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1.发明授权Process for catalytically producing monoalkylether of dihydric phenol compound 失效催化生产二羟基苯酚化合物单羟胺的方法
公开(公告)号：US5189225A
公开(公告)日：1993-02-23
申请号：US589612
申请日：1990-09-28
申请人： Shinichi Furusaki , Masaoki Matsuda , Muneki Saito , Yasushi Shiomi , Yasuo Nakamura , Michio Tobita
发明人： Shinichi Furusaki , Masaoki Matsuda , Muneki Saito , Yasushi Shiomi , Yasuo Nakamura , Michio Tobita
IPC分类号： C07C41/09
CPC分类号： C07C41/09
摘要： A monoalkylether of dihydric phenol compound is produced by bringing a feed gas comprising a mixture gas of a dihydric phenol compound with a monohydric alcohol compound into contact with an active catalyst component comprising at least one member selected from phosphorus compounds, and mixtures and reaction products of phosphorus compounds with boron compounds and carried on an inert solid carrier consisting of, for example, .alpha.-alumina, .gamma.-alumina, activated carbon or titania grains, and preferably having a pore volume of 0.1 ml/g or more and a specific surface area of 1 m.sup.2 /g or more, at a temperature of 200.degree. C. to 400.degree. C., and collecting the resultant reaction product from the reaction mixture.
摘要翻译： 通过将包含二元酚化合物与一元醇化合物的混合气体的进料气体与包含选自磷化合物中的至少一种的活性催化剂组分接触，制备二元酚化合物的单烷基醚，以及其混合物和反应产物 具有硼化合物的磷化合物并承载在由例如α-氧化铝，γ-氧化铝，活性炭或二氧化钛颗粒组成的惰性固体载体上，并且优选具有0.1ml / g以上的孔体积和比表面积 为1m 2 / g以上，在200〜400℃的温度下，从反应混合物中收集得到的反应产物。
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公开(公告)号：US5248835A
公开(公告)日：1993-09-28
申请号：US868962
申请日：1992-04-16
申请人： Yasushi Shiomi , Yasuo Nakamura , Takumi Manabe , Shinichi Furusaki , Masaoki Matsuda , Muneki Saito
发明人： Yasushi Shiomi , Yasuo Nakamura , Takumi Manabe , Shinichi Furusaki , Masaoki Matsuda , Muneki Saito
IPC分类号： B01J27/18 , B01J27/182 , B01J27/185 , C07C41/09
CPC分类号： B01J27/1806 , B01J27/182 , B01J27/1853 , C07C41/09
摘要： A monoalkylether of a dihydric phenol compound is produced at a high conversion and selectivity by catalytically dehydration reacting a dihydric phenol compound with a lower monohydric alcohol in the presence of a catalyst comprising at least one inorganic substance of the empirical formula (I):Al.sub.a P.sub.b Ti.sub.c Si.sub.d X.sub.e O.sub.f (I):wherein X is an alkali metal (Group Ia) atom, alkaline earth metal (Group IIa) atom or a metal atom of Group VIII of the Periodic Table, a, b, c, d, e and f are the numbers of Al, P, Ti, Si, X and O atoms respectively, and provided that a =1, b =1.0 to 1.9, c =0 05 to 0.5, d=0.05 to 0.2, e=0 to 0.9 and f=4.2 to 8.1, and collecting the resultant reaction product from the reaction system.
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公开(公告)号：US5710349A
公开(公告)日：1998-01-20
申请号：US448488
申请日：1995-06-05
IPC分类号： B01J23/745 , B01J23/80 , B01J35/00 , C07C29/149
CPC分类号： C07C29/149 , B01J23/745 , B01J23/80 , B01J35/0006
摘要： In the process of the present invention for producing diol compounds by esterifying a carboxylic acid mixture collected from a reaction product mixture of a liquid phase oxidation of cyclohexane with air and hydrogenate-decomposing the resultant esterification product mixture with hydrogen, the hydrogenate-decomposition is carried out by using a combined catalyst which includes a catalyst (A) including, as principal components, copper oxide and zinc oxide and a catalyst (B) including copper oxide and iron oxide carried on aluminum oxide, does not include chromium, has a high catalytic activity and can be easily separated by filtering, and the combined catalyst is collected from the hydrogenate-decomposition reaction product mixture by filtering it.
摘要翻译： PCT No.PCT / JP94 / 01664 Sec。 371日期：1995年6月5日 102（e）日期1995年6月5日PCT 1994年10月5日PCT PCT。 第WO95 / 10497号公报 日本1995年4月20日在本发明的制备二醇化合物的方法中，通过将从环己烷的液相氧化反应产物混合物中收集的羧酸混合物与空气酯化，并将所得酯化产物混合物用氢氢化分解， 氢化物分解通过使用包括以氧化铜和氧化锌为主要成分的催化剂（A）和在氧化铝上载有氧化铜和氧化铁的催化剂（B）的组合催化剂进行，不包括铬 ，具有高催化活性，可以通过过滤容易地分离，并且通过过滤从氢化物分解反应产物混合物中收集组合的催化剂。
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公开(公告)号：US4420633A
公开(公告)日：1983-12-13
申请号：US331614
申请日：1981-12-17
IPC分类号： C07C69/06 , B01J23/00 , B01J23/56 , B01J31/00 , B01J31/16 , C07B61/00 , C07C53/04 , C07C67/36
CPC分类号： C07C67/36
摘要： There is disclosed a novel process for the preparation of an ester of formic acid which comprises subjecting hydrogen, carbon monoxide and an ester of nitrous acid to a catalytic vapor phase reaction in the presence of a platinum group metal or a salt thereof. The product obtained by the process according to the present invention does not substantially contain water and free formic acid. The ester of formic acid formed by the process according to the present invention can be separated and purified in a simple manner, e.g., by conventional distillation procedure.
摘要翻译： 公开了一种制备甲酸酯的新方法，其包括在铂族金属或其盐存在下，使氢，一氧化碳和亚硝酸酯进行催化气相反应。 通过本发明的方法获得的产物基本上不含水和游离的甲酸。 通过本发明的方法形成的甲酸酯可以简单的方式分离和纯化，例如通过常规的蒸馏方法。
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公开(公告)号：US4453026A
公开(公告)日：1984-06-05
申请号：US459424
申请日：1983-01-19
IPC分类号： C07C31/20 , C07C29/149 , C07C29/80 , C07C203/00 , C07C29/136
CPC分类号： C07C29/149 , C07C201/04 , C07C29/80
摘要： There is disclosed a process for continuously preparing ethylene glycol, which comprises (1) a first step of contacting a gas containing carbon monoxide and an ester of nitrous acid with a solid catalyst of platinum group metal series in the gaseous phase thereby to obtain a product containing a diester of oxalic acid, (2) a second step of condensing the product of the first step thereby to separate a non-condensed gas containing nitrogen monoxide formed by the catalytic reaction of the first step from a condensed liquid containing the diester of oxalic acid, (3) a third step of contacting the non-condensed gas of the second step with a gas containing molecular oxygen and an alcohol, and recycling the resulting gas containing an ester of nitrous acid to the first step, (4) a fourth step of contacting the condensed liquid of the second step containing the diester of oxalic acid and hydrogen with a catalyst for hydrogenation in the gaseous phase thereby to obtain a product containing ethylene glycol, (5) a fifth step of distilling the product of the fourth step thereby to distill out the alcohol and to obtain ethylene glycol, and (6) a sixth step of recycling the alcohol of the fifth step as an alcohol source for the third step.
摘要翻译： 公开了连续制备乙二醇的方法，其包括（1）在气相中使含有一氧化碳和亚硝酸酯的气体与铂族金属系固体催化剂接触的第一步骤，从而获得产物 含有草酸二酯的方法，（2）将第一步骤的产物冷凝的第二步骤，由第一步骤的催化反应形成的含有一氧化氮的非冷凝气体与含有草酸二酯的冷凝液分离 酸，（3）使第二步骤的非冷凝气体与含有分子氧和醇的气体接触的第三步骤，并将产生的含有亚硝酸酯的气体再循环至第一步骤，（4）第四步骤 将含有草酸和氢的二酯的第二步骤的冷凝液与气相中的氢化催化剂接触的步骤，从而获得含有eth的产物 （5）第五步骤，蒸馏第四步骤的产物，从而蒸馏出醇并获得乙二醇;和（6）将第五步骤的醇再循环作为醇源的第六步骤， 第三步。
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公开(公告)号：US4229591A
公开(公告)日：1980-10-21
申请号：US938358
申请日：1978-08-31
摘要： A process for preparing a diester of oxalic acid which comprises bringing carbon monoxide into contact with an ester of nitrous acid or with an alcohol and a nitrogen oxide or a hydrate of the nitrogen oxide in the gaseous phase in the presence of a solid catalyst containing metallic palladium or a salt thereof, a gas containing molecular oxygen being introduced into the reaction system in cases where said nitrogen oxide or a hydrate of the nitrogen oxide requires molecular oxygen together with the alcohol to form an ester of nitrous acid.
摘要翻译： 一种制备草酸二酯的方法，其包括在含有金属的固体催化剂的存在下，使一氧化碳与亚硝酸的酯或醇和氮氧化物或氮氧化物的水合物在气相中接触， 钯或其盐，在所述氮氧化物或氮氧化物的水合物与醇一起需要分子氧以形成亚硝酸酯的情况下，将含有分子氧的气体引入反应体系。
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公开(公告)号：USRE31245E
公开(公告)日：1983-05-17
申请号：US293932
申请日：1981-08-18
申请人： Kozo Fujii , Keigo Nishihira , Masaoki Matsuda , Shinichiro Uchiumi , Kenji Nishimura, deceased
发明人： Kozo Fujii , Keigo Nishihira , Masaoki Matsuda , Shinichiro Uchiumi , Kenji Nishimura, deceased
摘要： A process for preparing a diester of oxalic acid which comprises bringing carbon monoxide into contact with an ester of nitrous acid or with an alcohol and a nitrogen oxide or a hydrate of the nitrogen oxide in the gaseous phase in the presence of a solid catalyst containing metallic palladium or a salt thereof, a gas containing molecular oxygen being introduced into the reaction system in cases where said nitrogen oxide or a hydrate of the nitrogen oxide requires molecular oxygen together with the alcohol to form an ester of nitrous acid.
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公开(公告)号：US4048197A
公开(公告)日：1977-09-13
申请号：US597789
申请日：1975-07-21
IPC分类号： C07C51/09 , C07C51/265 , C07C51/27 , C07C51/573 , C07C67/343 , C07D307/89
CPC分类号： C07C51/573 , C07C51/09 , C07C51/265 , C07C51/27 , C07C67/343
摘要： A process for separating and purifying biphenyltetracarboxylic dianhydride isomers from a mixture of these isomers by fractional crystallization in aliphatic acid anhydrides or acetone. The isomeric mixture is obtained by heating biphenyltetracarboxylic acids, optionally in the presence of an aliphatic acid anhydride. The biphenyltetracarboxylic acids are obtained by oxidizing coupling dimers of o-xylene or by hydrolyzing coupling dimers of dimethyl phthalate. 2,3,3',4'-biphenyltetracarboxylic acid dianhydride which can be isolated from the above mixture can be used to form polyimide.
摘要翻译： 通过在脂肪酸酐或丙酮中分级结晶从这些异构体的混合物中分离和纯化联苯四羧酸二酐异构体的方法。 异构体混合物通过加热联苯四羧酸，任选在脂族酸酐存在下获得。 联苯四羧酸是通过氧化邻二甲苯二聚体或通过水解邻苯二甲酸二甲酯的偶联二聚体得到的。 可从上述混合物中分离的2,3,3'，4'-联苯四羧酸二酐可用于形成聚酰亚胺。
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公开(公告)号：US4467109A
公开(公告)日：1984-08-21
申请号：US495460
申请日：1983-05-19
CPC分类号： C07C69/36
摘要： There is provided a process for the continuous preparation of a diester of oxalic acid, which comprises a first step of reacting carbon monoxide with an ester of nitrous acid in the gaseous phase; a second step of condensing the gaseous reaction mixture to separate a non-condensed gas from a condensed liquid containing the diester of oxalic acid; a third step of introducing the non-condensed gas of the second step to a regeneration column, thereby contacting it with a gas containing molecular oxygen and an alcohol, and recycling the resulting gas containing an ester of nitrous acid to the reactor of the first step; a fourth step of distilling out an alcohol containing a diester of carbonic acid formed as a by-product of the first step and obtaining a liquid diester of oxalic acid; and a fifth step of introducing the distillate of the fourth step to a hydrolysis column thereby hydrolyzing the diester of carbonic acid in the gas and recycling the alcohol as an alcohol source for the third step.
摘要翻译： 提供了一种用于连续制备草酸二酯的方法，其包括使一氧化碳与亚硝酸酯在气相中反应的第一步骤; 冷凝气态反应混合物以从含有草酸二酯的冷凝液分离非冷凝气体的第二步骤; 将第二步骤的非冷凝气体引入再生塔的第三步骤，由此使其与含有分子氧和醇的气体接触，并将产生的含有亚硝酸酯的气体再循环到第一步骤的反应器 ; 第四步骤，蒸馏出含有作为第一步副产物的碳酸二酯的醇，得到草酸的液体二酯; 以及第五步骤，将第四步骤的馏出物引入水解塔，由此使气体中的碳酸二酯水解并再循环醇作为第三步的醇源。
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公开(公告)号：US4461909A
公开(公告)日：1984-07-24
申请号：US495459
申请日：1983-05-19
CPC分类号： C07C69/36
摘要： There is provided a process for the continuous preparation of a diester of oxalic acid which comprises a first step of reacting carbon monoxide with an ester of nitrous acid in the gaseous phase; a second step of condensing the gaseous reaction mixture to separate a non-condensed gas from a condensed liquid containing the diester of oxalic acid; a third step of introducing the non-condensed gas of the second step to a regeneration column and thereby contacting it with a gas containing molecular oxygen and an alcohol to regenerate nitrogen monoxide in the non-condensed gas into an ester of nitrous acid so as to bring the concentration of nitrogen monoxide in the gas at the outlet of the column to a level of from 2 to 7% by volume; and a fourth step of recycling the gas of the third step containing the ester of nitrous acid and from 2 to 7% by volume of nitrogen monoxide to the reactor of the first step.
摘要翻译： 提供了一种用于连续制备草酸二酯的方法，该方法包括使一氧化碳与亚硝酸酯在气相中反应的第一步骤; 冷凝气态反应混合物以从含有草酸二酯的冷凝液分离非冷凝气体的第二步骤; 将第二步骤的非冷凝气体引入再生塔的第三步骤，由此使其与含有分子氧和醇的气体接触，以将非冷凝气体中的一氧化氮再生成亚硝酸酯，以便 使塔的出口处的气体中的一氧化氮浓度达到2〜7体积％的水平; 以及将含有亚硝酸酯和2〜7体积％一氧化氮的第三步骤的气体再循环到第一步骤的反应器的第四步骤。
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