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公开(公告)号：US09884770B2
公开(公告)日：2018-02-06
申请号：US14905355
申请日：2013-08-08
Applicant: Shinichi Takeshima
Inventor： Shinichi Takeshima
CPC classification number: C01C1/04 , C01B3/025 , C01B3/042 , C01C1/0405 , Y02E60/364 , Y02P20/134 , Y02P20/52
Abstract: According to the present invention there is provided an ammonia synthesis method using solar thermal energy, whereby it is possible to minimize the load of collecting solar thermal energy, and especially high-temperature solar thermal energy. The method of the present invention for synthesis of ammonia using solar thermal energy includes the following steps (a) to (c): (a) conducting ammonia synthesis reaction in which nitrogen and hydrogen are reacted to synthesize ammonia, (b) heating a heating medium by solar thermal energy and the reaction heat energy of the ammonia synthesis reaction, and (c) conducting at least part of the water splitting reaction in which water is split into hydrogen and oxygen, using the thermal energy of the heated heating medium, to obtain the hydrogen.
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公开(公告)号：US09381496B2
公开(公告)日：2016-07-05
申请号：US12673021
申请日：2009-03-18
Applicant: Shinichi Takeshima , Toru Sasatani
Inventor： Shinichi Takeshima , Toru Sasatani
CPC classification number: B01J23/10 , B01D53/9422 , B01D2255/2065 , B01D2255/20707 , B01D2255/20738 , B01D2255/2092 , B01D2255/91 , B01D2255/9202 , B01J21/04 , B01J23/745 , B01J35/0013 , B01J35/006 , B01J37/0207 , B01J37/0211 , B01J37/031
Abstract: A nanoparticle carrying method making a carrier adsorb ammonium ions, making the nanoparticles adsorb an organic acid, and making the carrier and the nanoparticles contact each other in a basic solution to thereby cause the carrier to adsorb the nanoparticles. Nanoparticles can be carried in high dispersion irrespective of superhydrophilicity.
Abstract translation: 使载体吸附铵离子的纳米颗粒携带方法，使得纳米颗粒吸附有机酸，并使载体和纳米颗粒在碱性溶液中相互接触，从而使载体吸附纳米颗粒。 无论超亲水性如何，纳米颗粒都可以承载高分散体。
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3.发明申请公开(公告)号：US20130280159A1
公开(公告)日：2013-10-24
申请号：US13997473
申请日：2011-12-27
Applicant: Shinichi Takeshima , Masato Machida
Inventor： Shinichi Takeshima , Masato Machida
IPC: B01J23/847 , B01J23/26 , C01B3/06 , B01J23/22
CPC classification number: B01J23/8472 , B01J23/22 , B01J23/26 , B01J29/0333 , B01J29/0341 , B01J35/002 , B01J35/1061 , B01J35/109 , B01J37/0201 , B01J37/0205 , B01J37/0242 , C01B3/068 , Y02A50/2348 , Y02E60/36
Abstract: To provide a sulfur trioxide decomposition catalyst, particularly, a sulfur trioxide decomposition catalyst capable of lowering the temperature required when producing hydrogen by an S—I cycle process.A sulfur trioxide decomposition catalyst comprising a composite oxide of vanadium and at least one metal selected from the group consisting of transition metal and rare earth elements is provided. Also, a sulfur dioxide production process comprising decomposing sulfur trioxide into sulfur dioxide and oxygen by using the sulfur trioxide decomposition catalyst above, is provided. Furthermore, a hydrogen production process, wherein the reaction of decomposing sulfur trioxide into sulfur dioxide and oxygen by an S—I cycle process is performed by the above-described sulfur dioxide production process, is provided.
Abstract translation: 提供一种三氧化硫分解催化剂，特别是能够降低通过S-I循环过程产生氢气所需的温度的三氧化硫分解催化剂。 提供了包含钒和选自过渡金属和稀土元素中的至少一种金属的复合氧化物的三氧化硫分解催化剂。 此外，还提供了通过使用上述三氧化硫分解催化剂将三氧化硫分解成二氧化硫和氧气的二氧化硫生产方法。 另外，通过上述二氧化硫的制造方法进行氢过程，其中通过S-I循环过程将三氧化硫分解成二氧化硫和氧的反应进行。
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4.发明授权Redox material for thermochemical water splitting, and method for producing hydrogen 有权用于热化学水分解的氧化还原材料，以及生产氢的方法公开(公告)号：US08435486B2
公开(公告)日：2013-05-07
申请号：US12785938
申请日：2010-05-24
Applicant: Shinichi Takeshima
Inventor： Shinichi Takeshima
CPC classification number: C01B3/042 , B01J21/08 , B01J23/002 , B01J23/34 , B01J23/83 , B01J23/8892 , B01J29/0333 , B01J29/0341 , B01J37/0203 , B01J2523/00 , Y02E60/364 , B01J2523/3706 , B01J2523/72 , B01J2523/3712 , B01J2523/842
Abstract: An improved redox material able to be used for thermochemical water splitting, and a method for producing hydrogen using this redox material are provided. The redox material for thermochemical water splitting comprises a redox metal oxide selected from the group comprising perovskite-type composite metal oxides, fluorite-type composite metal oxides and combinations thereof, and a metal oxide carrier. The redox metal oxide is carried on the metal oxide carrier in a dispersed state. The method for producing hydrogen uses the oxidation and reduction of the redox material to decompose water into hydrogen and oxygen.
Abstract translation: 提供能够用于热化学水分解的改进的氧化还原材料，以及使用该氧化还原材料制造氢的方法。 用于热化学水分解的氧化还原材料包括选自钙钛矿型复合金属氧化物，萤石型复合金属氧化物及其组合的氧化还原金属氧化物和金属氧化物载体。 氧化还原金属氧化物以分散状态载持在金属氧化物载体上。 氢的制造方法使用氧化还原材料的氧化还原，将水分解成氢气和氧气。
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5.发明授权公开(公告)号：US08288310B2
公开(公告)日：2012-10-16
申请号：US12513171
申请日：2007-11-01
Applicant: Shinichi Takeshima , Akio Koyama
Inventor： Shinichi Takeshima , Akio Koyama
CPC classification number: B01D53/945 , B01D2255/1025 , B01D2255/20715 , B01J21/066 , B01J23/464 , B01J35/006 , B01J35/1014 , B01J37/0207 , B01J37/0211 , B01J37/08 , Y02A50/2324 , Y02T10/22
Abstract: An automobile exhaust gas purification catalyst comprised of a support mainly comprised of ZrO2 in which Rh is supported as a catalyst metal preventing sintering of the support, raising the supporting efficiency, and raising the low temperature activity and a method of production of the same are provided. An automobile exhaust gas purification catalyst comprised of a support mainly comprised of ZrO2, sintered under firing conditions where the as fired ZrO2 will substantially not be charged in a catalyst metal supporting treatment solution, in which Rh is supported as a catalyst metal in a particle state. The method of production includes a step of charging the support mainly comprised of ZrO2 fired under the above firing conditions by applying at least one treatment of an acid treatment and a base treatment and a step of dipping the charged state support in the catalyst supporting treatment solution including a colloid of Rh as the catalyst metal to make the Rh colloid be adsorbed on the support.
Abstract translation: 本发明提供一种汽车排气净化催化剂，其特征在于，主要由作为催化剂金属负载的作为催化剂金属的ZrO 2的载体，能够防止烧结烧结，提高支持效率，提高低温活性的载体及其制造方法 。 一种汽车废气净化催化剂，由主要由ZrO 2组成的载体组成，在烧成条件下烧结ZrO 2基本上不会在催化剂金属负载处理溶液中充电，其中Rh作为催化剂金属以粒子状态负载 。 该制造方法包括以下步骤：在上述烧成条件下，通过进行至少一种酸处理和碱处理的处理，以及将带电状态的载体浸渍在催化剂负载处理液中的步骤， 包括Rh的胶体作为催化剂金属，使Rh胶体吸附在载体上。
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Patent Agency Ranking
公开(公告)号：US20120148469A1
公开(公告)日：2012-06-14
申请号：US13399774
申请日：2012-02-17
Applicant: Shinichi TAKESHIMA , Kohei YOSHIDA , Akio KOYAMA
Inventor： Shinichi TAKESHIMA , Kohei YOSHIDA , Akio KOYAMA
CPC classification number: B01J21/066 , B01D53/9445 , B01J23/002 , B01J23/02 , B01J23/10 , B01J35/0013 , B01J35/023 , B01J35/1061 , B01J35/1066 , B01J35/108 , B01J37/03 , B01J2523/00 , B82Y30/00 , C01B13/328 , C01F17/0018 , C01G25/00 , C01G25/02 , C01P2004/50 , C01P2004/64 , C01P2006/13 , C01P2006/16 , Y02T10/22 , B01J2523/24 , B01J2523/48 , B01J2523/3712 , B01J2523/3706
Abstract: The present invention provides a porous composite oxide comprising an aggregate of secondary particles in the form of aggregates of primary particles of a composite oxide containing two or more types of metal elements, and having mesopores having a pore diameter of 2-100 nm between the secondary particles; wherein, the percentage of the mesopores between the secondary particles having a diameter of 10 nm or more is 10% or more of the total mesopore volume after firing for 5 hours at 600° C. in an oxygen atmosphere.
Abstract translation: 本发明提供一种多孔复合氧化物，其包含以二次或多种类型的金属元素为主成分的复合氧化物的一次粒子的聚集体形式的二次粒子的聚集体，并且在二次粒子的孔径为2〜100nm的介孔 粒子; 其中，直径为10nm以上的二次粒子之间的中孔的百分比在氧气氛中在600℃下焙烧5小时后的总中孔体积的10％以上。
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7.发明申请REDOX MATERIAL FOR THERMOCHEMICAL WATER SPLITTING, AND METHOD FOR PRODUCING HYDROGEN 有权用于热化学水分解的氧化还原材料，以及用于生产氢的方法公开(公告)号：US20110300064A1
公开(公告)日：2011-12-08
申请号：US12785938
申请日：2010-05-24
Applicant: Shinichi TAKESHIMA
Inventor： Shinichi TAKESHIMA
IPC: C01B3/08
CPC classification number: C01B3/042 , B01J21/08 , B01J23/002 , B01J23/34 , B01J23/83 , B01J23/8892 , B01J29/0333 , B01J29/0341 , B01J37/0203 , B01J2523/00 , Y02E60/364 , B01J2523/3706 , B01J2523/72 , B01J2523/3712 , B01J2523/842
Abstract: An improved redox material able to be used for thermochemical water splitting, and a method for producing hydrogen using this redox material are provided. The redox material for thermochemical water splitting comprises a redox metal oxide selected from the group comprising perovskite-type composite metal oxides, fluorite-type composite metal oxides and combinations thereof, and a metal oxide carrier. The redox metal oxide is carried on the metal oxide carrier in a dispersed state. The method for producing hydrogen uses the oxidation and reduction of the redox material to decompose water into hydrogen and oxygen.
Abstract translation: 提供能够用于热化学水分解的改进的氧化还原材料，以及使用该氧化还原材料制造氢的方法。 用于热化学水分解的氧化还原材料包括选自钙钛矿型复合金属氧化物，萤石型复合金属氧化物及其组合的氧化还原金属氧化物和金属氧化物载体。 氧化还原金属氧化物以分散状态载持在金属氧化物载体上。 氢的制造方法使用氧化还原材料的氧化还原，将水分解成氢气和氧气。
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公开(公告)号：US20110082291A1
公开(公告)日：2011-04-07
申请号：US12995756
申请日：2009-06-02
Applicant: Shinichi Takeshima , Takeshi Kikuchi
Inventor： Shinichi Takeshima , Takeshi Kikuchi
CPC classification number: C13K1/02
Abstract: The invention relates to a method for hydrolyzing a plant fiber material to produce and separate a saccharide including glucose. The method includes a hydrolysis process of using a cluster acid catalyst in a pseudo-molten state to hydrolyze cellulose contained in the plant fiber material, and produce glucose. The cluster acid catalyst is subjected to a clustering enhancing treatment by which clustering of the cluster acid catalyst in a crystalline state is enhanced.
Abstract translation: 本发明涉及一种用于水解植物纤维材料以产生和分离包括葡萄糖的糖的方法。 该方法包括使用假熔融状态的簇酸催化剂水解纤维素中所含的纤维素并产生葡萄糖的水解方法。 聚簇酸催化剂进行聚簇增强处理，通过该聚集增强处理，晶体状态的聚集酸催化剂的聚集得到增强。
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公开(公告)号：US07867943B2
公开(公告)日：2011-01-11
申请号：US11408987
申请日：2006-04-24
Applicant: Shinichi Takeshima
Inventor： Shinichi Takeshima
CPC classification number: B01D53/945 , B01D2255/1021 , B01D2255/206 , B01D2255/40 , B01J23/58 , B01J23/63 , B01J35/0006 , B01J37/0215 , B01J37/0248 , F01N3/28 , Y02T10/22
Abstract: An exhaust gas purifying catalyst which is made excellent in heat resistance and in S-resistance by keeping the catalytic activity of Pt particles in a satisfactory state. The exhaust gas purifying catalyst is made such that a coating layer containing a compound oxide of cerium and an oxide of a metal for stabilizing the oxide of said cerium and an oxide containing no cerium is formed on a substrate, and such that platinum particles are carried on the catalyst. Said compound oxide has a pore volume of 0.1 cc/g or more, and said platinum particles are selectively adsorbed at the electron accepting points on said compound oxide.
Abstract translation: 通过使Pt粒子的催化活性保持在令人满意的状态，耐热性和S电阻优异的废气净化催化剂。 废气净化催化剂被制成使得在基材上形成含有铈复合氧化物和用于稳定所述铈的氧化物的金属氧化物的涂层和不含铈的氧化物，并且使铂颗粒被携带 在催化剂上。 所述复合氧化物的孔体积为0.1cc / g以上，并且所述铂粒子选择性地吸附在所述复合氧化物的电子接受点。
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公开(公告)号：US20100126501A1
公开(公告)日：2010-05-27
申请号：US12597176
申请日：2008-04-25
Applicant: Shinichi Takeshima , Akio Koyama
Inventor： Shinichi Takeshima , Akio Koyama
IPC: C13K1/02
Abstract: Cellulose contained in plant fiber material is hydrolyzed with the use of a pseudo-molten cluster acid as a hydrolysis catalyst to produce saccharide, most of which is glucose. After the glucose is produced, the saccharide is precipitated with the use of an organic solvent, and the saccharide including a solidified saccharide during the hydrolysis and the precipitated saccharide is separated from residues and the cluster acid.
Abstract translation: 植物纤维材料中所含的纤维素通过使用假熔融簇酸作为水解催化剂水解，生成糖，其中大部分是葡萄糖。 葡萄糖生成后，使用有机溶剂使糖类沉淀，在水解过程中包含固化的糖类的糖类和析出的糖类与残基和簇酸分离。
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