公开(公告)号：US08802800B2

公开(公告)日：2014-08-12

申请号：US13392698

申请日：2010-08-30

申请人： Shinichi Fujino ,  Kozo Nogi ,  Kunihiko Ishizaki

发明人： Shinichi Fujino ,  Kozo Nogi ,  Kunihiko Ishizaki

IPC分类号： C08F2/00 ,  C08F20/06

CPC分类号： C08J3/12 ,  C08J3/245 ,  C08J2300/14 ,  C08J2333/02

摘要： A production method for a water-absorbent resin, comprising a polymerization step for obtaining hydrogel by subjecting a monomer aqueous solution to a polymerization reaction, and a drying step for drying the hydrogel, wherein drying in the drying step is performed using a continuous through-flow belt-type drying machine, the pore opening rate of the through-flow belt in the continuous through-flow belt-type drying machine is 20 to 50%, the solid content of the hydrogel supplied to the drying step is 35% by weight or more, and the area occupancy rate of the hydrogel is 85 to 100% relative to the through-flow belt.

摘要翻译： 一种吸水性树脂的制造方法，其特征在于，包括通过使单体水溶液进行聚合反应而得到水凝胶的聚合工序和干燥水凝胶的干燥工序，干燥工序中的干燥是使用连续通孔 流式带式干燥机，连续通流式带式干燥机中通流带的开孔率为20〜50％，供给干燥工序的水凝胶的固体成分为35重量％ 以上，相对于贯流带，水凝胶的面积占有率为85〜100％。

公开(公告)号：US20130123435A1

公开(公告)日：2013-05-16

申请号：US13635045

申请日：2011-03-17

申请人： Sumio Okuda ,  Syuji Kanzaki ,  Kunihiko Ishizaki ,  Shinichi Fujino ,  Kozo Nogi

发明人： Sumio Okuda ,  Syuji Kanzaki ,  Kunihiko Ishizaki ,  Shinichi Fujino ,  Kozo Nogi

IPC分类号： C08J3/24

CPC分类号： C08F120/06 ,  B07B1/28 ,  B07B1/54 ,  B07B1/56 ,  B07B13/16 ,  C08F6/008 ,  C08F220/06 ,  C08J3/24 ,  C08J3/245 ,  C08J2300/14 ,  G01N15/0272 ,  G01N2015/0277 ,  G01N2015/0288

摘要： Provided is a method which does not require alteration of the raw materials or high capital investment, and improves and stabilizes the physical property (for example, liquid permeability) of a water absorbent resin by means of a simple technique. A method for producing a water absorbent resin is disclosed, which method includes a polymerization step of polymerizing an aqueous solution of acrylic acid (salt) to obtain a water-containing gel-like crosslinked polymer; a drying step of drying the water-containing gel-like crosslinked polymer to obtain a water absorbent resin powder; a classification step of classifying the water absorbent resin powder; and a surface crosslinking step of surface crosslinking the water absorbent resin powder, wherein in the classification steps that are carried before the surface crosslinking step and/or after the surface crosslinking step, the stretch tension (tension) of the metal sieve mesh used in the classification step is from 35 [N/cm] to 100 [N/cm].

摘要翻译： 提供了不需要改变原材料或高资本投资的方法，并且通过简单的技术提高和稳定吸水性树脂的物理性能（例如，透液性）。 公开了一种吸水性树脂的制造方法，该方法包括聚合丙烯酸（盐）水溶液以获得含水凝胶状交联聚合物的聚合步骤; 干燥步骤，干燥含水凝胶状交联聚合物以获得吸水性树脂粉末; 吸水性树脂粉末的分类步骤; 和表面交联吸水性树脂粉末的表面交联步骤，其中在表面交联步骤之前和/或表面交联步骤之后承载的分级步骤中，所用的金属筛网的拉伸张力（张力） 分级步骤为35 [N / cm]至100 [N / cm]。

公开(公告)号：US20120157648A1

公开(公告)日：2012-06-21

申请号：US13392909

申请日：2010-08-30

申请人： Koji Matsumoto ,  Kozo Nogi ,  Shinichi Fujino ,  Yorimichi Dairoku ,  Kunihiko Ishizaki

发明人： Koji Matsumoto ,  Kozo Nogi ,  Shinichi Fujino ,  Yorimichi Dairoku ,  Kunihiko Ishizaki

IPC分类号： C08F220/06

CPC分类号： C08J3/12 ,  C08J3/245 ,  C08J2300/14 ,  C08J2333/02

摘要： [PROBLEM]It is an object of the present invention to efficiently obtain efficiently a water-absorbent resin having excellent property.[SOLUTION]A production method for a water-absorbent resin, comprising: a polymerization step for obtaining hydrogel by subjecting a monomer aqueous solution to a polymerization reaction; and a drying step for drying the hydrogel; wherein drying in the drying step is performed using a continuous through-flow belt-type drying machine; solid content of the hydrogel supplied to the drying step is 35% by weight or more, and thickness variation rate (1) represented by the following EXPRESSION 1 of the hydrogel loaded onto through-flow belt in the continuous through-flow belt, is 1.05 to 5: [MATH. 1] Thickness variation rate (1)=(Maximum thickness of hydrogel in a width direction of the through-flow belt)/(Average thickness of hydrogel in a width direction of the through-flow belt).  [EXPRESSION 1]

摘要翻译： 本发明的目的在于有效地获得具有优异性能的吸水性树脂。 [解决方案]一种吸水性树脂的制备方法，包括：通过使单体水溶液进行聚合反应获得水凝胶的聚合步骤; 和干燥步骤，用于干燥水凝胶; 其中干燥步骤中的干燥是使用连续的通流式带式干燥机进行的; 提供给干燥步骤的水凝胶的固体含量为35重量％以上，并且由连续贯流带中的贯流带上的水凝胶的以下表达式1表示的厚度变化率（1）为1.05 到5：[MATH。 1]厚度变化率（1）=（贯穿流动带的宽度方向的水凝胶的最大厚度）/（贯通带的宽度方向的水凝胶的平均厚度）。 [表达1]

公开(公告)号：US09453091B2

公开(公告)日：2016-09-27

申请号：US13635045

申请日：2011-03-17

申请人： Sumio Okuda ,  Syuji Kanzaki ,  Kunihiko Ishizaki ,  Shinichi Fujino ,  Kozo Nogi

发明人： Sumio Okuda ,  Syuji Kanzaki ,  Kunihiko Ishizaki ,  Shinichi Fujino ,  Kozo Nogi

IPC分类号： A61L15/24 ,  C08F120/06 ,  C08F220/06 ,  C08J3/24 ,  B07B1/56 ,  C08F6/00 ,  B07B13/16 ,  G01N15/02 ,  B07B1/28

CPC分类号： C08F120/06 ,  B07B1/28 ,  B07B1/54 ,  B07B1/56 ,  B07B13/16 ,  C08F6/008 ,  C08F220/06 ,  C08J3/24 ,  C08J3/245 ,  C08J2300/14 ,  G01N15/0272 ,  G01N2015/0277 ,  G01N2015/0288

摘要： A method for producing a water absorbent resin, the method including a polymerization step, a drying step, a classification step, and a surface crosslinking step. The classification step carried out before or after the surface crosslinking step requires use of a metal sieve mesh having stretch tension from 35 to 100 N/cm, in which an air jet cleaner or an air jet brush cleaner and plural tapping balls or tapping blocks are installed below the metal sieve mesh, a classification aid particle having specific gravity different from that of the water absorbent resin powder is added, and a fine powder of the water absorbent resin and the classification aid particle are removed.

摘要翻译： 一种吸水性树脂的制造方法，其包括聚合工序，干燥工序，分级工序以及表面交联工序。 在表面交联步骤之前或之后进行的分级步骤需要使用具有35至100N / cm的拉伸张力的金属筛网，其中空气喷射清洁器或空气喷射刷清洁器和多个敲击球或攻丝块是 在金属筛网的下方，添加比重与吸水性树脂粉末不同的分级助剂粒子，除去吸水性树脂和分级助剂粒子的细粉末。

公开(公告)号：US08809475B2

公开(公告)日：2014-08-19

申请号：US13392909

申请日：2010-08-30

申请人： Koji Matsumoto ,  Kozo Nogi ,  Shinichi Fujino ,  Yorimichi Dairoku ,  Kunihiko Ishizaki

发明人： Koji Matsumoto ,  Kozo Nogi ,  Shinichi Fujino ,  Yorimichi Dairoku ,  Kunihiko Ishizaki

IPC分类号： C08F2/00 ,  C08F20/06

CPC分类号： C08J3/12 ,  C08J3/245 ,  C08J2300/14 ,  C08J2333/02

摘要： A production method for a water-absorbent resin, comprising a polymerization step for obtaining hydrogel by subjecting a monomer aqueous solution to a polymerization reaction, and a drying step for drying the hydrogel, wherein drying in the drying step is performed using a continuous through-flow belt-type drying machine, the solid content of the hydrogel supplied to the drying step is 35% by weight or more, and thickness variation rate (1) represented by the following EXPRESSION 1 of the hydrogel loaded onto through-flow belt in the continuous through-flow belt, is 1.05 to 5: [MATH. 1] Thickness variation rate (1)=(Maximum thickness of hydrogel in a width direction of the through-flow belt)/(Average thickness of hydrogel in a width direction of the through-flow belt).  [EXPRESSION 1]

摘要翻译： 一种吸水性树脂的制造方法，其特征在于，包括通过使单体水溶液进行聚合反应而得到水凝胶的聚合工序和干燥水凝胶的干燥工序，干燥工序中的干燥是使用连续通孔 流动带式干燥机中，提供给干燥步骤的水凝胶的固体含量为35重量％以上，并且由下述表达式1表示的厚度变化率（1）表示为加载到通气带中的水凝胶 连续通流带，为1.05〜5：[MATH。 1]厚度变化率（1）=（贯穿流动带的宽度方向的水凝胶的最大厚度）/（贯通带的宽度方向的水凝胶的平均厚度）。 [表达1]

公开(公告)号：US20140114035A1

公开(公告)日：2014-04-24

申请号：US14112774

申请日：2012-04-20

申请人： Kozo Nogi ,  Syuji Kanzaki ,  Kunihiko Ishizaki ,  Shinichi Fujino ,  Satoshi Matsumoto

发明人： Kozo Nogi ,  Syuji Kanzaki ,  Kunihiko Ishizaki ,  Shinichi Fujino ,  Satoshi Matsumoto

IPC分类号： C08F2/18

CPC分类号： C08F2/18 ,  C08F220/06 ,  C08J3/12 ,  C08J2333/02

摘要： The purpose of the present invention is to provide a method for producing a water absorbent resin in which a water absorbent resin having excellent properties can be obtained effectively. The present invention relates to a method for producing a polyacrylic acid (salt)-based water absorbent resin, which includes a polymerization step of polymerizing an aqueous monomer solution containing a polymerization inhibitor, acrylic acid (salt) and an internal cross-linking agent to produce a water-containing gel-like cross-linked polymer, a gel-crushing step of performing the gel-crushing of the water-containing gel-like cross-linked polymer simultaneously with or subsequent to the polymerization to produce a particulate water-containing gel-like cross-linked polymer, and a drying step of supplying the particulate water-containing gel-like cross-linked polymer to a continuous through-flow belt-type dryer by a traverse conveyor to dry the particulate water-containing gel-like cross-linked polymer, in which the belt temperature of the traverse conveyor is 40 to 120° C. and/or the water soluble component in the particulate water-containing gel-like cross-linked polymer on the traverse conveyor is 10% by weight or less and the water soluble component is increased after the drying step.

摘要翻译： 本发明的目的是提供一种可以有效获得具有优异性能的吸水性树脂的吸水性树脂的制造方法。 本发明涉及一种聚丙烯酸（盐）系吸水性树脂的制造方法，其包括将含有聚合抑制剂，丙烯酸（盐）和内部交联剂的单体水溶液聚合的聚合工序， 产生含水凝胶状交联聚合物，在聚合反应或聚合后同时进行凝胶状破碎的凝胶状破碎工序，制成含水凝胶状交联聚合物 凝胶状交联聚合物，以及通过横动输送机将含粒状含水凝胶状交联聚合物供给到连续流通带式干燥机的干燥工序，干燥含水凝胶状的颗粒状凝胶状 横向传送带的带温度为40〜120℃的交联聚合物和/或该混合物中的颗粒状含水凝胶状交联聚合物中的水溶性成分 惰性输送机为10重量％以下，干燥后水溶性成分增加。

公开(公告)号：US09580519B2

公开(公告)日：2017-02-28

申请号：US14112774

申请日：2012-04-20

申请人： Kozo Nogi ,  Syuji Kanzaki ,  Kunihiko Ishizaki ,  Shinichi Fujino ,  Satoshi Matsumoto

发明人： Kozo Nogi ,  Syuji Kanzaki ,  Kunihiko Ishizaki ,  Shinichi Fujino ,  Satoshi Matsumoto

IPC分类号： H01B1/00 ,  C08F2/18 ,  C08F220/06 ,  C08J99/00 ,  C08J3/12

CPC分类号： C08F2/18 ,  C08F220/06 ,  C08J3/12 ,  C08J2333/02

摘要： The purpose of the present invention is to provide a method for producing a water absorbent resin in which a water absorbent resin having excellent properties can be obtained effectively. The present invention relates to a method for producing a polyacrylic acid (salt)-based water absorbent resin, which includes a polymerization step of polymerizing an aqueous monomer solution containing a polymerization inhibitor, acrylic acid (salt) and an internal cross-linking agent to produce a water-containing gel-like cross-linked polymer, a gel-crushing step of performing the gel-crushing of the water-containing gel-like cross-linked polymer simultaneously with or subsequent to the polymerization to produce a particulate water-containing gel-like cross-linked polymer, and a drying step of supplying the particulate water-containing gel-like cross-linked polymer to a continuous through-flow belt-type dryer by a traverse conveyor to dry the particulate water-containing gel-like cross-linked polymer, in which the belt temperature of the traverse conveyor is 40 to 120° C. and/or the water soluble component in the particulate water-containing gel-like cross-linked polymer on the traverse conveyor is 10% by weight or less and the water soluble component is increased after the drying step.

摘要翻译： 本发明的目的是提供一种可以有效获得具有优异性能的吸水性树脂的吸水性树脂的制造方法。 本发明涉及一种聚丙烯酸（盐）系吸水性树脂的制造方法，其包括将含有聚合抑制剂，丙烯酸（盐）和内部交联剂的单体水溶液聚合的聚合工序， 产生含水凝胶状交联聚合物，在聚合反应或聚合后同时进行凝胶状破碎的凝胶状破碎工序，制成含水凝胶状交联聚合物 凝胶状交联聚合物，以及通过横动输送机将含粒状含水凝胶状交联聚合物供给到连续流通带式干燥机的干燥工序，干燥含水凝胶状的颗粒状凝胶状 横向传送带的带温度为40〜120℃的交联聚合物和/或该混合物中的颗粒状含水凝胶状交联聚合物中的水溶性成分 惰性输送机为10重量％以下，干燥后水溶性成分增加。

公开(公告)号：US20130066019A1

公开(公告)日：2013-03-14

申请号：US13635055

申请日：2011-03-17

申请人： Sumio Okuda ,  Syuji Kanzaki ,  Kunihiko Ishizaki ,  Shinichi Fujino ,  Kozo Nogi

发明人： Sumio Okuda ,  Syuji Kanzaki ,  Kunihiko Ishizaki ,  Shinichi Fujino ,  Kozo Nogi

IPC分类号： C08F120/06

CPC分类号： C08F120/06 ,  B07B1/28 ,  B07B1/54 ,  B07B1/56 ,  B07B13/16 ,  C08F6/008 ,  C08F220/06 ,  C08J3/24 ,  C08J3/245 ,  C08J2300/14 ,  G01N15/0272 ,  G01N2015/0277 ,  G01N2015/0288

摘要： A method of enhancing and stabilizing the physical property (for example, liquid permeability) of a water absorbent resin by means of a simple technique without requiring any alteration of the raw materials or high capital investment, is provided.Disclosed is a method for producing a water absorbent resin, which includes a polymerization step of polymerizing an aqueous solution of acrylic acid (salt) to obtain a water-containing gel-like crosslinked polymer; a drying step of drying the water-containing gel-like crosslinked polymer, to obtain a water absorbent resin powder; a classification step of classifying the water absorbent resin powder; and a surface crosslinking step of surface crosslinking the water absorbent resin powder, wherein in the classification step that is carried out before the surface crosslinking step and/or after the surface crosslinking step, a tapping material is installed below the metal sieve mesh used in the classification step, and thereby classification is carried out.

摘要翻译： 提供了一种通过简单的技术来增强和稳定吸水性树脂的物理性能（例如透液性）的方法，而不需要任何改变原料或高资本投资。 公开了一种吸水性树脂的制造方法，其包括使丙烯酸（盐）的水溶液聚合以获得含水凝胶状交联聚合物的聚合步骤; 干燥含水凝胶状交联聚合物的干燥工序，得到吸水性树脂粉末; 吸水性树脂粉末的分类步骤; 以及表面交联吸水性树脂粉末的表面交联步骤，其中在表面交联步骤之前和/或表面交联步骤之后进行的分级步骤中，将攻丝材料安装在用于 分类步骤，从而进行分类。

公开(公告)号：US09624322B2

公开(公告)日：2017-04-18

申请号：US13635055

申请日：2011-03-17

申请人： Sumio Okuda ,  Syuji Kanzaki ,  Kunihiko Ishizaki ,  Shinichi Fujino ,  Kozo Nogi

发明人： Sumio Okuda ,  Syuji Kanzaki ,  Kunihiko Ishizaki ,  Shinichi Fujino ,  Kozo Nogi

IPC分类号： B07B1/56 ,  C08F120/06 ,  C08F220/06 ,  C08J3/24 ,  C08F6/00 ,  B07B1/54 ,  B07B13/16 ,  G01N15/02 ,  B07B1/28

CPC分类号： C08F120/06 ,  B07B1/28 ,  B07B1/54 ,  B07B1/56 ,  B07B13/16 ,  C08F6/008 ,  C08F220/06 ,  C08J3/24 ,  C08J3/245 ,  C08J2300/14 ,  G01N15/0272 ,  G01N2015/0277 ,  G01N2015/0288

摘要： A method for producing a water absorbent resin, the method including a polymerization step, a drying step, a classification step, and a surface crosslinking step. The classification step carried out before or after the surface crosslinking step requires use of a tapping material and a metal sieve mesh, in which the tapping material being heated at 40° C. to 100° C. is installed below the metal sieve mesh, and the metal sieve mesh has an area of 1 to 10 m2/sheet. The classification step further requires introducing a classification aid particle, which has a specific gravity different from that of the water absorbent resin, to the metal sieve mesh; and monitoring the presence or absence of damage to the metal sieve mesh.

公开(公告)号：US20120157644A1

公开(公告)日：2012-06-21

申请号：US13392698

申请日：2010-08-30

申请人： Shinichi Fujino ,  Kozo Nogi ,  Kunihiko Ishizaki

发明人： Shinichi Fujino ,  Kozo Nogi ,  Kunihiko Ishizaki

IPC分类号： C08F2/00 ,  C08F20/06

CPC分类号： C08J3/12 ,  C08J3/245 ,  C08J2300/14 ,  C08J2333/02

摘要： [PROBLEM]It is an object of the present invention to efficiently obtain efficiently a water-absorbent resin having excellent property.[SOLUTION]A production method for a water-absorbent resin, comprising: a polymerization step for obtaining hydrogel by subjecting a monomer aqueous solution to a polymerization reaction; and a drying step for drying the hydrogel; wherein drying in the drying step is performed using a continuous through-flow belt-type drying machine; pore opening rate of the through-flow belt in the continuous through-flow belt-type drying machine is 20 to 50%; solid content of the hydrogel supplied to the drying step is 35% by weight or more; and area occupancy rate of the hydrogel is 85 to 100% relative to the through-flow belt.

摘要翻译： 本发明的目的在于有效地获得具有优异性能的吸水性树脂。 [解决方案]一种吸水性树脂的制备方法，包括：通过使单体水溶液进行聚合反应获得水凝胶的聚合步骤; 和干燥步骤，用于干燥水凝胶; 其中干燥步骤中的干燥是使用连续的通流式带式干燥机进行的; 连续通流式带式干燥机中通流带的开孔率为20〜50％; 提供给干燥步骤的水凝胶的固体含量为35重量％以上; 水凝胶的面积占有率相对于贯流带为85〜100％。