公开(公告)号：US5352527A

公开(公告)日：1994-10-04

申请号：US946609

申请日：1992-09-18

申请人： Shigeyuki Harada ,  Yoshihiko Hiyoshi ,  Takeshi Yuyama ,  Keishi Taniguchi

发明人： Shigeyuki Harada ,  Yoshihiko Hiyoshi ,  Takeshi Yuyama ,  Keishi Taniguchi

IPC分类号： B41M5/382 ,  B41M5/40 ,  B41M5/44 ,  B41M5/26

CPC分类号： B41M5/443 ,  Y10S428/913 ,  Y10S428/914 ,  Y10T428/24876 ,  Y10T428/31663

摘要： A thermal image transfer recording medium, containing a support, a thermal image transfer ink layer formed on the support, and a heat-resistant protective layer formed on the back side of the support, opposite to the thermal image transfer ink layer with respect to the support, the heat-resistant protective layer having a tensile strength effective to prevent the protective layer from adhering to a thermal head and to prevent loss of flexibility of the protective layer, the heat-resistant protective layer, containing an amount of each of (i) an amino-modified polysiloxane, (ii) a polyisocyanate and (iii) a reaction product of the amino-modified polysiloxane and the polyisocyanate effective for obtaining the tensile strength in the heat-resistant protective layer.

摘要翻译： 包含支撑体的热图像转印记录介质，形成在支撑体上的热图像转印油墨层和形成在支撑体的背侧上的相对于热像转印油墨层相反的耐热保护层 所述耐热保护层具有有效地防止保护层粘附到热敏头上的抗拉强度，并且防止保护层的柔性的损失，耐热保护层含有（i ）氨基改性聚硅氧烷，（ii）多异氰酸酯和（iii）氨基改性聚硅氧烷和多异氰酸酯的反应产物对于获得耐热保护层中的拉伸强度是有效的。

公开(公告)号：US5328754A

公开(公告)日：1994-07-12

申请号：US16957

申请日：1993-02-12

申请人： Takeshi Yuyama ,  Keishi Taniguchi ,  Shigeyuki Harada

发明人： Takeshi Yuyama ,  Keishi Taniguchi ,  Shigeyuki Harada

IPC分类号： B41M5/26 ,  B41M5/392 ,  B41M5/395

CPC分类号： B41M5/395 ,  B41M5/392 ,  Y10S428/913 ,  Y10S428/914 ,  Y10T428/31511

摘要： A thermosensitive image transfer ink sheet is composed of a support and a thermofusible coloring layer formed on the support, which contains a coloring agent, an epoxy resin, a mercapto-group-containing compound serving as an epoxy resin crosslinking agent, and a tertiary amine or a salt thereof serving as a crosslinking reaction promoting agent. A thermal image transfer recording material is composed of a thermosensitive image transfer ink sheet, and an image receiving sheet to which images are to be transferred from the thermosensitive image transfer ink sheet. This thermosensitive image transfer ink sheet is composed of a support and a thermofusible coloring layer formed on the support, with the thermofusible coloring layer containing a coloring agent and one or two components selected from the group consisting of the epoxy resin, the mercapto-group-containing compound, and the tertiary amine or the salt thereof, while one or two components selected from the group consisting of the epoxy resin, the mercapto-group-containing compound, and the tertiary amine or the salt thereof which are not contained in the thermofusible coloring layer are contained in a surface portion of the image receiving sheet.

摘要翻译： 热敏图像转印油墨片由载体和形成在支持体上的热熔着色层组成，其中含有着色剂，环氧树脂，含巯基的化合物作为环氧树脂交联剂，和叔胺 或其盐作为交联反应促进剂。 热图像转印记录材料由热敏图像转印油墨纸和从热敏图像转印油墨纸转印图像的图像接收纸组成。 该热敏图像转印油墨片由支撑体和形成在载体上的热熔着色层组成，热熔着色层含有着色剂和选自环氧树脂，巯基 - 含有叔胺或其盐的一种或两种以上的组分，所述组分选自所述热熔体中不含有的环氧树脂，含巯基化合物和叔胺或其盐 着色层包含在图像接收片的表面部分中。

公开(公告)号：US5622909A

公开(公告)日：1997-04-22

申请号：US441435

申请日：1995-05-15

申请人： Hiromi Furuya ,  Yasutomo Mori ,  Keishi Taniguchi ,  Takeshi Yuyama

发明人： Hiromi Furuya ,  Yasutomo Mori ,  Keishi Taniguchi ,  Takeshi Yuyama

IPC分类号： B41M5/333 ,  B41M5/155

CPC分类号： B41M5/3335

摘要： A thermosensitive recording material of this invention has a support, on which a thermosensitive color developing layer mainly composed of a leuco dye and a color developer which is contacted with the leuco dye while heating to develop a color and a protective layer mainly composed of polyvinyl alcohol together with either aziridine compound or dimethylolurea are successively provided, the color developer being at least one of phthalic acid derivatives represented by the following general formula (I): ##STR1## wherein R.sub.1, X, Y and 1 are as defined in above. The thermosensitive recording material of this invention is excellent in sensitivity and density of the color development and has the high storage stability of the recorded images. Accordingly, the thermosensitive recording material of this invention is very useful.The selected inorganic filler may be incorporated in the thermosensitive color developing layer and/or the protective layer.

摘要翻译： 本发明的热敏记录材料具有支撑体，在其上加热主要由无色染料组成的热敏彩色显影层和与无色染料接触以显色的显色剂和主要由聚乙烯醇组成的保护层 与氮丙啶化合物或二羟甲基脲一起提供，彩色显影剂是由以下通式（I）表示的邻苯二甲酸衍生物中的至少一种：其中R 1，X，Y和1如 以上。 本发明的热敏记录材料的显色灵敏度和密度优异，并且具有高记录图像的储存稳定性。 因此，本发明的热敏记录材料是非常有用的。 所选择的无机填料可以并入热敏彩色显影层和/或保护层中。

公开(公告)号：US5409884A

公开(公告)日：1995-04-25

申请号：US214101

申请日：1994-03-17

申请人： Shigeyuki Harada ,  Keishi Taniguchi ,  Yoichi Iwaki ,  Yutaka Sakai ,  Shigekazu Teranishi ,  Susumu Kawakami ,  Hironori Hata

发明人： Shigeyuki Harada ,  Keishi Taniguchi ,  Yoichi Iwaki ,  Yutaka Sakai ,  Shigekazu Teranishi ,  Susumu Kawakami ,  Hironori Hata

IPC分类号： B41M5/382 ,  B41M5/40 ,  B41M5/44 ,  B41M5/035 ,  B41M5/38

CPC分类号： B41M5/443 ,  Y10S428/913 ,  Y10S428/914 ,  Y10T428/31663 ,  Y10T428/31982

摘要： A thermal image transfer recording medium is composed of a support, a thermal image transfer ink layer formed thereon, and a heat resistant protective layer which is composed of a cellulose-modified polymer with a backbone polymer thereof being cellulose and/or a cellulose derivative and a branch polymer thereof being a copolymer of a reactive silicone oil and a vinyl monomer, and which is formed on the back side of the support opposite to the thermal image transfer ink layer with respect to the support.

摘要翻译： 热转印记录介质由支撑体，形成在其上的热转印油墨层和由其主链聚合物为纤维素和/或纤维素衍生物的纤维素改性聚合物组成的耐热保护层构成， 其分支聚合物是反应性硅油和乙烯基单体的共聚物，并且其形成在与热像转印油墨层相对于载体相对的载体的背面上。

公开(公告)号：US08317913B2

公开(公告)日：2012-11-27

申请号：US12190946

申请日：2008-08-13

申请人： Shigeo Hatada ,  Keishi Taniguchi ,  Shigeru Kusakata ,  Ichiroh Fujii ,  Akihiko Matsuyama ,  Yuuki Yokohama

发明人： Shigeo Hatada ,  Keishi Taniguchi ,  Shigeru Kusakata ,  Ichiroh Fujii ,  Akihiko Matsuyama ,  Yuuki Yokohama

IPC分类号： C09D11/00

CPC分类号： C09D11/101

摘要： The present invention provides an inkjet ink containing at least a colorant, water, a water insoluble resin, a fluorine surfactant, and a polyether-modified silicone oil, wherein the polyether-modified silicone oil has a hydrophobic value of 0.40 to 1.5, and the hydrophobic value is expressed by Equation 1: Hydrophobic value=A/B  Equation 1 where “A” represents an integration value of a peak area from 0 ppm to 0.3 ppm in a 1H-NMR spectrum of the polyether-modified silicone oil using tetramethylsilane as a reference substance; and “B” represents an integration value of a peak area from 3.5 ppm to 4.0 ppm in the 1H-NMR spectrum.

摘要翻译： 本发明提供至少含有着色剂，水，不溶于水的树脂，氟表面活性剂和聚醚改性硅油的喷墨油墨，其中聚醚改性硅油的疏水性值为0.40〜1.5， 疏水值由等式1表示：疏水值= A / B等式1其中A表示使用四甲基硅烷作为参考的聚醚改性硅油的1 H-NMR光谱中0ppm至0.3ppm的峰面积的积分值 物质; B表示1H-NMR谱中峰面积为3.5ppm〜4.0ppm的积分值。

公开(公告)号：US20090047431A1

公开(公告)日：2009-02-19

申请号：US12190946

申请日：2008-08-13

申请人： Shigeo HATADA ,  Keishi Taniguchi ,  Shigeru Kusakata ,  Ichiroh Fujii ,  Akihiko Matsuyama ,  Yuuki Yokohama

发明人： Shigeo HATADA ,  Keishi Taniguchi ,  Shigeru Kusakata ,  Ichiroh Fujii ,  Akihiko Matsuyama ,  Yuuki Yokohama

IPC分类号： B05D1/00 ,  C08K5/00 ,  C08K5/06 ,  B05C11/00 ,  C08K5/41

CPC分类号： C09D11/101

摘要： The present invention provides an inkjet ink containing at least a colorant, water, a water insoluble resin, a fluorine surfactant, and a polyether-modified silicone oil, wherein the polyether-modified silicone oil has a hydrophobic value of 0.40 to 1.5, and the hydrophobic value is expressed by Equation 1: Hydrophobic value=A/B  Equation 1 where “A” represents an integration value of a peak area from 0 ppm to 0.3 ppm in a 1H-NMR spectrum of the polyether-modified silicone oil using tetramethylsilane as a reference substance; and “B” represents an integration value of a peak area from 3.5 ppm to 4.0 ppm in the 1H-NMR spectrum.

摘要翻译： 本发明提供至少含有着色剂，水，不溶于水的树脂，氟表面活性剂和聚醚改性硅油的喷墨油墨，其中聚醚改性硅油的疏水性值为0.40〜1.5， 疏水值由等式1表示：<？in-line-formula description =“In-line Formulas”end =“lead”？>疏水值= A / B等式1 <？in-line-formula description =“In- 线“公式”end =“tail”？>其中“A”表示使用四甲基硅烷作为对照物质的聚醚改性硅油的1 H-NMR光谱中的峰面积从0ppm至0.3ppm的积分值; “1”表示1H-NMR谱中峰面积为3.5ppm〜4.0ppm的积分值。

公开(公告)号：US5658850A

公开(公告)日：1997-08-19

申请号：US631771

申请日：1996-04-12

申请人： Keishi Taniguchi ,  Hidehiro Mochizuki

发明人： Keishi Taniguchi ,  Hidehiro Mochizuki

IPC分类号： B41M5/52 ,  B41M7/00 ,  B41M5/035 ,  B41M5/38

CPC分类号： B41M7/0027 ,  B41M5/52 ,  B41M2205/02 ,  B41M5/5227 ,  B41M5/529 ,  Y10S428/913 ,  Y10S428/914 ,  Y10T428/169 ,  Y10T428/24826 ,  Y10T428/31551 ,  Y10T428/31663 ,  Y10T428/31739 ,  Y10T428/31786 ,  Y10T428/31855

摘要： An image supporting sheet, preferably for sublimation thermal transfer recording, which has excellent resistance to heat, light, solvents, scratch, and alteration.The image supporting sheet including:(a) a substrate;(b) a dye receiving layer which includes a resin and a releasing agent formed on the substrate;(c) a dye image diffused into the dye receiving layer; and(d) a clear protective film adhered to the dye receiving layer by an adhesive agent;wherein the adhesive agent includes at least one of a cyanoacrylate compound and a thermoplastic polyurethane resin, and preferably, the clear protective film includes an ultraviolet stabilizer, and/or at least one of the dye receiving layer and the adhesive agent includes at least one of an ultraviolet stabilizer, a photo-stabilizer, an antioxidant and a quencher.

摘要翻译： 图像支持片，优选用于升华热转印记录，其具有优异的耐热，轻，溶剂，划痕和变化的耐受性。 图像支持片材包括：（a）基底; （b）染料接收层，其包含在基材上形成的树脂和脱模剂; （c）染料图像扩散到染料接收层中; 和（d）通过粘合剂粘附到染料接收层上的透明保护膜; 其中所述粘合剂包括氰基丙烯酸酯化合物和热塑性聚氨酯树脂中的至少一种，并且优选地，所述透明保护膜包括紫外线稳定剂，和/或所述染料接收层和所述粘合剂中的至少一种包括以下中的至少一种： 紫外线稳定剂，光稳定剂，抗氧化剂和猝灭剂。

公开(公告)号：US5447900A

公开(公告)日：1995-09-05

申请号：US305913

申请日：1994-09-15

申请人： Hideo Suzaki ,  Keishi Taniguchi ,  Kunio Hayakawa ,  Hiromi Furuya

发明人： Hideo Suzaki ,  Keishi Taniguchi ,  Kunio Hayakawa ,  Hiromi Furuya

IPC分类号： B41M5/333 ,  B41M5/30 ,  B41M5/40

CPC分类号： B41M5/3335

摘要： A thermosensitive recording material having a support and a thermosensitive coloring layer which is formed on the support and contains a leuco dye and a color developer capable of inducing color formation in the leuco dye upon application of heat thereto, with the color developer including one compound with an acid dissociation constant (pKa) of 7.0 or less in a mixed solvent of water and methanol with a volume ratio of 1:1.

摘要翻译： 一种具有支持体和热敏着色层的热敏记录材料，其形成在载体上并含有无色染料和能够在加热时在无色染料中引起颜色形成的显色剂，其中显色剂包括一种具有 在水和甲醇的混合溶剂中体积比为1:1的酸解离常数（pKa）为7.0或更低。

公开(公告)号：US5432534A

公开(公告)日：1995-07-11

申请号：US338112

申请日：1994-11-09

申请人： Shoji Maruyama ,  Hiroshi Goto ,  Eiichi Kawamura ,  Masaru Shimada ,  Keishi Kubo ,  Kyoji Tsutsui ,  Hideaki Ema ,  Takehito Yamaguchi ,  Hiroki Kuboyama ,  Ichiro Sawamura ,  Keishi Taniguchi

发明人： Shoji Maruyama ,  Hiroshi Goto ,  Eiichi Kawamura ,  Masaru Shimada ,  Keishi Kubo ,  Kyoji Tsutsui ,  Hideaki Ema ,  Takehito Yamaguchi ,  Hiroki Kuboyama ,  Ichiro Sawamura ,  Keishi Taniguchi

IPC分类号： B41M5/30 ,  B41M5/333 ,  B41M5/26 ,  B41J2/32 ,  B41J2/435 ,  B41J2/475

CPC分类号： B41M5/305 ,  B41M5/3335 ,  B41M5/3336

摘要： A reversible thermosensitive coloring composition is composed of (i) an electron-donor coloring compound and (ii) an electron-acceptor compound selected from the group consisting of an organic phosphoric acid compound, an aliphatic carboxylic acid, and a phenolic compound, each having a straight chain or branched chain alkyl group or alkyenyl group having 12 or more carbon atoms, the electron-donor coloring compound and the electron-acceptor compound being capable of reacting to induce color formation in the reversible thermosensitive coloring composition at the eutectic temperature thereof. The electron-donor coloring compound and the electron-acceptor compound, when fused and colored in a mixed state, with application of heat thereto, followed by rapidly cooling the fused mixture, exhibit an exothermic peak in a temperature elevation process in a differential scanning calorific analysis or in a differential thermal analysis. A recording medium and display medium using the above reversible thermosensitive coloring composition, a recording method of using the recording medium, a display method of using the display medium, a display method of using the display medium, and a display apparatus using the display medium are disclosed.

公开(公告)号：US5395676A

公开(公告)日：1995-03-07

申请号：US51793

申请日：1993-04-26

申请人： Yuichi Taka ,  Keishi Taniguchi

发明人： Yuichi Taka ,  Keishi Taniguchi

IPC分类号： B41M5/382 ,  B41M5/40 ,  B41M5/44 ,  B32B3/00

CPC分类号： B41M5/443 ,  Y10S428/913 ,  Y10S428/914

摘要： A thermal image transfer recording medium is composed of a support, a thermosensitive image transfer layer formed thereon, and a back layer containing a silicone rubber and a silicone oil with a thickness of 0.001 to 0.1 .mu.m formed on the back side of the support opposite to the thermosensitive image transfer layer.

摘要翻译： 热图像转印记录介质由形成在其上的支持体，热敏图像转印层和背面层组成，该背面层形成在相对的支撑体背面上形成的厚度为0.001至0.1μm的硅橡胶和硅油 到热敏图像转印层。