公开(公告)号：US08680175B2

公开(公告)日：2014-03-25

申请号：US13616058

申请日：2012-09-14

申请人： Shigeo Hatada ,  Keishi Taniguchi ,  Shigeru Kusakata ,  Ichiroh Fujii ,  Akihiko Matsuyama ,  Yuuki Yokohama

发明人： Shigeo Hatada ,  Keishi Taniguchi ,  Shigeru Kusakata ,  Ichiroh Fujii ,  Akihiko Matsuyama ,  Yuuki Yokohama

IPC分类号： C09D11/10

CPC分类号： C09D11/101

摘要： The present invention provides an inkjet ink containing at least a colorant, water, a water insoluble resin, a fluorine surfactant, and a polyether-modified silicone oil, wherein the polyether-modified silicone oil has a hydrophobic value of 0.40 to 1.5, and the hydrophobic value is expressed by Equation 1; Hydrophobic value=A/B  Equation 1 where “A” represents an integration value of a peak area from 0 ppm to 0.3 ppm in a 1H-NMR spectrum of the polyether-modified silicone oil using tetramethylsilane as a reference substance; and “B” represents an integration value of a peak area from 3.5 ppm to 4.0 ppm in the 1H-NMR spectrum.

摘要翻译： 本发明提供至少含有着色剂，水，不溶于水的树脂，氟表面活性剂和聚醚改性硅油的喷墨油墨，其中聚醚改性硅油的疏水性值为0.40〜1.5， 疏水值由等式1表示; 疏水值= A / B等式1其中“A”表示使用四甲基硅烷作为参考物质的聚醚改性硅油的1 H-NMR光谱中的峰面积从0ppm至0.3ppm的积分值; “1”表示1H-NMR谱中峰面积为3.5ppm〜4.0ppm的积分值。

公开(公告)号：US08317913B2

公开(公告)日：2012-11-27

申请号：US12190946

申请日：2008-08-13

申请人： Shigeo Hatada ,  Keishi Taniguchi ,  Shigeru Kusakata ,  Ichiroh Fujii ,  Akihiko Matsuyama ,  Yuuki Yokohama

发明人： Shigeo Hatada ,  Keishi Taniguchi ,  Shigeru Kusakata ,  Ichiroh Fujii ,  Akihiko Matsuyama ,  Yuuki Yokohama

IPC分类号： C09D11/00

CPC分类号： C09D11/101

摘要： The present invention provides an inkjet ink containing at least a colorant, water, a water insoluble resin, a fluorine surfactant, and a polyether-modified silicone oil, wherein the polyether-modified silicone oil has a hydrophobic value of 0.40 to 1.5, and the hydrophobic value is expressed by Equation 1: Hydrophobic value=A/B  Equation 1 where “A” represents an integration value of a peak area from 0 ppm to 0.3 ppm in a 1H-NMR spectrum of the polyether-modified silicone oil using tetramethylsilane as a reference substance; and “B” represents an integration value of a peak area from 3.5 ppm to 4.0 ppm in the 1H-NMR spectrum.

摘要翻译： 本发明提供至少含有着色剂，水，不溶于水的树脂，氟表面活性剂和聚醚改性硅油的喷墨油墨，其中聚醚改性硅油的疏水性值为0.40〜1.5， 疏水值由等式1表示：疏水值= A / B等式1其中A表示使用四甲基硅烷作为参考的聚醚改性硅油的1 H-NMR光谱中0ppm至0.3ppm的峰面积的积分值 物质; B表示1H-NMR谱中峰面积为3.5ppm〜4.0ppm的积分值。

公开(公告)号：US20090047431A1

公开(公告)日：2009-02-19

申请号：US12190946

申请日：2008-08-13

申请人： Shigeo HATADA ,  Keishi Taniguchi ,  Shigeru Kusakata ,  Ichiroh Fujii ,  Akihiko Matsuyama ,  Yuuki Yokohama

发明人： Shigeo HATADA ,  Keishi Taniguchi ,  Shigeru Kusakata ,  Ichiroh Fujii ,  Akihiko Matsuyama ,  Yuuki Yokohama

IPC分类号： B05D1/00 ,  C08K5/00 ,  C08K5/06 ,  B05C11/00 ,  C08K5/41

CPC分类号： C09D11/101

摘要： The present invention provides an inkjet ink containing at least a colorant, water, a water insoluble resin, a fluorine surfactant, and a polyether-modified silicone oil, wherein the polyether-modified silicone oil has a hydrophobic value of 0.40 to 1.5, and the hydrophobic value is expressed by Equation 1: Hydrophobic value=A/B  Equation 1 where “A” represents an integration value of a peak area from 0 ppm to 0.3 ppm in a 1H-NMR spectrum of the polyether-modified silicone oil using tetramethylsilane as a reference substance; and “B” represents an integration value of a peak area from 3.5 ppm to 4.0 ppm in the 1H-NMR spectrum.

摘要翻译： 本发明提供至少含有着色剂，水，不溶于水的树脂，氟表面活性剂和聚醚改性硅油的喷墨油墨，其中聚醚改性硅油的疏水性值为0.40〜1.5， 疏水值由等式1表示：<？in-line-formula description =“In-line Formulas”end =“lead”？>疏水值= A / B等式1 <？in-line-formula description =“In- 线“公式”end =“tail”？>其中“A”表示使用四甲基硅烷作为对照物质的聚醚改性硅油的1 H-NMR光谱中的峰面积从0ppm至0.3ppm的积分值; “1”表示1H-NMR谱中峰面积为3.5ppm〜4.0ppm的积分值。

公开(公告)号：US5084593A

公开(公告)日：1992-01-28

申请号：US627583

申请日：1990-12-14

申请人： Hiroshi Gotoh ,  Shigeru Kusakata ,  Isao Shiojima

发明人： Hiroshi Gotoh ,  Shigeru Kusakata ,  Isao Shiojima

IPC分类号： B41M5/136 ,  B41M5/155 ,  B41M5/323 ,  B41M5/333

CPC分类号： B41M5/323 ,  B41M5/136 ,  B41M5/155 ,  B41M5/3335

摘要： Leuco dyes of the formula (I) are disclosed, ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represent an alkyl group having 1 to 10 carbon atoms; X represents hydrogen, an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms or a halogen; and Y represents R.sub.5 --Z--SO.sub.2 NH--, R.sub.6 --Z--CONH--, or ##STR2## in which Z represents ##STR3## R.sub.5 and R.sub.6 each represent hydrogen, an alkyl group having 1 to 10 carbon atoms, or a halogen; and R.sub.7 and R.sub.8 each represent hydrogen, a cyano group, or --COR.sub.9, in which R.sub.9 represents a lower alkyl group, a lower alkoxyl group, a phenyl group which may be substituted by an alkyl group having 1 to 4 carbon atoms, an alkoxyl group having 1 to 4 carbon atoms, or a halogen; a naphthyl group which may be substituted by an alkyl group having 1 to 4 carbon atoms, an alkoxyl group having 1 to 4 carbon atoms or a halogen with the proviso that R.sub.7 and R.sub.8 are not both hydrogen. Further a recording material comprising any of the above-mentioned leuco dyes and a particular phenolic compound as a color developer capable of inducing color formation in the leuco dye is disclosed.

摘要翻译： 公开了式（I）的无色染料，其中R 1，R 2，R 3和R 4各自表示具有1至10个碳原子的烷基; X表示氢，碳原子数1〜10的烷基，碳原子数1〜10的烷氧基或卤素; 并且Y表示R5-Z-SO2NH-，R6-Z-CONH-或其中Z表示R5和R6各自表示氢，具有1-10个碳原子的烷基或卤素的 并且R 7和R 8各自表示氢，氰基或-COR 9，其中R 9表示低级烷基，低级烷氧基，可被碳原子数1〜4的烷基取代的苯基，烷氧基 具有1至4个碳原子的基团，或卤素; 可以被碳原子数1〜4的烷基取代的萘基，碳原子数1〜4的烷氧基或卤素，条件是R 7和R 8不都是氢。 还公开了一种记录材料，其包含任何上述无色染料和特定的酚类化合物作为能够诱导无色染料形成颜色的彩色显影剂。

公开(公告)号：US4939117A

公开(公告)日：1990-07-03

申请号：US291675

申请日：1988-12-29

申请人： Shigeru Kusakata ,  Hiroshi Gotoh ,  Isao Shiojima

发明人： Shigeru Kusakata ,  Hiroshi Gotoh ,  Isao Shiojima

IPC分类号： B41M5/323

CPC分类号： B41M5/323

摘要： A leuco dye of the formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, and R.sup.8 each represent a lower alkyl group; A represents ##STR2## in which R.sup.9 and R.sup.10 each represent hydrogen, provided that both R.sup.9 and R.sup.10 may not be hydrogen, --CN or --COR.sup.14 in which R.sup.14 represents a phenyl group which is unsubstituted or is substituted by an alkyl group having 1 to 4 carbon atoms, an alkoxyl group having 1 to 4 carbon atoms, or a halogen, a naphthyl group which is unsubstituted or is substituted by an alkyl group having 1 to 4 carbon atoms, an alkoxyl group having 1 to 4 carbon atoms or a halogen, or a lower alkoxyl group, ##STR3## in which ##STR4## represents a phenyl group or a naphthyl group, R.sup.11 represents hydrogen, a lower alkyl group, a halogen, an amino group, which is unsubstituted or is substituted by an alkyl group having 1 to 4 carbon atoms, or a nitro group, or ##STR5## in which R.sup.12 represents a lower alkyl group, or ##STR6## in which R.sup.13 represents hydrogen, a lower alkyl group, a halogen, a hydroxyl group, a trifluoromethyl group, a nitro group, an amino group which is unsubstituted or is substituted by an alkyl group having 1 to 4 carbon atoms, or amide group. These dyes absorb in the near-infrared region and yields colored images with a color developer therefor with excellent preservability.

摘要翻译： 式（I）的无色染料：其中R 1，R 2，R 3，R 4，R 5，R 6，R 7和R 8各自表示低级烷基; A表示，其中R 9和R 10各自表示氢，条件是R 9和R 10可以不是氢，-CN或-COR 14，其中R 14表示未被取代或被具有1至 4个碳原子，具有1至4个碳原子的烷氧基或卤素，未被取代或被具有1至4个碳原子的烷基取代的萘基，具有1至4个碳原子的烷氧基或卤素 ，或低级烷氧基，其中表示苯基或萘基，R11表示氢，低级烷基，卤素，氨基，未取代或被烷基取代的低级烷氧基 具有1至4个碳原子的硝基或硝基，或其中R 12表示低级烷基的“IMAGE”，或其中R 13表示氢，低级烷基，卤素，羟基，三氟甲基 硝基，未取代或被取代的氨基 具有1〜4个碳原子的烷基或酰胺基。 这些染料在近红外区域吸收并产生具有显色剂的彩色图像，具有优异的保存性。

公开(公告)号：US5556733A

公开(公告)日：1996-09-17

申请号：US205565

申请日：1994-03-04

申请人： Shigeru Kusakata ,  Masanori Rimoto

发明人： Shigeru Kusakata ,  Masanori Rimoto

IPC分类号： B41M5/323 ,  G03C1/52 ,  G03C1/60 ,  G03C1/61 ,  G03C5/18 ,  G03F7/021

CPC分类号： G03C1/52

摘要： A thermal development diazo copying material is composed of a support, a diazo layer which contains a diazo compound, and a coupler layer which contains a coupling component, an alkali-soluble resin and a thermofusible material, which are overlaid on the support.

摘要翻译： 热显影重氮复制材料由载体，含有重氮化合物的重氮层和包含重叠在载体上的偶联组分，碱溶性树脂和热熔性材料的成色剂层组成。

公开(公告)号：US4847385A

公开(公告)日：1989-07-11

申请号：US31374

申请日：1987-03-30

申请人： Shigeru Kusakata ,  Aimi Suzuki ,  Isao Shiojima

发明人： Shigeru Kusakata ,  Aimi Suzuki ,  Isao Shiojima

IPC分类号： G11B7/247

CPC分类号： G11B7/2472 ,  G11B7/2531 ,  G11B7/2532 ,  G11B7/2533 ,  Y10T428/2457 ,  Y10T428/24835

摘要： A cyanine dye having formula (I): ##STR1## wherein R.sup.1 represents Cl, Br or hydrogen; R.sup.2 represents Cl, Br, hydrogen, or a nitro group; R.sup.3 and R.sup.4 each represent a methyl group, an ethyl group, a propyl group or --(CH.sub.2).sub.n OR.sup.5 (in which n is an integer of 2 or 3, and R.sup.5 represents hydrogen or an acetyl group), and X.sup..crclbar. represents an acid anion, provided that the case where R.sup.3 and R.sup.4 are both an identical alkyl group, and R.sup.1 and R.sup.2 are an identical group, is excluded; andan optical information recording medium including a recording layer comprising the above cyanine dye.

摘要翻译： 具有式（I）的花青染料：其中R 1表示Cl，Br或氢; R2表示Cl，Br，氢或硝基; R 3和R 4各自表示甲基，乙基，丙基或 - （CH 2）nOR 5（其中n为2或3的整数，R 5表示氢或乙酰基），X（ - ）表示 只要R3和R4都是相同的烷基，R1和R2是相同的基团的情况就被排除了; 以及包括含有上述花青染料的记录层的光学信息记录介质。

公开(公告)号：US07368007B2

公开(公告)日：2008-05-06

申请号：US10855377

申请日：2004-05-28

申请人： Shigeru Kusakata ,  Tsutomu Matsuda ,  Masashi Itoh ,  Mamoru Soga ,  Hidekazu Arase ,  Masaichiro Tatekawa

发明人： Shigeru Kusakata ,  Tsutomu Matsuda ,  Masashi Itoh ,  Mamoru Soga ,  Hidekazu Arase ,  Masaichiro Tatekawa

IPC分类号： C09D11/02

CPC分类号： C09D11/32 ,  C09D11/30

摘要： An ink-jet recording ink contains at least a colorant, a moisturizer, water and a water-soluble substance capable of undergoing polycondensation along with vaporization of the water, in which the colorant is a chelate azo dye.

摘要翻译： 喷墨记录油墨至少含有着色剂，保湿剂，水和能够与水蒸发一起进行缩聚的水溶性物质，其中着色剂是螯合偶氮染料。

公开(公告)号：US5691099A

公开(公告)日：1997-11-25

申请号：US529674

申请日：1995-09-18

申请人： Shigeru Kusakata ,  Masanori Rimoto ,  Kazuo Matsuda ,  Naohito Shimota

发明人： Shigeru Kusakata ,  Masanori Rimoto ,  Kazuo Matsuda ,  Naohito Shimota

IPC分类号： B41M5/323 ,  G03C1/52 ,  G03C1/60 ,  G03C1/61 ,  G03C1/76 ,  G03F7/021 ,  G03C5/18

CPC分类号： G03C1/52 ,  G03C1/60

摘要： The object of the present invention is to provide a novel and useful thermal developing type diazo copying material wherein an initial image quality and an initial image reliability are maintained, while undesired coloring can be avoided and long-term preservation characteristics can be improved. The present invention comprises a support, a photosensitive layer formed on said support, said photosensitive layer including a diazo compound, and a coupler layer formed on said support, said coupler layer including a coupler component, said coupler layer having a copolymer including a monomer having a carboxylic acid and water-soluble guanidine salt.

摘要翻译： 本发明的目的是提供一种新颖有用的热显影型重氮复制材料，其中保持初始图像质量和初始图像可靠性，同时可以避免不希望的着色，并且可以提高长期保存特性。 本发明包括载体，形成在所述载体上的感光层，所述感光层包括重氮化合物，以及形成在所述载体上的成色剂层，所述成色剂层包括成色剂组分，所述成色剂层具有共聚物， 羧酸和水溶性胍盐。

公开(公告)号：US5478689A

公开(公告)日：1995-12-26

申请号：US199024

申请日：1994-02-18

申请人： Masanori Rimoto ,  Shigeru Kusakata

发明人： Masanori Rimoto ,  Shigeru Kusakata

IPC分类号： B41M5/323 ,  B41M5/28 ,  B41M5/30 ,  G03C1/00 ,  G03C1/52 ,  G03C1/60 ,  G03C1/61 ,  G03C1/72

CPC分类号： G03C1/002 ,  G03C1/52

摘要： A thermal development diazo copying material is composed of a support, and a photosensitive layer formed thereon, which includes a diazo compound, a coupler, an alkali-soluble resin, and a sensitizer, with only the coupler being contained in microcapsules made of the alkali-soluble resin.

摘要翻译： 热显影重氮复印材料由支撑体和形成在其上的感光层组成，其包含重氮化合物，成色剂，碱溶性树脂和敏化剂，只有由碱形成的微胶囊中包含成色剂 - 可溶性树脂。