够进行自由基聚合的化合物。 这有助于制备具有商业上期望的两部分体积比的组合物。

    ACCELERATED ORGANOBORANE AMINE COMPLEX INITIATED POLYMERIZABLE COMPOSITIONS
    3.
    发明申请
    ACCELERATED ORGANOBORANE AMINE COMPLEX INITIATED POLYMERIZABLE COMPOSITIONS 有权
    加速的有机硼复合引发的可聚合组合物

    公开(公告)号：US20080045681A1

    公开(公告)日：2008-02-21

    申请号：US11861616

    申请日：2007-09-26

    申请人： Gary Jialanella ,  Dean Johnson

    发明人： Gary Jialanella ,  Dean Johnson

    IPC分类号： C08F4/52 ,  B05D3/00 ,  B32B7/12 ,  C09K3/00 ,  C07C50/18

    CPC分类号： C09J4/00 ,  C08F4/52 ,  C09J4/06

    摘要： The invention is a two part polymerizable composition comprising in one part an organoboron compound capable of forming free radical generating species amine complex and in the second part one or more compounds capable of free radical polymerization and a cure accelerator comprising a) at least one compound containing a quinone structure or b) at least one compound containing at least one aromatic ring and one or more, preferably two substituents on the aromatic ring selected from hydroxyl, ether and both, where there are two substituents they are located either ortho or para with respect to one another and a peroxide containing compound. The second part may further contain an agent capable of causing the organoboron compound to form free radical generating species upon contacting the two parts. The first part may further comprises one or more compounds capable of free radical polymerization. This facilitates formulating compositions that have commercially desirable volumetric ratios of the two parts. Adhesive compositions of the present formulation provide excellent adhesion to low surface energy substrates, such as plastics.

    摘要翻译： 本发明是一种两部分可聚合组合物，其一部分包含能够形成自由基产生物质胺络合物的有机硼化合物，在第二部分中包含一种或多种能够进行自由基聚合的化合物和固化促进剂，其包含：a）至少一种含 醌结构或b）至少一种含有至少一个芳香环和一个或多个，优选在选自羟基，醚和二者的芳环上的两个取代基的化合物，其中有两个取代基，它们位于邻位或对位，相对于 彼此和含过氧化物的化合物。 第二部分可以进一步含有能够使有机硼化合物在接触两部分时形成自由基产生物质的试剂。 第一部分还可以包含一种或多种能够进行自由基聚合的化合物。 这有助于制备具有商业上期望的两部分体积比的组合物。 本发明配方的粘合剂组合物对低表面能基材例如塑料提供优异的粘合性。

    ACCELERATED ORGANOBORANE AMINE COMPLEX INITIATED POLYMERIZABLE COMPOSITIONS
    4.
    发明申请
    ACCELERATED ORGANOBORANE AMINE COMPLEX INITIATED POLYMERIZABLE COMPOSITIONS 有权

    公开(公告)号：US20080045680A1

    公开(公告)日：2008-02-21

    申请号：US11861598

    申请日：2007-09-26

    申请人： Gary Jialanella ,  Dean Johnson

    发明人： Gary Jialanella ,  Dean Johnson

    IPC分类号： C08F4/52

    CPC分类号： C08F4/52 ,  C08L23/34 ,  C08L33/08 ,  C08L2205/02 ,  C08L2666/02 ,  C08L2666/04 ,  C09J133/08

    摘要： The invention is a two part polymerizable composition comprising in one part an organoboron compound capable of forming free radical generating species amine complex and in the second part one or more compounds capable of free radical polymerization and a cure accelerator comprising a) at least one compound containing a quinone structure or b) at least one compound containing at least one aromatic ring and one or more, preferably two substituents on the aromatic ring selected from hydroxyl, ether and both, where there are two substituents they are located either ortho or para with respect to one another and a peroxide containing compound. The second part may further contain an agent capable of causing the organoboron compound to form free radical generating species upon contacting the two parts. The first part may further comprises one or more compounds capable of free radical polymerization. This facilitates formulating compositions that have commercially desirable volumetric ratios of the two parts. Adhesive compositions of the present formulation provide excellent adhesion to low surface energy substrates, such as plastics.

    Accelerated organoborane amine complex initiated polymerizable compositions
    5.
    发明申请
    Accelerated organoborane amine complex initiated polymerizable compositions 失效
    加速的有机硼烷胺络合物引发的可聚合组合物

    公开(公告)号：US20050137370A1

    公开(公告)日：2005-06-23

    申请号：US11019056

    申请日：2004-12-21

    申请人： Gary Jialanella ,  Dean Johnson

    发明人： Gary Jialanella ,  Dean Johnson

    IPC分类号： B32B7/12 ,  C08F4/52 ,  C08F220/00 ,  C08L83/04 ,  C09J4/00 ,  C09J4/06

    CPC分类号： C09J4/00 ,  C08F4/52 ,  C09J4/06

    摘要： The invention is a two part polymerizable composition comprising in one part an organoboron compound capable of forming free radical generating species amine complex and in the second part one or more compounds capable of free radical polymerization and a cure accelerator comprising a) at least one compound containing a quinone structure or b) at least one compound containing at least one aromatic ring and one or more, preferably two substituents on the aromatic ring selected from hydroxyl, ether and both, where there are two substituents they are located either ortho or para with respect to one another and a peroxide containing compound. The second part may further contain an agent capable of causing the organoboron compound to form free radical generating species upon contacting the two parts. The first part may further comprises one or more compounds capable of free radical polymerization. This facilitates formulating compositions that have commercially desirable volumetric ratios of the two parts. Adhesive compositions of the present formulation provide excellent adhesion to low surface energy substrates, such as plastics.

    摘要翻译： 本发明是一种两部分可聚合组合物，其一部分包含能够形成自由基产生物质胺络合物的有机硼化合物，在第二部分中包含一种或多种能够进行自由基聚合的化合物和固化促进剂，其包含：a）至少一种含 醌结构或b）至少一种含有至少一个芳香环和一个或多个，优选在选自羟基，醚和二者的芳环上的两个取代基的化合物，其中有两个取代基，它们位于邻位或对位，相对于 彼此和含过氧化物的化合物。 第二部分可以进一步含有能够使有机硼化合物在接触两部分时形成自由基产生物质的试剂。 第一部分还可以包含一种或多种能够进行自由基聚合的化合物。 这有助于制备具有商业上期望的两部分体积比的组合物。 本发明配方的粘合剂组合物对低表面能基材例如塑料提供优异的粘合性。

    Adhesively bonded engine and transmission parts
    6.
    发明申请
    Adhesively bonded engine and transmission parts 失效
    粘合发动机和传动部件

    公开(公告)号：US20050061280A1

    公开(公告)日：2005-03-24

    申请号：US10943540

    申请日：2004-09-17

    申请人： Gary Jialanella ,  David Courter

    发明人： Gary Jialanella ,  David Courter

    IPC分类号： C08G59/66 ,  C08G75/00 ,  C08G75/02 ,  C09J181/02 ,  F01M9/10

    CPC分类号： C08G59/66 ,  C08G75/02 ,  C09J181/02

    摘要： In one embodiment the invention is a system and method for bonding parts to an engine or a transmission which comprises contacting with the part or the location of the engine or the transmission to which the part is to be attached an adhesive comprising a polythiol ether having two or more reactive groups capable of reacting with a curing agent and a curing agent for the polythiol ether and thereafter contacting the part with the engine or transmission such that the adhesive is disposed between them and curing the adhesive.

    摘要翻译： 在一个实施方案中，本发明是用于将部件粘合到发动机或变速器的系统和方法，其包括与发动机的部件或位置或所述部件将要附接的变速器接触，所述粘合剂包括具有两个 或更多的能够与固化剂反应的反应性基团和用于多硫醇醚的固化剂，然后使该部分与发动机或变速器接触，使得粘合剂设置在它们之间并固化粘合剂。