摘要:
There are provided a nonaqueous-type electrolyte solution having high flame retardancy and a good capacity retention rate, and a device comprising the nonaqueous-type electrolyte solution. The nonaqueous-type electrolyte solution is used in a device comprising a positive electrode, a negative electrode and the nonaqueous-type electrolyte solution, and contains a lithium salt and a compound having a phosphazene structure, and further contains 0.05% by mass or more and 12.0% by mass or less of at least one disulfonate ester selected from a cyclic disulfonate ester and a chain disulfonate ester based on the total of the nonaqueous-type electrolyte solution.
摘要:
An object of this invention is to provide a highly safe secondary battery employing a non-flammable electrolyte solution. The secondary battery has a positive pole comprising an oxide for storing and releasing lithium ions, a negative pole comprising a carbon material for storing and releasing lithium ions, and an electrolyte solution. The electrolyte solution comprises 1.5 mol/L or more of a lithium salt, or 1.0 mol/L or more of a lithium salt and 20% by volume or more of a phosphate ester derivative.
摘要:
An object of the present invention is to provide a gel electrolyte for a lithium ion secondary battery having flame retardancy over a long period and a good capacity maintenance rate. The gel electrolyte for a lithium ion secondary battery according to the exemplary embodiment contains a lithium salt, a copolymer of at least one first monomer selected from compounds represented by chemical formulae (1) and (2) and a second monomer represented by chemical formula (4), at least one oxo-acid ester derivative of phosphorus selected from compounds represented by chemical formulae (5) to (7), and at least one disulfonate ester selected from a cyclic-chain type disulfonate ester represented by chemical formula (8) and a linear-chain type disulfonate ester represented by chemical formula (9).
摘要:
A non-aqueous electrolyte can suppress decomposition of a solvent, improve the cycle life of a secondary battery, suppress the rise of resistance of a secondary battery and improve the capacity maintenance ratio of a secondary battery. A non-aqueous electrolyte secondary battery formed by using such a non-aqueous electrolyte includes a non-aqueous electrolyte containing an aprotic solvent and a disulfonic acid ester as expressed by chemical formula 1 shown below, a positive electrode and a negative electrode:
摘要:
A polymer gel electrolyte, comprising a polymer gel including an aprotic organic solvent, a carrier salt and a sulfur-containing organic compound having at least one —O—SO2— in its chemical structure, for instance, a straight-chain sulfonic acid ester or a cyclic sulfonic acid ester, and a lithium polymer secondary battery using the polymer gel electrolyte and having improved rate performance and cycle performance.
摘要:
There is provided a lithium ion battery having high flame retardancy and good cycle characteristics on a long-term basis. The lithium ion battery according to this exemplary embodiment is a lithium ion battery comprising a nonaqueous electrolytic solution or gel electrolyte containing a Li salt and an oxoacid ester derivative of phosphoric acid; a group of stacked electrode in which positive electrodes comprising a positive electrode layer comprising a positive electrode active material disposed on at least one surface of a positive electrode current collector, and negative electrodes comprising a negative electrode layer comprising a negative electrode active material disposed on at least one surface of a negative electrode current collector are alternately stacked via separators; and a package containing the nonaqueous electrolytic solution or gel electrolyte and the group of stacked electrode, wherein both of two electrodes A disposed on outermost sides of the group of stacked electrode, respectively, satisfy 0≦(Wc/Wb)≦0.55 when a mass of an electrode active material contained in an electrode active material-coated layer B disposed on a group-of-stacked-electrodes side of an electrode current collector is Wb, and a mass of an electrode active material contained in an electrode active material-coated layer C disposed on a package side of the electrode current collector is Wc.
摘要:
To provide high energy density, good cycle properties and rate characteristics and long-term safety of a lithium ion battery containing at least an ionic liquid and a lithium salt. The above problems are solved by suppressing reduction and decomposition of the ionic liquid on an anode by using a graphite coated with an amorphous carbon or onto which an amorphous carbon is deposited as an anode active material.
摘要:
The exemplary embodiment has an object to provide a nonaqueous electrolyte solution having a flame retardancy over a long period and having a good capacity maintenance rate. The exemplary embodiment is a nonaqueous electrolyte solution containing a lithium salt, at least one oxo-acid ester derivative of phosphorus selected from compounds represented by a predetermined formula, and at least one disulfonate ester selected from a cyclic disulfonate ester and a linear disulfonate ester represented by the predetermined formulae.
摘要:
There are provided a nonaqueous-type electrolyte solution having high flame retardancy and a good capacity retention rate, and a device comprising the nonaqueous-type electrolyte solution. The nonaqueous-type electrolyte solution is used in a device comprising a positive electrode, a negative electrode and the nonaqueous-type electrolyte solution, and contains a lithium salt and a compound having a phosphazene structure, and further contains 0.05% by mass or more and 12.0% by mass or less of at least one disulfonate ester selected from a cyclic disulfonate ester and a chain disulfonate ester based on the total of the nonaqueous-type electrolyte solution.
摘要:
There is provided a lithium ion battery which maintains the flame retardancy of an electrolyte over a long period of time, has high energy density, and has improved charge/discharge cycle characteristics, high temperature storage characteristics, and rate characteristics. The lithium ion battery according to the present exemplary embodiment is a lithium ion battery comprising an electrolyte containing at least an ionic liquid and a lithium salt, a positive electrode, and a negative electrode, wherein the negative electrode includes a negative electrode active material which is a carbon material treated with a surface treatment agent.