摘要:
A process for producing 1,1,1,2-tetrafluoroethane, which comprises reacting 2,2-dichloro-1,1,1,2-tetrafluoroethane, 2-chloro-1,1,1,2-tetrafluoroethane or a mixture thereof with hydrogen in the presence of a hydrogenation catalyst consisting essentially of a Group VIII element as the main component and at least one element selected from the group consisting of Group IB elements, lanthanum and lanthanide elements, as an additional component.
摘要:
A process for producing 1,1-dichloro-1,2,2,2-tetrafluoroethane, which comprises isomerizing 1,1,2-trichloro-1,2,2-trifluoroethane to form 1,1,1-trichloro-2,2,2-trifluoroethane, followed by fluorination with hydrofluoric acid.
摘要:
A process for producing a 2,2-difluoropropane of the following formula (2), which comprises fluorinating a chlorine-containing 2,2-halogenopropane of the following formula (1) by hydrogen fluoride or a fluorinating agent:C.sub.3 H.sub.a Cl.sub.b F.sub.c (1)C.sub.3 H.sub.a Cl.sub.b-x F.sub.c+x (2)wherein a, b, c and x are integers satisfying the following conditions:a.gtoreq.0, b.gtoreq.1, c.gtoreq.0, x.gtoreq.1, a+b+c=8.
摘要:
A hydrochlorofluoropropane azeotropic or azeotropic-like composition comprising at least two members selected from the group consisting of hydrochlorofluoropropanes of the formula I:CH.sub.a Cl.sub.b F.sub.c CF.sub.2 CH.sub.x Cl.sub.y F.sub.z (I)wherein a+b+c=3, x+y+z=3, a+x.gtoreq.1, b+y.gtoreq.1, and 0.ltoreq.a,b,c,x,y,z.ltoreq.3.
摘要翻译:一种氢氯氟丙烷共沸或共沸组合物,其包含选自式I的氢氯氟丙烷中的至少两种成员:CHaClbFcCF2CHxClyFz(I)其中a + b + c = 3,x + y + z = 3,a + x> / = 1,b + y> / = 1,0 = a,b,c,x,y,z 3。
摘要:
A process for producing a hydrogen-containing 2,2-difluoropropane of the following formula (2), which comprises subjecting a 2,2-difluoropropane of the following formula (1) to hydrogen reduction:C.sub.3 H.sub.a Cl.sub.b F.sub.c (1)C.sub.3 H.sub.a+x Cl.sub.b-y F.sub.c-z (2)wherein a, b, c, x, y and z are integers satisfying the following conditions:a.gtoreq.0, b.gtoreq.1, c.gtoreq.2, x.gtoreq.1, y.gtoreq.0, z.gtoreq.0, a+b+c=8, x=y+z b-y.gtoreq.0, and c-z.gtoreq.2.
摘要翻译:一种制备下式(2)的含氢2,2-二氟丙烷的方法,包括使下式(1)的2,2-二氟丙烷进行氢还原:C3HaClbFc(1)C3Ha + xClb-yFc -z(2)其中a,b,c,x,y和z是满足以下条件的整数:a> / = 0,b> / = 1,c> / = 2,x> / = 1,y> / = 0,z> / = 0,a + b + c = 8,x = y + z by> / = 0,cz> / = 2。
摘要:
A process for producing a perfluoroacrylic acid ester represented by the general formula CF.sub.2 .dbd.CFCOOR where R is a monovalent organic substituent, which comprises pyrolyzing a monoester of perfluorosuccinyl fluoride represented by the general formula FOCCF.sub.2 CF.sub.2 COOR where R is as defined above, in a vapor phase.
摘要:
A solvent consisting essentially of a compound of the formula:CH.sub.a Cl.sub.b F.sub.c CF.sub.2 CH.sub.x Cl.sub.y F.sub.z(I)wherein a+b+c=3, x+y+z=3, a+x.gtoreq.1, b+y.gtoreq.1, and 0.ltoreq.a, b, c, x, y, z.ltoreq.3
摘要翻译:基本上由以下化合物组成的溶剂:其中a + b + c = 3,x + y + z = 3,a + x> = 1,b + y> = 1,0 <= a,b,c,x,y,z <= 3
摘要:
A solvent consisting essentially of a compound of the formula:CH.sub.a Cl.sub.b F.sub.c CF.sub.2 CH.sub.x Cl.sub.y F.sub.z(I)wherein a+b+c=3, x+y+z=3, a+x.gtoreq.1, b+y.gtoreq.1, and 0.ltoreq.a, b, c, x, y, z.ltoreq.3.
摘要翻译:基本上由以下化合物组成的溶剂:CHaClbFcCF2CHxClyFz(I)其中a + b + c = 3,x + y + z = 3,a + x> / = 1,b + y> / = 1和0 = a,b,c,x,y,z <3。
摘要:
A fluorinated vinyl ether having an ester group which has the formulaCF.sub.2 .dbd. CFOCF.sub.2 (CF(CF.sub.3)OCF.sub.2).sub.n-1 (Rf).sub.m CO.sub.2 Rwherein n represents an integer of 1 to 5; m represents 0 or 1; Rf represents a C.sub.1 -C.sub.10 bifunctional perfluoro group and R represents an alkyl group, is produced by reacting fluorinated acyl fluoride having an ester group which has the formulaFOC(CF(CF.sub.3)OCF.sub.2).sub.n (Rf).sub.m CO.sub.2 Rwith an alkali metal carbonate to produce an alkali metal salt of fluorinated carboxylic acid having an ester group which has the formulaMOOC(CF(CF.sub.3)OCF.sub.2).sub.n (Rf).sub.m CO.sub.2 Rwherein M represnts an alkali metal;And then, thermally decomposing the alkali metal salt of fluorinated carboxylic acid having an ester group.
摘要翻译:具有式CF 2 = CFOCF 2(CF(CF 3)OCF 2)n-1(R f)m CO 2 R的酯基的氟化乙烯基醚,其中n表示1〜5的整数; m表示0或1; Rf表示C1-C10双官能全氟基团,R表示烷基,是通过使具有式FOC(CF(CF 3)OCF 2)n(R f)m CO 2 R的酯基的氟化酰氟与碱金属碳酸盐反应制得的 制备具有式MOOC(CF(CF 3)OCF 2)n(R f)m CO 2 R的酯基的氟化羧酸的碱金属盐,其中M表示碱金属; 然后,热分解含有ESTER集团的氟化羧酸的碱金属盐。
摘要:
A hydrochlorofluorocarbon azeotropic or azeotropic-like mixture comprising at least one member selected from the group consisting of hydrogen-containing fluoropropanes of the formula I:CH.sub.a Cl.sub.b F.sub.c CF.sub.2 CH.sub.x Cl.sub.y F.sub.z (I)wherein a+b+c=3, x+y+z=3, a+x.gtoreq.1, b+y.gtoreq.1, and 0.ltoreq.a,b,c,x,y,z.ltoreq.3, and at least one member selected from the group of compounds II consisting of halogenated hydrocarbons having a boiling point of from 20.degree. to 85.degree. C. other than said hydrochlorofluoropropanes, hydrocarbons having a boiling point of from 20.degree. to 85.degree. C. and alcohols having from 1 to 4 carbon atoms.
摘要翻译:一种氢氯氟烃共沸或共沸混合物,其包含选自式I的含氢氟丙烷中的至少一种:CHaClbFcCF2CHxClyFz(I)其中a + b + c = 3,x + y + z = 3,a + x> / = 1,b + y> / = 1和0