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公开(公告)号：US20110160039A1
公开(公告)日：2011-06-30
申请号：US12966023
申请日：2010-12-13
IPC分类号： B01J29/00
CPC分类号： B01J29/70 , B01J31/06 , B01J2229/42
摘要： There is provided a zeolite membrane which is thinner than a conventional membrane and which has improved permeability and a method for manufacturing the zeolite membrane. The method includes a surface layer forming step for forming a surface layer by attaching a low polar polymer on a first surface of a porous substrate to cover the surface, a filling step for filling a masking polymer into pores in the porous substrate from a surface different from the first surface of the porous substrate up to the surface layer by impregnating the porous substrate with the masking polymer and solidifying the masking polymer, and a surface layer removing step for removing the surface layer. After the surface layer removing step, a zeolite membrane is formed on the first surface of the porous substrate.
摘要翻译： 提供比常规膜更薄并且具有改善的渗透性的沸石膜和制造沸石膜的方法。 该方法包括用于通过在多孔基材的第一表面上附着低极性聚合物以覆盖该表面来形成表面层的表面层形成步骤，用于将掩蔽聚合物从不同的表面填充到多孔基材中的孔中的填充步骤 通过用掩蔽聚合物浸渍多孔基材并固化掩蔽聚合物，从多孔基材的第一表面直到表面层，以及去除表面层的表面层去除步骤。 在表面层去除步骤之后，在多孔基材的第一表面上形成沸石膜。
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公开(公告)号：US08637416B2
公开(公告)日：2014-01-28
申请号：US12966023
申请日：2010-12-13
CPC分类号： B01J29/70 , B01J31/06 , B01J2229/42
摘要： There is provided a zeolite membrane which is thinner than a conventional membrane and which has improved permeability and a method for manufacturing the zeolite membrane. The method includes a surface layer forming step for forming a surface layer by attaching a low polar polymer on a first surface of a porous substrate to cover the surface, a filling step for filling a masking polymer into pores in the porous substrate from a surface different from the first surface of the porous substrate up to the surface layer by impregnating the porous substrate with the masking polymer and solidifying the masking polymer, and a surface layer removing step for removing the surface layer. After the surface layer removing step, a zeolite membrane is formed on the first surface of the porous substrate.
摘要翻译： 提供比常规膜更薄并且具有改善的渗透性的沸石膜和制造沸石膜的方法。 该方法包括用于通过在多孔基材的第一表面上附着低极性聚合物以覆盖该表面来形成表面层的表面层形成步骤，用于将掩蔽聚合物从不同的表面填充到多孔基材中的孔中的填充步骤 通过用掩蔽聚合物浸渍多孔基材并固化掩蔽聚合物，从多孔基材的第一表面直到表面层，以及去除表面层的表面层去除步骤。 在表面层去除步骤之后，在多孔基材的第一表面上形成沸石膜。
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公开(公告)号：US20060266696A1
公开(公告)日：2006-11-30
申请号：US11289763
申请日：2005-11-29
申请人： Takao Masuda , Teruoki Tago , Shuichi Yoshida , Toshihiro Tomita , Kenji Suzuki
发明人： Takao Masuda , Teruoki Tago , Shuichi Yoshida , Toshihiro Tomita , Kenji Suzuki
IPC分类号： B01D71/04
CPC分类号： B01D71/04 , B01D67/0051 , B01D69/02 , B01D69/12 , B01D2325/04 , B01D2325/30 , B01D2325/36
摘要： The present invention provides an inorganic separation membrane including a silicalite nanocrystalline layer formed on a porous ceramic substrate, and a porous inorganic protective layer is formed on the nanocrystalline layer. The crystal grain diameter of the silicalite nanocrystal is preferably 150 nm or less, and the thickness of the silicalite nanocrystalline layer is preferably 1.0 to 4.0 μm. The separation membrane may be manufactured by: immersing a porous ceramic substrate in a dispersion solution of silicalite nanocrystals; laminating the silicalite nanocrystals on the surface of the porous ceramic substrate by evacuating the insider of the porous ceramic substrate; forming a porous inorganic protective layer on the silicalite nanocrystalline layer by a hydrothermal synthesis by heating after immersing the porous substrate in a zeolite synthesis solution containing a silica source; and removing organic components in the silicalite nanocrystal by liquid phase oxidation.
摘要翻译： 本发明提供一种无机分离膜，其包括在多孔陶瓷基板上形成的硅沸石纳米晶层，在纳米晶层上形成多孔无机保护层。 硅沸石纳米晶体的晶粒直径优选为150nm以下，并且硅沸石纳米晶层的厚度优选为1.0〜4.0μm。 分离膜可以通过以下步骤制造：将多孔陶瓷基材浸渍在硅沸石纳米晶体的分散溶液中; 通过抽真空多孔陶瓷基板的内部，在多孔陶瓷基板的表面层叠硅沸石纳米晶体; 在将多孔基材浸入含有二氧化硅源的沸石合成溶液中之后通过加热通过水热合成在硅沸石纳米晶层上形成多孔无机保护层; 并通过液相氧化除去硅沸石纳米晶体中的有机成分。
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4.发明授权Structure provided with zeolite separation membrane, method for producing same, method for separating mixed fluids and device for separating mixed fluids 有权提供沸石分离膜的结构，其制造方法，分离混合流体的方法和用于分离混合流体的装置公开(公告)号：US08361197B2
公开(公告)日：2013-01-29
申请号：US13231440
申请日：2011-09-13
申请人： Masaaki Kawai , Toshihiro Tomita , Nobuhiko Mori , Aya Satoh
发明人： Masaaki Kawai , Toshihiro Tomita , Nobuhiko Mori , Aya Satoh
CPC分类号： B01D53/228 , B01D63/066 , B01D67/0051 , B01D71/028 , B01D2323/42
摘要： There is provided a zeolite separation membrane-provided article having gaps or pores larger than pores inherent to zeolite crystals and controlled within an appropriate range and being capable of achieving both high permeability and high separability for components with small difference in adsorption properties or a component having a smaller molecular diameter than the diameter of the pores, a method for producing the same, a method for separating mixed fluids, and a device for separating mixed fluids. The zeolite separation membrane-provided article is provided with a zeolite membrane having an N2 gas permeation speed at room temperature of 1.0×10−6 mol·m−2·s−1·Pa−1 or more and a permeation speed ratio of 1,3,5-trimethylbenzene/N2 at room temperature of 0.17 or more and being free from dyeing caused by the impregnation with Rhodamine B.
摘要翻译： 本发明提供一种沸石分离膜的制品，其具有比沸石晶体固有的孔隙大的孔隙，并且控制在适当的范围内，能够实现吸附性差的成分的高渗透性和高分离性， 比孔的直径小的分子直径，其制造方法，分离混合流体的方法和用于分离混合流体的装置。 在沸石分离膜的制品中，室温下的N 2气体透过速度为1.0×10 -6 mol·m-2·s -1·Pa -1以上且透过速度比为1的沸石膜 ，3,5-三甲基苯/ N 2在室温下为0.17以上，并且不被由罗丹明B浸渍引起的染色。
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5.发明授权Method for preparing DDR type zeolite membrane, DDR type zeolite membrane, and composite DDR type zeolite membrane, and method for preparation thereof 有权制备DDR型沸石膜，DDR型沸石膜和复合DDR型沸石膜的方法及其制备方法公开(公告)号：US07014680B2
公开(公告)日：2006-03-21
申请号：US11140760
申请日：2005-05-31
申请人： Kunio Nakayama , Kenji Suzuki , Manabu Yoshida , Kenji Yajima , Toshihiro Tomita
发明人： Kunio Nakayama , Kenji Suzuki , Manabu Yoshida , Kenji Yajima , Toshihiro Tomita
CPC分类号： B01D69/10 , B01D53/228 , B01D67/0051 , B01D69/12 , B01D71/028 , B01D2323/12 , Y10S55/05
摘要： A DDR type zeolite membrane formed on a substrate includes silica as a main component. The DDR type zeolite membrane separates at least one type of a gas component from a mixed gas containing at least two types of gases selected from a group consisting of carbon dioxide (CO2), hydrogen (H2), oxygen (O2), nitrogen (N2), methane (CH4), normal butane (n-C4H10), isobutane (i-C4H10), sulfur hexafluoride (SF6), ethane (C2H6), ethylene (C2H4), propane (C3H8), propylene (C3H6), carbon monoxide (CO), and nitrogen monoxide (NO). Each single gas permeance at room temperature and 100° C. are different, respectively, in order to separate at least one selected gas component from the mixed gas.
摘要翻译： 形成在基板上的DDR型沸石膜包括二氧化硅作为主要成分。 DDR型沸石膜将至少一种类型的气体成分与含有选自二氧化碳（CO 2/2），氢（H
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公开(公告)号：US06667265B1
公开(公告)日：2003-12-23
申请号：US09806682
申请日：2001-04-03
申请人： Toshihiro Tomita , Kunio Nakayama
发明人： Toshihiro Tomita , Kunio Nakayama
IPC分类号： B01J2906
CPC分类号： C01B39/02 , B01D67/0083 , B01D69/10 , B01D71/028
摘要： A method for producing a zeolite composite membrane in which a zeolite membrane is formed on a porous substrate includes the steps of: coating a zeolite membrane on a porous substrate made of zeolite having the same or a similar composition as the zeolite membrane and containing the same template as the zeolite membrane; and calcining the porous substrate having the zeolite membrane thereon to remove the template from the zeolite membrane and the porous substrate at once. A zeolite composite membrane that does not have cracks can be obtained by almost equalizing thermal expansion coefficients of the porous substrate and the zeolite membrane.
摘要翻译： 一种在多孔基材上形成沸石膜的沸石复合膜的制造方法，其特征在于，包括以下工序：将沸石膜涂布在与沸石膜相同或相同组成的沸石制的多孔质基材上，并含有沸石膜 模板作为沸石膜; 并在其上煅烧其上具有沸石膜的多孔基材，以一次从沸石膜和多孔基材上除去模板。 通过使多孔基材和沸石膜的热膨胀系数几乎相等，可以得到不具有裂纹的沸石复合膜。
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公开(公告)号：US20120199097A1
公开(公告)日：2012-08-09
申请号：US13502799
申请日：2010-06-23
IPC分类号： F01M1/04
摘要： A lubrication apparatus for a four-stroke engine (1) is provided that prevents lubrication failure from occurring around the crankshaft and reliably prevents oil from remaining in a valve operating chamber (30). The lubrication apparatus for the four-stroke engine (1) includes: an intake part (55) positioned below the level of an oil A in an oil reservoir (7) even if the oil reservoir (7) is tilted and the level of the oil A changes; an oil feeding passageway (54) that sucks up the oil A from the intake part (55) and supplies the oil A to the crank chamber (5a); and an direct passageway (47) that allows communication between a valve operating chamber (30) and a crank chamber (5a) when a negative pressure is created in the crank chamber (5a). Open end parts (47a, 54a) of the oil feeding passageway (54) and the direct passageway (47) which are open in the crank chamber (5a) are provided to open as the piston (13) moves from a position near the top dead center to the top dead center. It is possible to control the flow rate of oil supplied to the crank chamber (5a) via the oil supply passageway (54) by means of a flow rate control passageway (67) that allows communication between a supply passageway (51) to supply oil mist from the oil reservoir (7) to the valve operating chamber (30) and the oil feeding passageway (54).
摘要翻译： 提供一种用于四冲程发动机（1）的润滑装置，其防止在曲轴周围发生润滑故障，并且可靠地防止油残留在阀操作室（30）中。 用于四冲程发动机（1）的润滑装置包括：即使储油器（7）倾斜并且油位（7）的水平位于油藏（7）中的位于油A的高度之下的进气部分（55） 油A变化; 供油通路（54），其从所述进气部（55）吸入油A，并将油A供给到所述曲柄室（5a）; 以及当在曲柄室（5a）中产生负压时允许阀操作室（30）和曲柄室（5a）之间的连通的直接通道（47）。 供油通道（54）的开口端部（47a，54a）和在曲柄室（5a）中敞开的直接通道（47）设置成随着活塞（13）从靠近顶部 死中心到上死点。 可以通过流量控制通道（67）来控制经由供油通道（54）供应到曲柄室（5a）的油的流量，流量控制通道（67）允许供给通道（51） 从油箱（7）到阀操作室（30）和供油通道（54）的雾。
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公开(公告)号：US20110067659A1
公开(公告)日：2011-03-24
申请号：US12876722
申请日：2010-09-07
IPC分类号： F01M9/10
CPC分类号： F01M1/04 , F01M9/10 , F01M11/067 , F01M13/022 , F01M13/025 , F01M13/0405
摘要： A lubrication system for a portable four-stroke engine includes an opening end of the breather passage is disposed at substantially a center of a valve-operating chamber, and the valve-operating chamber is formed by attaching a valve-operating chamber cover. An inner cover is attached to an inner surface of the valve-operating chamber cover so as to be provided along and in contact with the inner surface of the valve-operating chamber cover. A suction passage is formed as a gap between the circumferential edge of the top plate portion and the inner cover. Three or more suction tubes that are in communication with the suction passage are provided in the inner cover, each of the suction tubes having an opening end. At least one of the opening ends of the suction tubes is provided lower than the opening end of the breather passage in an attitude of the engine during use.
摘要翻译： 用于便携式四冲程发动机的润滑系统包括通气通道的开口端设置在阀操作室的大致中心处，并且阀操作室通过安装阀操作室盖而形成。 内盖附接到阀操作室盖的内表面，以便与阀操作室盖的内表面一并设置。 吸入通道形成为顶板部分的圆周边缘和内盖之间的间隙。 与吸入通道连通的三个或更多个吸管设置在内盖中，每个吸管具有开口端。 吸入管的开口端中的至少一个在使用期间以发动机的姿态设置得比通气通道的开口端低。
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9.发明申请SEPARATION MEMBRANE COMPLEX, AND METHOD FOR MANUFACTURING THE SEPARATION MEMBRANE COMPLEX 有权分离膜复合物，以及制造分离膜复合物的方法公开(公告)号：US20100072127A1
公开(公告)日：2010-03-25
申请号：US12629409
申请日：2009-12-02
CPC分类号： B01D69/12 , B01D63/066 , B01D67/0046 , B01D67/0067 , B01D69/02 , B01D71/021 , B01D71/025 , B01D71/027 , B01D71/028 , B01D2325/04
摘要： A separation membrane complex 1 where a carbon membrane 66 is formed directly on a porous body 61 (surface layer 64) and an intermediate layer 63 has a thickness of 10 to 100 μm can be used as a filter having improved flux and selectivity in comparison with a conventional one.
摘要翻译： 将碳膜66直接形成在多孔体61（表面层64）上的分离膜复合体1和厚度为10〜100μm的中间层63可以用作具有提高的通量和选择性的过滤器，与 常规的。
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10.发明授权Carbon film laminate and method for production thereof, and VOC removing device 有权碳膜层叠体及其制造方法以及VOC除去装置公开(公告)号：US07621979B2
公开(公告)日：2009-11-24
申请号：US11511204
申请日：2006-08-28
CPC分类号： B01D71/021 , B01D53/02 , B01D67/0067 , B01D69/10 , B01D2253/102 , B01D2257/102 , B01D2257/104 , B01D2257/708 , B01D2325/04 , B01J20/20 , B01J20/28035 , C01B32/05 , Y02A50/235
摘要： A carbon film laminate 1 having a porous substrate 6 formed of a plurality of particles and a carbon film 2 provided on a surface of the porous substrate 6, wherein the porous substrate 6 includes a surface layer 3 which is in contact with the carbon film 2 and which is formed of particles 3a having a mean particle size of 0.01 to 0.11 μm, and a porous body 5 formed of particles having a mean particle size differing from that of the particles 3a forming the surface layer 3. The invention provides a carbon film laminate which does not generate cracks and pinholes of the carbon film and which is suitable for producing thin film thereof.
摘要翻译： 具有由多个颗粒形成的多孔基材6和设置在多孔基材6的表面上的碳膜2的碳膜层压体1，其中多孔基材6包括与碳膜2接触的表面层3 由平均粒径为0.01〜0.11μm的粒子3a形成的多孔体5以及与构成表面层3的粒子3a的平均粒径不同的粒子形成的多孔体5构成。本发明提供一种碳膜 层压体不会产生碳膜的裂纹和针孔，并且适用于制造其薄膜。
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