摘要:
A process comprising polymerizing at least one fluorinated monomer in an aqueous medium containing initiator and polymerization agent to form an aqueous dispersion of particles of fluoropolymer, wherein said polymerization agent is a compound of the formula (I): Rf—O—(CF2)n—COOX (I) wherein Rf is CF3CF2CF2—, n is an integer equal to 3, 5 or 7, and X is H, NH4, Li, Na or K.
摘要:
A compound of Formula (1) Rf—O—(CXX′)m—(CY2)nSO3M (1) wherein Rf is a C1 to C4 linear or branched perfluoroalkyl group, X and X′ are each independently H or F, provided that at least one of X or X′ is F, each Y is independently H or F, m is an integer from 1 to 4, n is an integer from 1 to 2, and M is H, NH4, Li, Na or K, provided that when CXX′ is CHF or CFH, then n is 2.
摘要:
A compound of Formula (1) Rf—O—(CXX′)m—(CY2)nSO3M (1) wherein Rf is a C1 to C4 linear or branched perfluoroalkyl group, X and X′ are each independently H or F, provided that at least one of X or X′ is F, each Y is independently H or F, m is an integer from 1 to 4, n is an integer from 1 to 2, and M is H, NH4, Li, Na or K, provided that when CXX′ is CHF or CFH, then n is 2.
摘要:
A low-wear fluoropolymer composite body comprises at least one fluoropolymer and additive particles dispersed therein. Also provided is a process for the fabrication of such a fluoropolymer composite body. The composite body exhibits a low wear rate for sliding motion against a hard counterface, and may be formulated with either melt-processible or non-melt-processible fluoropolymers.
摘要:
This invention relates to compounds useful as ionic liquids that are based on an N-substituted pyrrolidinone and incorporate a pendant ammonium cation that is spaced from the pyrrolidone ring by a variable length linker; and to methods of carbon dioxide removal in which they may be used.
摘要:
The present invention relates to compositions of matter that are ionic liquids, the compositions comprising any of eleven cations combined with any of three fluorinated sulfonated anions. Compositions of the invention should be useful as solvents and, perhaps, as catalysts for many reactions, including aromatic electrophilic substitution, nitration, acylation, esterification, etherification, oligomerization, transesterification, isomerization and hydration.
摘要:
The present invention relates to compositions of matter that are ionic liquids, the compositions comprising any of eleven cations combined with any of three fluorinated sulfonated anions. Compositions of the invention should be useful as solvents and, perhaps, as catalysts for many reactions, including aromatic electrophilic substitution, nitration, acylation, esterification, etherification, oligomerization, transesterification, isomerization and hydration.
摘要:
A process for manufacture of hydrofluoroalkanesulfonic acid with at least one hydrogen bonded to the carbon atom adjacent to the carbon atom bonded to the sulfonic acid group comprising: contacting a fluoroolefin with sulfite in an aqueous solution adjusted to about pH 4 to pH 12; removing water from the solution to form a solid; directly treating the solid with oleum; and distilling the hydrofluoroalkanesulfonic acid therefrom. Also a process for manufacture of potassium hydrofluoroalkanesulfonate in high purity is described.
摘要:
Compositions of matter useful as ionic liquids of the formula Z+A−, wherein Z+ is a cation selected from the group consisting of pyridinium, pyridazinium, pyrimidinium, pyrazinium, imidazolium, pyrazolium, thiazolium, oxazolium, triazolium, and phosphonium, ammonium cations with specified substituents, and A− is selected from the group consisting of the following three anions wherein R11, R12 and R13 are as specified. R11—CHF—CF2—SO3− Formula I R12—CF2—CF2—SO3− Formula II (R13—CHF—CF2—SO2)2N− Formula III.
摘要:
The invention provides a process for the preparation of fluorinated alkanesulfonic acid anhydrides by contacting alkanesulfonic acids with phosphorus pentoxide, the phosphorus pentoxide being provided as a dispersion in an inert oil. The invention also provides novel fluorinated alkanesulfonic acid anhydrides including 2-hydrotetrafluoroethanesulfonic acid anhydride.