摘要:
The present invention relates to compositions of matter that are ionic liquids, the compositions comprising any of eleven cations combined with any of three fluorinated sulfonated anions. Compositions of the invention should be useful as solvents and, perhaps, as catalysts for many reactions, including aromatic electrophilic substitution, nitration, acylation, esterification, etherification, oligomerization, transesterification, isomerization and hydration.
摘要:
The present invention relates to compositions of matter that are ionic liquids, the compositions comprising any of eleven cations combined with any of three fluorinated sulfonated anions. Compositions of the invention should be useful as solvents and, perhaps, as catalysts for many reactions, including aromatic electrophilic substitution, nitration, acylation, esterification, etherification, oligomerization, transesterification, isomerization and hydration.
摘要:
The present invention relates to the synthesis of alkylated aromatic compounds. Alkylated aromatic compounds are synthesized by reacting an aromatic compound with a monoolefin in the presence of a porous microcomposite comprising at least one fluorinated sulfonic acid on silica.
摘要:
The present invention relates to compositions of matter that are ionic liquids, the compositions comprising any of eleven cations combined with any of three fluorinated sulfonated anions. Compositions of the invention should be useful as solvents and, perhaps, as catalysts for many reactions, including aromatic electrophilic substitution, nitration, acylation, esterification, etherification, oligomerization, transesterification, isomerization and hydration.
摘要:
The present invention relates to compositions of matter that are ionic liquids, the compositions comprising any of eleven cations combined with any of three fluorinated sulfonated anions. Compositions of the invention should be useful as solvents and, perhaps, as catalysts for many reactions, including aromatic electrophilic substitution, nitration, acylation, esterification, etherification, oligomerization, transesterification, isomerization and hydration.
摘要:
Compositions of matter useful as ionic liquids of the formula Z+A−, wherein Z+ is a cation selected from the group consisting of pyridinium, pyridazinium, pyrimidinium, pyrazinium, imidazolium, pyrazolium, thiazolium, oxazolium, triazolium, and phosphonium, ammonium cations with specified substituents, and A− is selected from the group consisting of the following three anions wherein R11, R12 and R13 are as specified. R11—CHF—CF2—SO3− Formula I R12—CF2—CF2—SO3− Formula II (R13—CHF—CF2—SO2)2N− Formula III.
摘要:
This invention relates to porous microcomposites comprising fluorinated sulfonic acid and a network of silica, wherein the fluorinated sulfonic acid is selected from the group consisting of 1,1,2,2-tetrafluoroethanesulfonic acid, 1,1,2-trifluoro-2-(perfluoroethoxy)ethanesulfonic acid, 1,1,2-trifluoro-2-(trifluoromethoxy)ethanesulfonic acid, 1,1,2-trifluoro-2-(perfluoropropoxy)ethanesulfonic acid; 1,1,2,3,3,3-hexafluoropropanesulfonic acid; and 2-chloro-1,1,2-trifluoroethanesulfonic acid. The porous microcomposites are useful as catalysts.
摘要:
The present invention relates to compositions of matter that are ionic liquids, the compositions comprising any of eleven cations combined with any of three fluorinated sulfonated anions. Compositions of the invention should be useful as solvents and, perhaps, as catalysts for many reactions, including aromatic electrophilic substitution, nitration, acylation, esterification, etherification, oligomerization, transesterification, isomerization and hydration.
摘要:
The present invention relates to compositions of matter that are ionic liquids, the compositions comprising any of eleven cations combined with any of three fluorinated sulfonated anions. Compositions of the invention should be useful as solvents and, perhaps, as catalysts for many reactions, including aromatic electrophilic substitution, nitration, acylation, esterification, etherification, oligomerization, transesterification, isomerization and hydration.