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1.发明授权公开(公告)号：US06407184B1
公开(公告)日：2002-06-18
申请号：US09539785
申请日：2000-03-31
IPC分类号： C08F234
摘要： A method of multistage gas phase polymerization is provided comprising performing polymerization of a feed gas mixture at least containing ethylene gas, an &agr;-olefin gas and hydrogen gas in an upstream fluid bed reactor to thereby produce a polymer powder, recovering the thus-produced polymer powder and performing further polymerization of the polymer powder in a downstream fluid bed reactor, the downstream fluid bed reactor being continuously connected to the upstream fluid bed reactor so that the polymer powder recovered from the upstream fluid bed reactor is introduced into the downstream fluid bed reactor, which method comprises the steps of: recovering polymer powder from the upstream fluid bed reactor, treating the recovered polymer powder so as to lower the content of &agr;-olefin gas and hydrogen gas therein by contacting the polymer powder with a stream of gas comprising ethylene or an inert gas, and introducing the treated polymer powder into the downstream fluid bed reactor. By this method, &agr;-olefin gas and hydrogen gas which inhibit the polymerization reaction in the downstream fluid bed reactor and which render regulation of desired polymer product properties difficult are removed from the polymer product prior to the downstream fluid bed reactor.
摘要翻译： 提供了一种多级气相聚合方法，包括在上游流化床反应器中进行至少含有乙烯气体，α-烯烃气体和氢气的进料气体混合物的聚合，从而产生聚合物粉末，回收如此制备的聚合物 粉末并在下游流化床反应器中进一步聚合聚合物粉末，下游流化床反应器连续地连接到上游流化床反应器，使得从上游流化床反应器回收的聚合物粉末被引入下游流化床反应器 该方法包括以下步骤：从上游流化床反应器回收聚合物粉末，处理回收的聚合物粉末，以便通过使聚合物粉末与包含乙烯的气体流接触来降低其中的α-烯烃气体和氢气的含量 或惰性气体，并将经处理的聚合物粉末引入下游流化床反应 要么。 通过这种方法，在下游流化床反应器之前，从聚合物产物中除去抑制下游流化床反应器中的聚合反应并且使所需聚合物产物性质调节困难的α-烯烃气体和氢气。
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公开(公告)号：US06472484B1
公开(公告)日：2002-10-29
申请号：US09937479
申请日：2001-09-26
申请人： Shinji Abe , Tomohiro Arase , Satoru Ohtani , Shotaro Matsuda
发明人： Shinji Abe , Tomohiro Arase , Satoru Ohtani , Shotaro Matsuda
IPC分类号： C08F234
CPC分类号： C08F297/083 , C08F210/16 , C08F297/08 , Y10S526/901 , C08F2/34 , C08F2/001 , C08F2/005 , C08F210/14 , C08F2500/12 , C08F2500/06 , C08F2500/03
摘要： The present invention provides a method for producing a polyolefin composition having a narrow composition distribution and is characterized in that when at least two olefins are copolymerized in the presence of a transition metal compound catalyst using at least two gas phase fluidized bed reactors, a saturated aliphatic hydrocarbon is allowed to exist in each reactor in a concentration from 0.1 to 30 mol %, and the ratio of the concentration (C2) of a saturated aliphatic hydrocarbon in a reactor of a second stage to the concentration (C1) of a saturated aliphatic hydrocarbon in a reactor of a first stage (C2/C1) is 0.13 or more. Further, the present invention provides a method for producing a polyolefin composition by multi-stage polymerization, which can prevent sheeting in the reactor and can give a polyolefin composition stably with high productivity, and is characterized in that a saturated aliphatic hydrocarbon is allowed to exist in a transport line for transporting a polymer particle extracted from a fluidized bed reactor in the previous stage to a fluidized bed reactor in the subsequent stage at a concentration from 0.1 to 30 mol %.
摘要翻译： 本发明提供一种制备具有窄组成分布的聚烯烃组合物的方法，其特征在于当至少两种烯烃在使用至少两种气相流化床反应器的过渡金属化合物催化剂存在下共聚时，饱和脂族 碳氢化合物以0.1〜30摩尔％的浓度存在于各反应器中，第二阶段的反应器中的饱和脂肪族烃的浓度（C2）与饱和脂肪族烃的浓度（C1）的比例 在第一级（C2 / C1）的反应器中为0.13以上。 此外，本发明提供了一种通过多级聚合制备聚烯烃组合物的方法，其可以防止反应器中的片材，并且可以以高生产率稳定地得到聚烯烃组合物，其特征在于允许存在饱和脂族烃 在将前一阶段的流化床反应器中提取的聚合物颗粒输送到后续阶段的流化床反应器的输送管线中，浓度为0.1-30mol％。
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公开(公告)号：US06891002B2
公开(公告)日：2005-05-10
申请号：US10395254
申请日：2003-03-25
申请人： Shinji Abe , Shotaro Matsuda , Satoru Ohtani , Hiroto Nishida , Michiharu Sakata , Tomohiro Arase
发明人： Shinji Abe , Shotaro Matsuda , Satoru Ohtani , Hiroto Nishida , Michiharu Sakata , Tomohiro Arase
IPC分类号： C08F2/00 , C08F2/34 , C08F210/16
CPC分类号： C08F210/16 , Y10S526/901 , C08F2/005 , C08F2/001 , C08F2/34 , C08F210/14 , C08F2500/12 , C08F2500/18 , C08F2500/17
摘要： A process for producing a polyolefin according to the present invention comprises (co) polymerizing one or two or more α-olefins in a vapor phase in a fluidized-bed reactor, wherein the concentration of (A) a saturated aliphatic hydrocarbon in the fluidized bed reactor is 1 mol % or more and at least one compound selected from (B) an aliphatic amide and (C) a nonionic surfactant constituted only of carbon, oxygen and hydrogen atoms is made to exist in the reactor. The present invention can provide a process for producing a polyolefin, the process ensuring that the prevention of clogging caused by the generation of sheet or block polymers and a high efficiency of the production of a polyolefin due to good catalytic activity can be accomplished at the same time and also having superb continuous productivity.
摘要翻译： 根据本发明的聚烯烃的制备方法包括在流化床反应器中（a）在气相中共聚合一种或两种以上的α-烯烃，其中在流化床中（A）饱和脂族烃的浓度 反应器为1摩尔％以上，并且在反应器中存在至少一种选自（B）脂族酰胺和（C）仅由碳，氧和氢原子构成的非离子表面活性剂的化合物。 本发明可以提供一种聚烯烃的制造方法，该方法确保防止由于片状或嵌段聚合物的产生而导致的堵塞以及由于良好的催化活性而产生聚烯烃的高效率可以在同一个 时间也具有极好的连续生产力。
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公开(公告)号：US5753191A
公开(公告)日：1998-05-19
申请号：US578998
申请日：1995-12-27
申请人： Ryoichi Yamamoto , Takao Uetake , Satoru Ohtani , Yoshiaki Kikuchi , Kenji Doi
发明人： Ryoichi Yamamoto , Takao Uetake , Satoru Ohtani , Yoshiaki Kikuchi , Kenji Doi
CPC分类号： B01J8/44 , B01J8/24 , C08F10/00 , B01J2208/00256 , B01J2208/00274 , B01J2219/185
摘要： A gas distributor plate provided in a fluidized bed polymerization vessel which effects the gas phase polymerization of olefins, the gas distributor plate exhibiting excellent action for uniformly diffusing the gas flow in the fluidized bed zone. A gas distributor plate has a number of gas passage holes and is provided in a fluidized bed polymerization vessel which effects the gas phase polymerization of olefins, wherein when the inner radius of the straight drum portion of the polymerization vessel is denoted by 1, the holes perforated in the outer peripheral portion of the distributor plate at 0.7 to 1.0 from the center of the straight drum portion have an average diameter which is larger than the average diameter of the holes perforated in the inner peripheral portion of the distributor plate at smaller than 0.7 from said center. This makes it possible to uniformly and stably diffuse the gas flow in the fluidized bed zone in the polymerization vessel, to effectively prevent the formation of a dead zone, as well as to effectively prevent the polymer from adhering onto the wall surfaces of the polymerization vessel.
摘要翻译： 气体分配器板设置在流化床聚合容器中，其实现烯烃的气相聚合，气体分布板显示了在流化床区域中均匀扩散气流的优异作用。 气体分布板具有多个气体通道孔，并且设置在进行烯烃气相聚合的流化床聚合容器中，其中当聚合容器的直筒部分的内半径表示为1时，孔 在分配器板的外周部分中，从直式鼓部分的中心开始的0.7-1.0的平均直径大于在分布板的内周部分中穿孔的孔的平均直径小于0.7 从中心。 这使得可以均匀且稳定地扩散在聚合容器中的流化床区域中的气流，以有效地防止形成死区，并且有效地防止聚合物粘附到聚合容器的壁表面上 。
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5.发明授权公开(公告)号：US06897268B2
公开(公告)日：2005-05-24
申请号：US10252566
申请日：2002-09-24
申请人： Ryouichi Yamamoto , Satoru Ohtani , Tomohiro Arase , Fumio Hattori , Yoshiaki Kikuchi , Hisayoshi Watanabe , Jun Iwama
发明人： Ryouichi Yamamoto , Satoru Ohtani , Tomohiro Arase , Fumio Hattori , Yoshiaki Kikuchi , Hisayoshi Watanabe , Jun Iwama
CPC分类号： B01J8/1809 , B01J8/0015 , B01J2208/00017 , B01J2208/00044 , B01J2208/00061 , B01J2208/00088 , B01J2208/00274 , B01J2208/0061 , C08F10/00 , Y10S526/901 , C08F2/01 , C08F2/34
摘要： In a gas phase olefin polymerization process using a fluidized bed vessel, an apparatus is employed having a device for measuring temperature or temperature distribution on the external wall surface of the vessel and a controlling means which predicts the progressive state of reaction inside the vessel, calculates the difference between the measured value and a target value determined beforehand and modifies polymerization conditions in relation thereto.
摘要翻译： 在使用流化床容器的气相烯烃聚合方法中，使用具有用于测量容器的外壁表面上的温度或温度分布的装置的装置以及预测容器内反应进行状态的控制装置，计算 测量值与预先确定的目标值之间的差异，并修改与之相关的聚合条件。
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6.发明授权公开(公告)号：US06461573B1
公开(公告)日：2002-10-08
申请号：US09165365
申请日：1998-10-02
申请人： Ryouichi Yamamoto , Satoru Ohtani , Tomohiro Arase , Fumio Hattori , Yoshiaki Kikuchi , Hisayoshi Watanabe , Jun Iwama
发明人： Ryouichi Yamamoto , Satoru Ohtani , Tomohiro Arase , Fumio Hattori , Yoshiaki Kikuchi , Hisayoshi Watanabe , Jun Iwama
IPC分类号： G05D2300
CPC分类号： B01J8/1809 , B01J8/0015 , B01J2208/00017 , B01J2208/00044 , B01J2208/00061 , B01J2208/00088 , B01J2208/00274 , B01J2208/0061 , C08F10/00 , Y10S526/901 , C08F2/01 , C08F2/34
摘要： In a gas phase olefin polymerization process using a fluidized bed vessel, an apparatus is employed having a device for measuring temperature or temperature distribution on the external wall surface of the vessel and a controlling means which predicts the progressive state of reaction inside the vessel, calculates the difference between the measured value and a target value determined beforehand an modifies polymerization conditions.
摘要翻译： 在使用流化床容器的气相烯烃聚合方法中，使用具有用于测量容器的外壁表面上的温度或温度分布的装置的装置以及预测容器内反应进行状态的控制装置，计算 测量值与预先确定的目标值之间的差异修改聚合条件。
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公开(公告)号：US5804678A
公开(公告)日：1998-09-08
申请号：US273987
申请日：1994-07-12
申请人： Yoshinori Morita , Hiroshi Nishikawa , Yutaka Haneda , Satoru Ohtani , Kenji Doi
发明人： Yoshinori Morita , Hiroshi Nishikawa , Yutaka Haneda , Satoru Ohtani , Kenji Doi
CPC分类号： B01J8/1809 , B01J8/24 , C08F10/02 , B01J2208/00061 , B01J2208/00088 , B01J2208/00274 , B01J2208/00283 , Y10S526/901 , Y10S526/943
摘要： In a gas phase olefin polymerization, an olefin is continuously fed to a fluid bed reactor in which a metallocene catalyst is present. At least one compound selected from water, alcohols and ketones is added in a specified amount simultaneously with the feeding of the olefin. Thus, an olefin polymer having a satisfactory drop second count index as defined by the below indicated formula is produced: ##EQU1## wherein t.sub.0 and t respectively represent a flow time measured in the flow test according to ASTM D-1775 of the olefin polymer obtained when none of the water, alcohols and ketones is incorporated in the reactor, and when at least one compound of water, alcohols and ketones is incorporated in the reactor. The flowability of the polymer formed in the reactor is excellent, so that blocking, bridging and the like do not occur during the gas phase polymerization. Thus, it is feasible to stably produce a (co)polymer having excellent particle properties in high yield for a prolonged period of time.
摘要翻译： 在气相烯烃聚合中，将烯烃连续进料到存在茂金属催化剂的流化床反应器中。 在进料烯烃的同时，以特定的量加入至少一种选自水，醇和酮的化合物。 因此，制备具有如下式所定义的令人满意的滴二次计数指数的烯烃聚合物：其中t 0和t分别表示在根据ASTM D-1775的流动试验中测量的流动时间，所得到的烯烃聚合物 当反应器中并没有加入水，醇和酮时，并且当在反应器中加入至少一种水，醇和酮的化合物时。 在反应器中形成的聚合物的流动性是优异的，因此在气相聚合期间不会发生堵塞，桥接等。 因此，长时间稳定地制备具有优异的粒子特性的（共）聚合物是可行的。
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公开(公告)号：US06858681B2
公开(公告)日：2005-02-22
申请号：US10400539
申请日：2003-03-28
申请人： Satoru Ohtani , Shinji Abe , Hiroto Nishida
发明人： Satoru Ohtani , Shinji Abe , Hiroto Nishida
IPC分类号： B01J8/24 , C08F2/34 , C08F210/16
CPC分类号： B01J8/1827 , C08F210/16 , C08F2/001 , C08F2/34 , C08F2/005 , C08F210/14 , C08F2500/12 , C08F2500/18 , C08F2500/17
摘要： The process for producing an olefinic polymer comprises introducing a saturated aliphatic hydrocarbon in a liquid phase state and in a vapor phase state into the aforementioned fluidized-bed and (co)polymerizing in the condition that when the inside radius of the cylinder section of the fluidized-bed reactor is defined as a distance of 1, the relationship between the concentration (C1) of the saturated aliphatic hydrocarbon put in a liquid state in the peripheral portion of the cylinder section at a relative distance of 0.7 to 1.0 from the center of the cylinder section as a start point and the concentration (C2) of the saturated aliphatic hydrocarbon put in a liquid state in the center portion of the cylinder section at a relative distance less than 0.7 from the center fulfills the following equation: C1>C2 at a place close to the upstream section of said gas distributing plate.
摘要翻译： 制备烯烃聚合物的方法包括将液相状态和气相状态的饱和脂族烃引入上述流化床和（共）聚合，条件是当流化床的圆筒部分的内半径 反应器被定义为距离1的距离，在圆筒部分的周边部分中的液体状态的饱和脂族烃的浓度（C1）之间的距离为距离中心的0.7至1.0的相对距离 气缸部分作为起始点，并且在中心部分的中心部分处于液态的饱和脂族烃的浓度（C2）在距中心小于0.7的相对距离处满足以下等式：C1> C2 靠近所述气体分配板的上游部分。
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公开(公告)号：US5990272A
公开(公告)日：1999-11-23
申请号：US861069
申请日：1997-05-21
IPC分类号： C08F6/02
CPC分类号： C08F6/02
摘要： A method of treating polyolefin comprises (i) a ligand-decomposition step of contacting polyolefin, which is obtained by the use of a transition metal compound containing ligands having cyclopentadienyl skeleton, with a ligand decomposer, such as water, oxygen, alcohol, alkylene oxide or peroxide, to decompose the ligands contained in the polyolefin, and (ii) a ligand-removal step of heating the polyolefin contacted with the ligand decomposer to remove the decomposed ligands from the polyolefin. According to this method, the residual ligands having cyclopentadienyl skeleton, which are contained in the polyolefin produced by the use of a transition metal compound containing ligands having cyclopentadienyl skeleton, are decomposed and removed from the polyolefin, whereby polyolefin diminished in odor development in the molding process can be obtained.
摘要翻译： 处理聚烯烃的方法包括（i）通过使用含有具有环戊二烯基骨架的配位体的过渡金属化合物与配体分解剂如水，氧，醇，烯化氧接触而获得的聚烯烃的配位体分解步骤 或过氧化物，以分解聚烯烃中所含的配体，和（ii）加热与配体分解剂接触的聚烯烃以除去聚烯烃中分解的配体的配体去除步骤。 根据该方法，通过使用含有具有环戊二烯基骨架的配体的过渡金属化合物制造的聚烯烃中含有的具有环戊二烯基骨架的残留配体从聚烯烃中分解除去，由此聚烯烃在成型中的气味发展中降低 可以获得过程。
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公开(公告)号：US07037998B2
公开(公告)日：2006-05-02
申请号：US10400572
申请日：2003-03-28
申请人： Satoru Ohtani , Shinji Abe , Hiroto Nishida
发明人： Satoru Ohtani , Shinji Abe , Hiroto Nishida
IPC分类号： C08F210/02
CPC分类号： B01J8/24 , B01J8/0015 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F6/02 , C08F210/16 , Y10S526/943 , C08L23/00 , C08F2/001 , C08F2/005 , C08F2/34 , C08F210/14 , C08F2500/12 , C08F2500/18 , C08F2500/17
摘要： The olefinic polymer characterised in that the n-decane-soluble content thereof is 10% by weight or less and the content of a ligand having a cyclopentadienyl structure is 5 ppb by weight or less. The process for producing an olefinic polymer is a process of producing an olefinic polymer by (co)polymerizing olefins in a gas phase using a fluidized-bed reactor, the process comprising: a polymerization step of (co)polymerizing the olefins with allowing a saturated aliphatic hydrocarbon to exist in a concentration of 2 to 30 mol % in the fluidized-bed reactor and a ligand removing step involving a step of bringing the resulting (co)polymer into contact with a ligand-remover and a step of heating said (co)polymer which has been brought into contact with the ligand-remover.
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