摘要:
An object of the present invention is to improve the decomposition at low temperatures of perfluorocompounds containing only fluorine as a halogen, such as CF4, C2F6 and the like. In the present invention, a perfluorocompound containing only fluorine as a halogen is brought into contact with a catalyst comprising Al, Ni and W as catalytically active ingredients and comprising a mixed oxide or complex oxide of Ni and Al and a mixed oxide or complex oxide of W and Ni, in the presence of steam or a combination of steam and air at a temperature of 500 to 800° C. to convert the fluorine in the perfluorocompound to hydrogen fluoride. Employment of the catalyst of the present invention improves the decomposition at low temperatures and hence makes it possible to decompose the perfluoro-compound at a high percentage of decomposition at a lower temperature.
摘要:
An object of the present invention is to improve the decomposition at low temperatures of perfluorocompounds containing only fluorine as a halogen, such as CF4, C2F6 and the like. In the present invention, a perfluorocompound containing only fluorine as a halogen is brought into contact with a catalyst comprising Al, Ni and W as catalytically active ingredients and comprising a mixed oxide or complex oxide of Ni and Al and a mixed oxide or complex oxide of W and Ni, in the presence of steam or a combination of steam and air at a temperature of 500 to 800° C. to convert the fluorine in the perfluorocompound to hydrogen fluoride. Employment of the catalyst of the present invention improves the decomposition at low temperatures and hence makes it possible to decompose the perfluoro-compound at a high percentage of decomposition at a lower temperature.
摘要翻译:本发明的一个目的是改进在低温下仅含氟作为卤素的全氟化合物的分解,例如CF 4,C 2 F 6, / SUB>等。 在本发明中,将仅含氟作为卤素的全氟化合物与包含Al,Ni和W的催化剂作为催化活性成分接触,并且包含Ni和Al的混合氧化物或复合氧化物以及混合氧化物或复合氧化物 W和Ni,在蒸汽或蒸汽与空气的组合的存在下,在500〜800℃的温度下,将全氟化合物中的氟转化成氟化氢。 本发明的催化剂的使用改善了低温下的分解,因此可以在较低温度下以高百分比的分解来分解全氟化合物。
摘要:
An object of the present invention is to improve the decomposition at low temperatures of perfluorocompounds containing only fluorine as a halogen, such as CF4, C2F6 and the like. In the present invention, a perfluorocompound containing only fluorine as a halogen is brought into contact with a catalyst comprising Al, Ni and W as catalytically active ingredients and comprising a mixed oxide or complex oxide of Ni and Al and a mixed oxide or complex oxide of W and Ni, in the presence of steam or a combination of steam and air at a temperature of 500 to 800° C. to convert the fluorine in the perfluorocompound to hydrogen fluoride. Employment of the catalyst of the present invention improves the decomposition at low temperatures and hence makes it possible to decompose the perfluoro-compound at a high percentage of decomposition at a lower temperature.
摘要:
In order to prevent exhaust pipe for exhausting perfluorocompound (PFC) decomposition gas after washing from corrosion, a mist separating apparatus is provided at a rear stage of the washing tower for washing the PFC decomposition gas. The corrosion of the exhaust pipe can be prevented by removing the mist from the washed gas.
摘要:
A reactor containment vessel comprises typically a reactor pressure vessel housed in a dry well of the reactor containment vessel, a vent passage through which steam in the dry well is introduced into coolant accommodated in a pressure suppression chamber of the reactor containment vessel, a closed space formed at a position lower than the level of the normal liquid surface of the coolant, a first passage having an inlet opened into the pressure suppression chamber at a level higher than that of the normal liquid surface of the coolant and an outlet opened into the closed space, and a second passage communicating between the closed space and the dry well through a counter flow preventing arrangement for checking the flow directed toward the closed space, and therefore, noncondensable gas and liquid accumulated in the pressure suppression chamber are discharged into the dry well the pressure in which is higher than that in the pressure suppression chamber by making use of a difference in water head increased due to increase of the liquid while allowing fluid to be condensed to newly flow into the pressure suppression chamber from the dry well so as to be condensed, over a long cooling period after the occurrence of an accident of piping fracture in the reactor containment vessel. Owing to condensation, the pressure in the reactor containment vessel can be reduced, and moreover, fluid can make a natural circulation in a closed circuit passing through the dry well, the pressure suppression chamber and the closed space in order without flowing outside the circuit.
摘要:
Improved operability and economy of a nuclear reactor can be obtained by attaining a mixing of the flows of coolant in the lower plenum of the fuel assemblies of the nuclear reactor, a high flow stability of the two-phase flow in the fuel assemblies and a small pressure loss in the core. To achieve this, there is provided a coolant guide tube 60 that communicates with the inside of the fuel support piece 12 inserted in the control rod guide tube and the passage 16, wherein there is formed a coolant guide passage 61 along which coolant descends in the area outside of the coolant guide tube in the fuel assemblies from opening 79. The coolant guide passage along which the coolant descends from the opening is formed in an area outside of the coolant guide tube in the fuel support piece.