公开(公告)号：US4266013A

公开(公告)日：1981-05-05

申请号：US961827

申请日：1978-11-17

申请人： Keiichi Adachi ,  Shigeo Hirano ,  Nobuyuki Tsujino

发明人： Keiichi Adachi ,  Shigeo Hirano ,  Nobuyuki Tsujino

IPC分类号： C07C67/00 ,  C07C243/38 ,  C07C325/00 ,  C07C335/04 ,  G03C1/485 ,  G03C7/392 ,  G03C1/36

CPC分类号： C07C243/00 ,  C07C243/38 ,  G03C1/48561

摘要： A light-sensitive silver halide photographic material comprising a support having thereon a layer containing a compound represented by the formula (I): ##STR1## wherein R.sub.1 represents an aliphatic or aromatic residue; R.sub.2 represents a hydrogen atom, an aliphatic or an aromatic residue; and X.sub.1 and X.sub.2, which may be the same or different, each represents a divalent aromatic group; and a method of forming a direct positive image which comprises processing a light-sensitive silver halide photographic material having a support carrying thereon an internal latent image type silver halide emulsion layer in the presence of the compound represented by the said formula (I). The compound is particularly effective in combination with diffusible dye releasing (DRR) compounds having o-hydroxyarylsulfamoyl groups.

摘要翻译： 一种感光卤化银照相材料，其包含其上具有由式（I）表示的化合物的层的载体：其中R 1表示脂族或芳族残基; R2代表氢原子，脂族或芳族残基; X 1和X 2可以相同或不同，表示二价芳基; 以及形成直接正像的方法，其包括在所述式（I）表示的化合物的存在下处理其上带有载体上的载体的感光卤化银照相材料。 该化合物与具有邻羟基芳基氨磺酰基的扩散性染料释放（DRR）化合物特别有效。

公开(公告)号：US4245037A

公开(公告)日：1981-01-13

申请号：US88232

申请日：1979-10-25

申请人： Nobuyuki Tsujino ,  Shigeo Hirano ,  Keiichi Adachi

发明人： Nobuyuki Tsujino ,  Shigeo Hirano ,  Keiichi Adachi

IPC分类号： C07C67/00 ,  C07C325/00 ,  C07C335/04 ,  G03C1/485 ,  G03C8/08 ,  G03C1/36

CPC分类号： G03C1/48561 ,  G03C8/08

摘要： A direct positive light-sensitive silver halide photographic material comprising a support having thereon a layer containing a compound represented by the formula (I): ##STR1## wherein R.sub.1 represents an aliphatic residue or an aromatic residue; R.sub.2 represents a hydrogen atom, an aliphatic residue, or an aromatic residue; X.sub.1 and X.sub.2, which may be the same or different, each represents a divalent aromatic residue; and Y represents ##STR2## or a direct bond wherein the O or S is bonded to X.sub.1 ; R represents a divalent aliphatic residue and R.sub.3 represents an aliphatic residue or an aromatic residue. The compound is particularly effective in combination with a diffusible dye releasing dye image providing compound having an o-hydroxyarylsulfamoyl group.

摘要翻译： 一种直接感光型卤化银感光材料，其特征在于，包括具有其上含有式（I）表示的化合物的层的载体：其中R1表示脂肪族残基或芳香族残基; R2表示氢原子，脂肪族残基或芳香族残基; X1和X2可以相同或不同，各自表示二价芳族残基; Y表示直接键，其中O或S键合到X1上; R表示二价脂肪族残基，R 3表示脂肪族残基或芳香族残基。 该化合物与提供具有邻羟基芳基氨磺酰基的化合物的可扩散染料释放染料图像组合特别有效。

公开(公告)号：US4255511A

公开(公告)日：1981-03-10

申请号：US026962

申请日：1979-04-04

申请人： Shigeo Hirano ,  Keiichi Adachi ,  Nobuyuki Tsujino

发明人： Shigeo Hirano ,  Keiichi Adachi ,  Nobuyuki Tsujino

IPC分类号： C07C67/00 ,  C07C325/00 ,  C07C335/04 ,  G03C1/485 ,  G03C8/08 ,  G03C1/06 ,  G03C1/36 ,  G03C1/76 ,  G03C7/00

CPC分类号： G03C1/48561

摘要： A direct positive light-sensitive silver halide photographic material comprising a support having thereon a layer containing a compound represented by the formula (I): ##STR1## wherein R.sub.1 represents an aliphatic residue or an aromatic residue; R.sub.2 represents a hydrogen atom, an aliphatic residue, or an aromatic residue; X.sub.1 and X.sub.2, which may be the same or different, each represents a divalent aromatic residue; and Y represents --R--, --O--R or --S--R-- wherein R represents a divalent aliphatic residue and the O or S is bonded to X.sub.1. The compound is particularly effective in combination with a diffusible dye releasing dye image providing compound having an o-hydroxyarylsulfamoyl group.

摘要翻译： 一种直接感光型卤化银感光材料，其特征在于，包括具有其上含有式（I）表示的化合物的层的载体：其中R1表示脂肪族残基或芳香族残基; R2表示氢原子，脂肪族残基或芳香族残基; X1和X2可以相同或不同，各自表示二价芳族残基; 并且Y表示-R - ， - O-R或-S-R-，其中R表示二价脂族残基，O或S键合到X1上。 该化合物与提供具有邻羟基芳基氨磺酰基的化合物的可扩散染料释放染料图像组合特别有效。

公开(公告)号：US4115122A

公开(公告)日：1978-09-19

申请号：US748858

申请日：1976-12-09

申请人： Keiichi Adachi ,  Tadashi Ikeda ,  Nobuyuki Tsujino

发明人： Keiichi Adachi ,  Tadashi Ikeda ,  Nobuyuki Tsujino

IPC分类号： G03C1/485 ,  G03C1/48 ,  G03C1/06

CPC分类号： G03C1/48546

摘要： A direct positive silver halide photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer of the internal latent image type and being capable of forming a direct positive image, in which at least one hydrophilic colloid layer contains at least one heterocyclic quaternary salt compound represented by the following general formula (I) ##STR1## wherein Z represents an atomic group necessary for forming a 5- or 6-membered heterocyclic nucleus, R.sub.1 represents an aliphatic group, R.sub.2 represents a hydrogen atom or an aliphatic group, R.sub.3 and R.sub.4, which may be the same or different, each represents a hydrogen atom, a halogen atom, an aliphatic group, an alkoxy group, a hydroxy group or an aromatic group, and at least one of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represents a propargyl group, a butynyl group or a substituent containing a propargyl or butynyl group, X.crclbar. represents an anion, n is 1 or 2, with n being 1 in the case that the compound forms an inner salt; in such an amount as to exert a fogging effect on the silver halide emulsion of the internal latent image type.

摘要翻译： 一种直接正性卤化银照相感光材料，其包括其上具有至少一种内部潜像型卤化银乳剂层的载体，并且能够形成直接正像，其中至少一个亲水胶体层包含至少一个 由下列通式（I）表示的杂环季盐化合物其中Z表示形成5-或6-元杂环核所需的原子团，R1表示脂族基团，R2表示氢原子或 可以相同或不同的脂族基团R 3和R 4各自表示氢原子，卤素原子，脂族基团，烷氧基，羟基或芳族基团，R 1，R 2， R 3和R 4表示炔丙基，丁炔基或含有炔丙基或丁炔基的取代基，X（ - ）表示阴离子，n为1或2，在化合物形成 神经盐 其量为对内部潜像型卤化银乳剂发出起雾作用。

公开(公告)号：US4094683A

公开(公告)日：1978-06-13

申请号：US700365

申请日：1976-06-28

申请人： Nobuyuki Tsujino ,  Akira Ogawa ,  Tadao Shishido ,  Keiichi Adachi

发明人： Nobuyuki Tsujino ,  Akira Ogawa ,  Tadao Shishido ,  Keiichi Adachi

IPC分类号： C07C67/00 ,  C07C241/00 ,  C07D213/53 ,  C07D277/62 ,  G03C1/485 ,  G03C5/24 ,  G03C1/06 ,  G03C1/28

CPC分类号： G03C1/48584 ,  G03C1/48561

摘要： A direct positive silver halide light-sensitive material capable of forming direct positive images comprising a support having coated thereon at least one internal image type silver halide emulsion layer, wherein at least one hydrophilic colloid layer contains a heterocyclic quaternary salt compound represented by formula (I) in an amount necessary to provide the silver halide photographic emulsion with a fogging function. ##STR1## wherein Z is an atomic group necessary for completing a 5- or 6-membered heterocyclic nucleus, R.sub.1 is an aliphatic group, R.sub.2 is a hydrazonoalkyl group, X.crclbar. is an anion, and n is 1 or 2.

摘要翻译： 能够形成直接正图像的直接正卤化银感光材料，其包括涂覆有至少一个内部图像型卤化银乳剂层的载体，其中至少一个亲水胶体层含有由式（I）表示的杂环季盐化合物 ）以提供具有起雾功能的卤化银照相乳剂所需的量。 （I）其中Z是完成5-或6-元杂环核所必需的原子团，R 1是脂族基团，R 2是亚肼基烷基，X（ - ）是阴离子，n是1或 2。

公开(公告)号：US4518682A

公开(公告)日：1985-05-21

申请号：US532631

申请日：1983-09-15

申请人： Hidetoshi Kobayashi ,  Toshiro Takahashi ,  Shigeo Hirano ,  Takeshi Hirose ,  Keiichi Adachi

发明人： Hidetoshi Kobayashi ,  Toshiro Takahashi ,  Shigeo Hirano ,  Takeshi Hirose ,  Keiichi Adachi

IPC分类号： G03C7/32 ,  G03C1/485 ,  G03C7/26 ,  G03C7/305

CPC分类号： G03C7/30541 ,  G03C1/485 ,  Y10S430/156

摘要： A silver halide photographic light-sensitive material is disclosed. The material has improved sensitivity and granularity as well as an increased gradient. Further, the material can be processed by rapid processing methods. The material is comprised of a support having positioned thereon a light-sensitive silver halide emulsion layer and a compound represented by the general formula (I):A-B (I)wherein A is residue of a compound capable of undergoing a coupling reaction with an oxidized primary amine developer, the residue being derived by eliminating a hydrogen atom from an active position of the compound. B is a group capable of being released through a coupling reaction to exert a fogging effect.

摘要翻译： 公开了一种卤化银照相感光材料。 该材料具有提高的灵敏度和粒度以及增加的梯度。 此外，材料可以通过快速加工方法加工。 该材料由其上定位有感光卤化银乳剂层的支持体和由通式（I）表示的化合物组成：AB（I）其中A是能够与氧化的（I）化合物进行偶联反应的化合物的残基 伯胺显影剂，残留物是通过从该化合物的活性位置除去氢原子得到的。 B是能够通过偶联反应释放以发挥起雾效果的基团。

公开(公告)号：US4489155A

公开(公告)日：1984-12-18

申请号：US511030

申请日：1983-07-05

申请人： Kei Sakanoue ,  Shigeo Hirano ,  Keiichi Adachi

发明人： Kei Sakanoue ,  Shigeo Hirano ,  Keiichi Adachi

IPC分类号： G03C7/26 ,  G03C7/30 ,  G03C7/32 ,  G03C7/00

CPC分类号： G03C7/3003 ,  G03C1/42 ,  G03C1/7614 ,  G03C2200/19 ,  G03C7/32

摘要： In a silver halide color photographic material is disclosed. The material is comprised of a blue-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer, and a red-sensitive silver halide emulsion layer. The granularity of the material is improved by incorporating a non-diffusible coupler capable of forming a properly smearing diffusible dye by causing a reaction with the oxidation product of a color developing agent and a colorless competing compound capable of capturing the oxidation product of a color developing agent in at least one of the foregoing silver halide emulsion layers.

摘要翻译： 在卤化银彩色照相材料中公开。 该材料包括感蓝卤化银乳剂层，感绿卤化银乳剂层和感红卤化银乳剂层。 通过引入能够形成适当涂抹的可扩散染料的非扩散性成色剂，通过引发与彩色显影剂的氧化产物和能够捕获显色剂的氧化产物的无色竞争化合物的反应来改善材料的粒度 在上述卤化银乳剂层中的至少一种。

公开(公告)号：US4195999A

公开(公告)日：1980-04-01

申请号：US896870

申请日：1978-04-17

申请人： Keiichi Adachi ,  Shigeo Hirano ,  Tadashi Ikeda ,  Takeshi Mikami

发明人： Keiichi Adachi ,  Shigeo Hirano ,  Tadashi Ikeda ,  Takeshi Mikami

IPC分类号： G03C7/26 ,  C07D231/22 ,  C07D231/32 ,  C07D239/60 ,  C07D239/62 ,  C07D295/104 ,  C07D295/145 ,  G03C1/815 ,  G03C1/84 ,  G03C1/06 ,  G03C1/72 ,  G03C1/76

CPC分类号： C07D295/104 ,  C07D231/22 ,  C07D231/32 ,  C07D239/60 ,  C07D239/62 ,  C07D295/145 ,  G03C1/8155

摘要： A silver halide photographic material comprising a support having thereon at least one silver halide photographic emulsion layer with the silver halide photographic material containing, as an ultraviolet light absorbing agent, at least one compound having the general formula (I) ##STR1## wherein R.sub.1 and R.sub.2, which may be the same or different, each represents a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, or an aryl group having 6 to 20 carbon atoms, provided that the both of R.sub.1 and R.sub.2 do not simultaneously represent hydrogen atoms, and further, R.sub.1 and R.sub.2 can combine and form a cyclic amino group; R.sub.3 represents a carboxyl group, --COOR.sub.5, --COR.sub.5 or --SO.sub.2 R.sub.5, and R.sub.4 represents a carboxyl group, --COOR.sub.6, or --COR.sub.6 wherein R.sub.5 and R.sub.6, which may be the same or different, each represents an alkyl group having 1 to 20 carbon atoms, or an aryl group having 6 to 20 carbon atoms and further, R.sub.5 and R.sub.6 can combine together and form a 1,3-dioxocyclohexane nucleus, a barbituric acid nucleus, a 1,2-diaza-3,5-dioxocyclopentane nucleus, or a 2,4-diazo-1-alkoxy-3,5-dioxocyclohexene nucleus; n is an integer of 1 or 2 and when n is 2, at least one of R.sub.1, R.sub.2 and R.sub.6 may represent an alkylene or arylene group whereby the compound is a dimer; and a method of preventing the effects of ultraviolet light on a silver halide photographic material comprising incorporating into the silver halide photographic material, as an ultraviolet light absorbing agent, at least one compound having the general formula (I) above.

摘要翻译： 一种卤化银照相材料，其中含有至少一种卤化银照相乳剂层的支持体，其中卤化银照相材料含有作为紫外线吸收剂的至少一种具有通式（I）的化合物（I） 其中R 1和R 2可以相同或不同，各自表示氢原子，具有1-20个碳原子的烷基或具有6至20个碳原子的芳基，条件是R 1和R 2都不 同时代表氢原子，此外，R1和R2可以结合形成环氨基; R3表示羧基-COOR5，-COR5或-SO2R5，R4表示羧基-COOR6或-COR6，其中R5和R6可相同或不同，表示具有1〜20个碳原子的烷基 碳原子或具有6〜20个碳原子的芳基，此外，R5和R6可以结合在一起形成1,3-二氧环己烷核，巴比土酸核，1,2-二氮杂-3,5-二氧杂环戊烷核 ，或2,4-重氮-1-烷氧基-3,5-二氧环己烯核; n是1或2的整数，当n是2时，R 1，R 2和R 6中的至少一个可以表示亚烷基或亚芳基，由此化合物是二聚体; 以及防止紫外光对卤化银照相材料的影响的方法，包括将卤化银照相材料作为紫外线吸收剂，至少一种具有上述通式（I）的化合物。

公开(公告)号：US4789624A

公开(公告)日：1988-12-06

申请号：US42612

申请日：1987-04-21

申请人： Kei Sakanoue ,  Shigeo Hirano ,  Takehiko Ueda ,  Keiichi Adachi

发明人： Kei Sakanoue ,  Shigeo Hirano ,  Takehiko Ueda ,  Keiichi Adachi

IPC分类号： G03C7/26 ,  G03C7/32 ,  G03C7/392 ,  G03C7/34 ,  G03C7/36 ,  G03C7/38

CPC分类号： G03C7/39216

摘要： A silver halide color photographic light-sensitive material which contains a high speed reactive type coupler having a relative coupling speed of 0.35 to 1.0 and a compound represented by the following general formula (I): ##STR1## wherein R represents a hydrogen atom, a substituted or unsubstituted aliphatic group, a substituted or unsubstituted aromatic group, or a substituted or unsubstituted heterocyclic group.The silver halide color photographic light-sensitive material provides color images having greatly improved graininess in both high density areas and low density areas, without adversely affecting sensitivity.

摘要翻译： 一种卤化银彩色照相感光材料，其含有相对耦合速度为0.35至1.0的高速反应型偶合剂和由以下通式（I）表示的化合物：其中R表示氢 取代或未取代的脂族基团，取代或未取代的芳基，或取代或未取代的杂环基。 卤化银彩色摄影感光材料提供了在高密度区域和低密度区域中具有极大改善的颗粒度的彩色图像，而不会不利地影响灵敏度。

公开(公告)号：US4474874A

公开(公告)日：1984-10-02

申请号：US474610

申请日：9183-03-11

申请人： Shigeo Hirano ,  Kei Sakanoue ,  Keiichi Adachi

发明人： Shigeo Hirano ,  Kei Sakanoue ,  Keiichi Adachi

IPC分类号： G03C7/26 ,  C07C45/00 ,  C07C47/565 ,  C07C49/825 ,  C07C67/00 ,  C07C231/00 ,  C07C235/46 ,  C07C235/48 ,  C07C235/52 ,  C07C301/00 ,  C07C309/42 ,  C07C309/75 ,  C07C313/00 ,  C07C313/04 ,  C07C317/22 ,  C07D295/18 ,  G03C7/392

CPC分类号： G03C7/39216

摘要： A color photographic silver halide light-sensitive material which prevents formation of color fog is disclosed, containing a negative gradation photographic silver halide emulsion which is substantially of the surface latent image type, and at least one compound represented by the general formula (I): ##STR1## wherein X represents --CONR.sup.1 R.sup.2, --COR.sup.1, --SO.sub.2 R.sup.1, or --SO.sub.3 R.sup.1 and wherein R.sup.1 and R.sup.2 each are selected from the group consisting of a hydrogen atom, a substituted or unsubstituted aliphatic group, and a substituted or unsubstituted aromatic group, and are selected such that may combine together to form a ring.

摘要翻译： 公开了一种防止色雾形成的彩色照相卤化银感光材料，其含有基本上为表面潜影型的负型渐变照相卤化银乳剂，以及至少一种由通式（I）表示的化合物： 其中X表示-CONR1R2，-COR1，-SO2R1或-SO3R1，其中R1和R2各自选自氢原子，取代或未取代的脂族基团和取代或未取代的芳族基团， 并且被选择成可以组合在一起以形成环。