Method for producing cycloalkanol and/or cycloalkanone
    9.
    发明授权
    Method for producing cycloalkanol and/or cycloalkanone 失效
    环烷醇和/或环烷酮的制备方法

    公开(公告)号:US07910777B2

    公开(公告)日:2011-03-22

    申请号:US12560788

    申请日:2009-09-16

    IPC分类号: C07C45/32 C07C35/18

    摘要: The present invention provides a method for producing cycloalkanol and/or cycloalkanone, which comprises reacting cycloalkane with molecular oxygen in the presence of mesoporous silica, (1) the mesoporous silica containing at least one transition metal; (2) the mesoporous silica having such pore distribution that the ratio of a total pore volume of mesoporous silica particles having a pore size of 3 to 50 nm to a total pore volume of mesoporous silica particles having a pore size of 2 to 50 nm is 50% or more; and (3) the mesoporous silica being modified by an organic silicon compound.

    摘要翻译: 本发明提供一种制备环烷醇和/或环烷酮的方法,其包括在介孔二氧化硅存在下使环烷烃与分子氧反应,(1)含有至少一种过渡金属的介孔二氧化硅; (2)具有孔分布的孔隙二氧化硅,孔径为3〜50nm的介孔二氧化硅粒子的总细孔容积与孔径为2〜50nm的介孔二氧化硅粒子的总孔体积的比为 50%以上; 和(3)介孔二氧化硅被有机硅化合物改性。