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    Catalyst for decomposition of sulfur trioxide and hydrogen production process
    1.
    发明授权
    Catalyst for decomposition of sulfur trioxide and hydrogen production process 有权
    三氧化硫分解催化剂和氢气生产工艺

    公开(公告)号：US08940270B2

    公开(公告)日：2015-01-27

    申请号：US13997473

    申请日：2011-12-27

    申请人： Shinichi Takeshima ,  Masato Machida

    发明人： Shinichi Takeshima ,  Masato Machida

    IPC分类号： B01J23/847 ,  B01J23/26 ,  C01B3/06 ,  B01J23/22

    CPC分类号： B01J23/8472 ,  B01J23/22 ,  B01J23/26 ,  B01J29/0333 ,  B01J29/0341 ,  B01J35/002 ,  B01J35/1061 ,  B01J35/109 ,  B01J37/0201 ,  B01J37/0205 ,  B01J37/0242 ,  C01B3/068 ,  Y02A50/2348 ,  Y02E60/36

    摘要： To provide a sulfur trioxide decomposition catalyst, particularly, a sulfur trioxide decomposition catalyst capable of lowering the temperature required when producing hydrogen by an S—I cycle process.A sulfur trioxide decomposition catalyst comprising a composite oxide of vanadium and at least one metal selected from the group consisting of transition metal and rare earth elements is provided. Also, a sulfur dioxide production process comprising decomposing sulfur trioxide into sulfur dioxide and oxygen by using the sulfur trioxide decomposition catalyst above, is provided. Furthermore, a hydrogen production process, wherein the reaction of decomposing sulfur trioxide into sulfur dioxide and oxygen by an S—I cycle process is performed by the above-described sulfur dioxide production process, is provided.

    摘要翻译： 提供一种三氧化硫分解催化剂，特别是能够降低通过S-I循环过程产生氢气所需的温度的三氧化硫分解催化剂。 提供了包含钒和选自过渡金属和稀土元素中的至少一种金属的复合氧化物的三氧化硫分解催化剂。 此外，还提供了通过使用上述三氧化硫分解催化剂将三氧化硫分解成二氧化硫和氧气的二氧化硫生产方法。 另外，通过上述二氧化硫的制造方法进行氢过程，其中通过S-I循环过程将三氧化硫分解成二氧化硫和氧的反应进行。

    CATALYST FOR DECOMPOSITION OF SULFUR TRIOXIDE AND HYDROGEN PRODUCTION PROCESS
    2.
    发明申请
    CATALYST FOR DECOMPOSITION OF SULFUR TRIOXIDE AND HYDROGEN PRODUCTION PROCESS 有权
    用于分解三氧化硫和氢生产过程的催化剂

    公开(公告)号：US20130280159A1

    公开(公告)日：2013-10-24

    申请号：US13997473

    申请日：2011-12-27

    申请人： Shinichi Takeshima ,  Masato Machida

    发明人： Shinichi Takeshima ,  Masato Machida

    IPC分类号： B01J23/847 ,  B01J23/26 ,  C01B3/06 ,  B01J23/22

    CPC分类号： B01J23/8472 ,  B01J23/22 ,  B01J23/26 ,  B01J29/0333 ,  B01J29/0341 ,  B01J35/002 ,  B01J35/1061 ,  B01J35/109 ,  B01J37/0201 ,  B01J37/0205 ,  B01J37/0242 ,  C01B3/068 ,  Y02A50/2348 ,  Y02E60/36

    摘要： To provide a sulfur trioxide decomposition catalyst, particularly, a sulfur trioxide decomposition catalyst capable of lowering the temperature required when producing hydrogen by an S—I cycle process.A sulfur trioxide decomposition catalyst comprising a composite oxide of vanadium and at least one metal selected from the group consisting of transition metal and rare earth elements is provided. Also, a sulfur dioxide production process comprising decomposing sulfur trioxide into sulfur dioxide and oxygen by using the sulfur trioxide decomposition catalyst above, is provided. Furthermore, a hydrogen production process, wherein the reaction of decomposing sulfur trioxide into sulfur dioxide and oxygen by an S—I cycle process is performed by the above-described sulfur dioxide production process, is provided.

    摘要翻译： 提供一种三氧化硫分解催化剂，特别是能够降低通过S-I循环过程产生氢气所需的温度的三氧化硫分解催化剂。 提供了包含钒和选自过渡金属和稀土元素中的至少一种金属的复合氧化物的三氧化硫分解催化剂。 此外，还提供了通过使用上述三氧化硫分解催化剂将三氧化硫分解成二氧化硫和氧气的二氧化硫生产方法。 另外，通过上述二氧化硫的制造方法进行氢过程，其中通过S-I循环过程将三氧化硫分解成二氧化硫和氧的反应进行。

    AMMONIA SYNTHESIS METHOD
    5.
    发明申请
    AMMONIA SYNTHESIS METHOD 有权
    氨基酸合成方法

    公开(公告)号：US20160152483A1

    公开(公告)日：2016-06-02

    申请号：US14905355

    申请日：2013-08-08

    申请人： Shinichi TAKESHIMA

    发明人： Shinichi Takeshima

    IPC分类号： C01C1/04 ,  C01B3/04 ,  C01B3/02

    CPC分类号： C01C1/04 ,  C01B3/025 ,  C01B3/042 ,  C01C1/0405 ,  Y02E60/364 ,  Y02P20/134 ,  Y02P20/52

    摘要： According to the present invention there is provided an ammonia synthesis method using solar thermal energy, whereby it is possible to minimize the load of collecting solar thermal energy, and especially high-temperature solar thermal energy. The method of the present invention for synthesis of ammonia using solar thermal energy includes the following steps (a) to (c): (a) conducting ammonia synthesis reaction in which nitrogen and hydrogen are reacted to synthesize ammonia, (b) heating a heating medium by solar thermal energy and the reaction heat energy of the ammonia synthesis reaction, and (c) conducting at least part of the water splitting reaction in which water is split into hydrogen and oxygen, using the thermal energy of the heated heating medium, to obtain the hydrogen.

    摘要翻译： 根据本发明，提供了一种使用太阳能热能的氨合成方法，由此可以最小化收集太阳能热能的负荷，特别是高温太阳能热能。 本发明使用太阳能热能合成氨的方法包括以下步骤（a）至（c）：（a）进行氨合成反应，其中使氮和氢反应合成氨，（b）加热 介质由太阳热能和氨合成反应的反应热能，以及（c）使用加热的加热介质的热能将水分解成氢和氧的至少一部分水分解反应进行至 获得氢气。

    HYDROGEN PRODUCTION PROCESS
    6.
    发明申请
    HYDROGEN PRODUCTION PROCESS 有权
    氢生产过程

    公开(公告)号：US20130330269A1

    公开(公告)日：2013-12-12

    申请号：US13996147

    申请日：2011-12-07

    申请人： Shinichi Takeshima ,  Norihiko Nakamura

    发明人： Shinichi Takeshima ,  Norihiko Nakamura

    IPC分类号： C01B3/06

    CPC分类号： C01B3/068 ,  C01B17/502 ,  C01B17/503 ,  Y02E60/36 ,  Y02P20/134

    摘要： A method for producing hydrogen from water is provided. The hydrogen production process includes splitting water into hydrogen and oxygen, wherein the process includes decomposing sulfuric acid into water, sulfur dioxide and oxygen through a reaction of formula (X1) by using solar thermal energy, wherein at least a part of the elementary reaction of formula (X1-1) is performed using thermal solar energy, and at least a part of the elementary reaction of formula (X1-2) is performed using additional thermal energy other than solar thermal energy, and wherein the heating temperature by the additional thermal energy is higher by 10° C. or more than the heating temperature by the solar thermal energy, and at least a part of the additional thermal energy is generated in a reaction vessel: (X1) H2SO4→H2O+SO2+1/2O2, (X1−1) H2SO4→H2O+SO3, and (X1−2) SO3→SO2+1/2O2

    摘要翻译： 提供了一种从水中生产氢的方法。 氢气生产过程包括将水分解成氢气和氧气，其中该方法包括通过使用太阳能热能将式（X 1）的反应将硫酸分解成水，二氧化硫和氧，其中至少一部分基本反应为 使用热太阳能进行式（X1-1），并且使用除了太阳能热能之外的附加热能进行式（X1-2）的至少一部分元素反应，并且其中通过附加热量的加热温度 能量通过太阳能热能高于加热温度10℃或更高，并且在反应容器中产生至少一部分附加热能：（X1）H 2 SO 4→H 2 O + SO 2 + 1 / 2O 2 ，（X1-1）H2SO4-> H2O + SO3，（X1-2）SO3-> SO2 + 1 / 2O2

    Method for glycosylating and separating plant fiber material
    7.
    发明授权
    Method for glycosylating and separating plant fiber material 有权
    糖基化和分离植物纤维材料的方法

    公开(公告)号：US08409356B2

    公开(公告)日：2013-04-02

    申请号：US12995784

    申请日：2009-06-02

    申请人： Shinichi Takeshima ,  Takeshi Kikuchi

    发明人： Shinichi Takeshima ,  Takeshi Kikuchi

    IPC分类号： C13K1/02

    CPC分类号： C13K1/02

    摘要： The invention relates to a method for hydrolyzing the plant fiber material to produce and separate a saccharide including glucose. The method includes a hydrolysis process of hydrolyzing cellulose contained in the plant fiber material and producing glucose in a first organic solvent having a cluster acid catalyst dissolved therein.

    摘要翻译： 本发明涉及水解植物纤维材料以产生和分离包含葡萄糖的糖的方法。 该方法包括水解含有植物纤维材料中的纤维素并在其中溶解有簇酸催化剂的第一有机溶剂中产生葡萄糖的水解方法。

    PRETREATMENT METHOD FOR SACCHARIFICATION OF PLANT FIBER MATERIAL AND SACCHARIFICATION METHOD
    8.
    发明申请
    PRETREATMENT METHOD FOR SACCHARIFICATION OF PLANT FIBER MATERIAL AND SACCHARIFICATION METHOD 有权
    植物纤维材料和分类方法的预处理方法

    公开(公告)号：US20110315138A1

    公开(公告)日：2011-12-29

    申请号：US13254252

    申请日：2010-03-08

    申请人： Shinichi Takeshima ,  Takeshi Kikuchi

    发明人： Shinichi Takeshima ,  Takeshi Kikuchi

    IPC分类号： C13K1/02

    CPC分类号： C13K1/02 ,  C13K1/04

    摘要： A pretreatment method for saccharification of plant fiber materials includes: immersing the plant fiber material in a solution that contains an organic solvent, in which a cluster acid is dissolved, prior to saccharifying cellulose contained in the plant fiber material; and distilling off the organic solvent from the immersed plant fiber material to obtain a pretreated mixture that contains the cluster acid and the pretreated plant fiber material.

    摘要翻译： 用于植物纤维材料糖化的预处理方法包括：在将含有植物纤维材料的纤维素糖化之前，将植物纤维材料浸渍在含有簇酸溶解的有机溶剂的溶液中; 并从浸渍的植物纤维材料中蒸除有机溶剂，得到含有簇酸和预处理的植物纤维材料的预处理混合物。

    METHOD FOR GLYCOSYLATING AND SEPARATING PLANT FIBER MATERIAL
    9.
    发明申请
    METHOD FOR GLYCOSYLATING AND SEPARATING PLANT FIBER MATERIAL 有权
    用于糖化和分离植物纤维材料的方法

    公开(公告)号：US20110105744A1

    公开(公告)日：2011-05-05

    申请号：US12995809

    申请日：2009-06-02

    申请人： Shinichi Takeshima ,  Takeshi Kikuchi

    发明人： Shinichi Takeshima ,  Takeshi Kikuchi

    IPC分类号： C07H1/08

    CPC分类号： C13K1/02

    摘要： The invention relates to a method for hydrolyzing a plant fiber material and producing and separating a saccharide including glucose. The method of the invention includes a hydrolysis process of using a cluster acid catalyst in a pseudo-molten state to hydrolyze cellulose contained in the plant fiber material and produce glucose. In the hydrolysis process, the cluster acid catalyst and a first amount of the plant fiber material that increases a viscosity of the cluster acid catalyst in a pseudo-molten state when added to the cluster acid catalyst in a pseudo-molten state are heated and mixed, and a second amount of the plant fiber material is then further added when the decrease in viscosity of the heated mixture occurs.

    摘要翻译： 本发明涉及水解植物纤维材料并生产和分离包括葡萄糖的糖类的方法。 本发明的方法包括使用假熔融状态的簇酸催化剂水解纤维素中所含的纤维素并产生葡萄糖的水解方法。 在水解过程中，将加入到熔融状态的聚氨酯催化剂中的模拟熔融状态下的聚氨酯酸催化剂的粘度增加的簇酸催化剂和第一量的植物纤维材料加热混合 然后当加热的混合物的粘度降低时，进一步添加第二量的植物纤维材料。

    COMPOUND OXIDE MANUFACTURING METHOD
    10.
    发明申请
    COMPOUND OXIDE MANUFACTURING METHOD 有权
    化合物制造方法

    公开(公告)号：US20090324474A1

    公开(公告)日：2009-12-31

    申请号：US12309844

    申请日：2007-08-29

    申请人： Shinichi Takeshima ,  Akio Koyama

    发明人： Shinichi Takeshima ,  Akio Koyama

    IPC分类号： C01F17/00

    CPC分类号： B01J35/0013 ,  B01D53/945 ,  B01J23/002 ,  B01J23/10 ,  B01J37/03 ,  B01J37/033 ,  B01J2523/00 ,  C01G1/02 ,  C01G25/00 ,  C01G25/02 ,  C01P2004/04 ,  C01P2004/50 ,  C01P2004/82 ,  C01P2006/12 ,  C01P2006/32 ,  Y02T10/22 ,  B01J2523/3725 ,  B01J2523/48

    摘要： A compound oxide manufacturing method includes: dispersing micelles, in each of which an aqueous phase is formed, in an oil phase; producing primary particles of a precursor of compound oxide in the aqueous phases in the micelles; synthesizing secondary particles by causing the primary particles to aggregate; and causing the secondary particles to aggregate by breaking the dispersion state of the micelles, or by causing the micelles to coalesce. In particular, polarization is produced in each of the micelles with the use of a cation having an ionic radius larger than that of a metal ion at least when the secondary particles are synthesized in the micelles.

    摘要翻译： 复合氧化物的制造方法包括：在油相中分散各自形成水相的胶束; 在胶束中的水相中产生复合氧化物前体的初级颗粒; 通过使一次粒子聚集合成二次粒子; 并通过破坏胶束的分散状态或通过使胶束聚结而使二次粒子聚集。 特别地，至少当二次粒子在胶束中合成时，使用离子半径大于金属离子半径的阳离子，在每个胶束中产生极化。