Polyimides, process for the preparation thereof and polyimide resin
compositions
    1.
    发明授权
    Polyimides, process for the preparation thereof and polyimide resin compositions 失效
    聚酰亚胺,其制备方法和聚酰亚胺树脂组合物

    公开(公告)号:US5380805A

    公开(公告)日:1995-01-10

    申请号:US143105

    申请日:1993-10-29

    IPC分类号: C08G73/10 C08L79/08

    摘要: In one aspect, the present invention relates to polyimides having excellent thermal resistance and process for preparing the same comprising carrying out condensation of 4,4'-bis(3-aminophenoxy)biphenyl with pyromellitic dianhydride in the presence of a different diamine compound and optionally with a different tetracarboxylic acid dianhydride.In a second aspect, the present invention relates to a heat resistant resin composition consisting essentially of an aromatic polyetherimide and a defined polyimide.In a third aspect, the present invention relates to a polyimide resin composition comprised on a defined polyimide and a separate high-temperature engineering polymer.In a fourth aspect, the present invention relates to a resin composition comprised of a defined polyimide and an aromatic polyamideimide.

    摘要翻译: 一方面,本发明涉及具有优异耐热性的聚酰亚胺及其制备方法,包括在不同的二胺化合物和任选地存在下进行4,4'-双(3-氨基苯氧基)联苯与均苯四酸二酐的缩合 与不同的四羧酸二酐。 在第二方面,本发明涉及一种主要由芳族聚醚酰亚胺和所定义的聚酰亚胺组成的耐热树脂组合物。 在第三方面,本发明涉及包含在限定的聚酰亚胺和单独的高温工程聚合物上的聚酰亚胺树脂组合物。 在第四方面,本发明涉及由限定的聚酰亚胺和芳族聚酰胺酰亚胺组成的树脂组合物。

    Polyimide resin composition
    3.
    发明授权

    公开(公告)号:US5086125A

    公开(公告)日:1992-02-04

    申请号:US574502

    申请日:1990-08-24

    IPC分类号: C08L79/08

    摘要: This invention relates to molding resin compositions, and more particularly relates to polyimide resin compositions having markedly improved molding ability in addition to excellent high temperature stability, chemical resistance and mechanical strength.The polyimide resin composition of this invention comprises 99.9 to 50% by weight of the polyimide and 0.1 to 50% by weight of high temperature engineering polymer. The polyimide has recurring units of the following formula: ##STR1## wherein X is a sulfonyl radical or a carbonyl radical and R is a tetravalent radical selected from an aliphatic radical, alicyclic radical, monoaromatic radical, condensed aromatic radical and non-condensed aromatic radical. R is, for example, ##STR2## The high temperature engineering polymer is, for example, polyphenylene sulfide consisting of recurring units of the formula: ##STR3## aromatic polysulfone consisting of recurring units of the formula: ##STR4## or aromatic polyetherimide consisting of recurring units of the formula: ##STR5##

    Polyimide and high-temperature adhesive thereof
    5.
    发明授权
    Polyimide and high-temperature adhesive thereof 失效
    聚酰亚胺及其高温粘合剂

    公开(公告)号:US4931531A

    公开(公告)日:1990-06-05

    申请号:US210789

    申请日:1988-06-24

    CPC分类号: C08G73/1064 C08G73/1071

    摘要: This invention relates to a novel polyimide which is high-temperature resistant and capable of being molded in a fused state. This invention also relates to a high-temperature adhesive using the polyimide.The polyimide consists essentially of recurring units of the formula: ##STR1## where R is a tetra-valent radical selected from the group consisting of an aliphatic radical having 2 or more carbon atoms, alicyclic radical, monoaromatic radical, condensed polyaromatic radical, and non-condensed polyaromatic radical wherein aromatic radicals are linked to one another directly or via a bridge member.The polyimide can be prepared by reacting bis[4-(4-aminophenoxy)phenoxy)phenyl] sulfone with a tetracarboxylic dianhydride in an organic solvent and imidizing the resultant polyamic acid.Various tetracarboxylic dianhydrides can be used and preferred dianhydride are pyromellitic dianhydride, 3,3',4,4'-benzophenonetetracarboxylic dianhydride, bis(3,4-diarboxyphenyl) ether dianhydride, 3,3',4,4'-biphenyltetracarboxylic dianhydride, and 4,4'-(p-phenylenedioxy)diphthalic dianhydride.

    摘要翻译: 本发明涉及一种耐高温且能够熔融融合的新型聚酰亚胺。 本发明还涉及使用该聚酰亚胺的高温粘合剂。 聚酰亚胺基本上由下式的重复单元组成:其中R是选自具有2个或更多个碳原子的脂族基团,脂环族基团,单芳族基团,稠合多芳族基团和非芳族基团的四价基团, 其中芳族基团直接或通过桥连构件彼此连接。 聚酰亚胺可以通过使双[4-(4-(4-(4-氨基苯氧基)苯氧基)苯基]砜与四羧酸二酐在有机溶剂中反应制备,并酰亚胺化得到的聚酰胺酸。 可以使用各种四羧酸二酐,优选二酐是均苯四酸二酐,3,3分钟,4,4分钟 - 二苯甲酮四羧酸二酐,双(3,4-二羧基苯基)醚二酐,3,3分钟,4,4分钟 - 联苯四羧酸二酐, 和4,4分钟 - (对亚苯基二氧基)二邻苯二甲酸二酐。

    Polyimides, process for the preparation thereof and polyimide resin
compositions
    6.
    发明授权
    Polyimides, process for the preparation thereof and polyimide resin compositions 失效
    聚酰亚胺,其制备方法和聚酰亚胺树脂组合物

    公开(公告)号:US5288843A

    公开(公告)日:1994-02-22

    申请号:US608727

    申请日:1990-11-05

    摘要: In one aspect, the present invention relates to polyimides having excellent thermal resistance and process for preparing the same comprising carrying out condensation of 4,4'-bis(3-aminophenoxy)biphenyl with pyromellitic dianhydride in the presence of a different diamine compound and optionally with a different tetracarboxylic acid dianhydride.In a second aspect, the present invention relates to a heat resistant resin composition consisting essentially of an aromatic polyetherimide and a defined polyimide.In a third aspect, the present invention relates to a polyimide resin composition comprised on a defined polyimide and a separate high-temperature engineering polymer.In a fourth aspect, the present invention relates to a resin composition comprised of a defined polyimide and an aromatic polyamideimide.

    摘要翻译: 一方面,本发明涉及具有优异耐热性的聚酰亚胺及其制备方法,包括在不同的二胺化合物和任选地存在下进行4,4'-双(3-氨基苯氧基)联苯与均苯四酸二酐的缩合 与不同的四羧酸二酐。 在第二方面,本发明涉及一种主要由芳族聚醚酰亚胺和所定义的聚酰亚胺组成的耐热树脂组合物。 在第三方面,本发明涉及包含在限定的聚酰亚胺和单独的高温工程聚合物上的聚酰亚胺树脂组合物。 在第四方面,本发明涉及由限定的聚酰亚胺和芳族聚酰胺酰亚胺组成的树脂组合物。