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公开(公告)号：US20050143612A1
公开(公告)日：2005-06-30
申请号：US10505787
申请日：2003-02-27
申请人： Shyh-Yuan Hwang , Maruti Bhandarkar , Chung-Ming Chi , Waheed Mukaddam , Frank Demers , Richard Guarino , Dana Johnson
发明人： Shyh-Yuan Hwang , Maruti Bhandarkar , Chung-Ming Chi , Waheed Mukaddam , Frank Demers , Richard Guarino , Dana Johnson
IPC分类号： C07C7/04 , C07B61/00 , C07C2/64 , C07C2/66 , C07C2/70 , C07C7/10 , C07C7/12 , C07C11/04 , C07C11/06 , C07C11/08 , C07C11/09 , C07C15/02 , C07C15/04 , C07C15/06 , C07C15/073 , C07C15/08 , C07C15/085
CPC分类号： C07C2/66 , C07C7/04 , C07C7/10 , C07C7/12 , C07C7/13 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/70 , C07C2529/82 , Y02P20/125 , C07C15/085 , C07C11/06 , C07C15/04
摘要： Improved integrated processes for the production of alkyl aromatic compounds are disclosed wherein aromatic compounds which may be treated for removal of deleterious substances are reacted with olefin compounds, which may also be treated for contaminant removal, in the presence of acidic zeolite catalyst(s) to produce the desired alkyl aromatic compound(s). The aromatic and preferably also the olefin feeds are treated substantially to remove contaminants, particularly the nitrogen compounds contained therein, before they are brought together for reaction in the presence of the zeolite catalyst(s). In accordance with the present invention, it has been found that feed pretreatment for removal of nitrogen compounds significantly improves the run length and life of the acidic zeolite catalyst(s). The feed pretreatment of this invention may include the steps of distillation, extraction, and/or adsorption by solid adsorbent, which may be regenerated in accordance with further embodiments of this invention.
摘要翻译： 公开了用于生产烷基芳族化合物的改进的一体化方法，其中可以处理去除有害物质的芳族化合物与烯烃化合物反应，烯烃化合物也可以在酸性沸石催化剂存在下进行处理以除去污染物， 产生所需的烷基芳族化合物。 在沸石催化剂的存在下，芳族化合物和烯烃进料基本上被处理以除去污染物，特别是其中所含的氮化合物，然后将它们聚集在一起进行反应。 根据本发明，已经发现用于除去氮化合物的进料预处理显着地改善了酸性沸石催化剂的运行长度和使用寿命。 本发明的进料预处理可以包括根据本发明的其它实施方案可以再生的固体吸附剂的蒸馏，萃取和/或吸附的步骤。
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公开(公告)号：US20100268008A1
公开(公告)日：2010-10-21
申请号：US12830725
申请日：2010-07-06
申请人： Shyh-Yuan Hwang , Maruti Bhandarkar , Chung-Ming Chi , Waheed Mukaddam , Frank Demers , Richard F. Guarino , Dana E. Johnson
发明人： Shyh-Yuan Hwang , Maruti Bhandarkar , Chung-Ming Chi , Waheed Mukaddam , Frank Demers , Richard F. Guarino , Dana E. Johnson
IPC分类号： C07C2/66
CPC分类号： C07C2/66 , C07C7/04 , C07C7/10 , C07C7/12 , C07C7/13 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/70 , C07C2529/82 , Y02P20/125 , C07C15/085 , C07C11/06 , C07C15/04
摘要： Improved integrated processes for the production of alkyl aromatic compounds are disclosed wherein aromatic compounds which may be treated for removal of deleterious substances are reacted with olefin compounds, which may also be treated for contaminant removal, in the presence of acidic zeolite catalyst(s) to produce the desired alkyl aromatic compound(s). The aromatic and preferably also the olefin feeds are treated substantially to remove contaminants, particularly the nitrogen compounds contained therein, before they are brought together for reaction in the presence of the zeolite catalyst(s). In accordance with the present invention, it has been found that feed pretreatment for removal of nitrogen compounds significantly improves the run length and life of the acidic zeolite catalyst(s). The feed pretreatment of this invention may include the steps of distillation, extraction, and/or adsorption by solid adsorbent, which may be regenerated in accordance with further embodiments of this invention.
摘要翻译： 公开了用于生产烷基芳族化合物的改进的一体化方法，其中可以处理去除有害物质的芳族化合物与烯烃化合物反应，烯烃化合物也可以在酸性沸石催化剂存在下进行处理以除去污染物， 产生所需的烷基芳族化合物。 在沸石催化剂的存在下，芳族化合物和烯烃进料基本上被处理以除去污染物，特别是其中所含的氮化合物，然后将它们聚集在一起进行反应。 根据本发明，已经发现用于除去氮化合物的进料预处理显着地改善了酸性沸石催化剂的运行长度和使用寿命。 本发明的进料预处理可以包括根据本发明的其它实施方案可以再生的固体吸附剂的蒸馏，萃取和/或吸附的步骤。
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公开(公告)号：US07777086B2
公开(公告)日：2010-08-17
申请号：US10505787
申请日：2003-02-27
申请人： Shyh-Yuan Hwang , Maruti Bhandarkar , Chung-Ming Chi , Waheed Mukaddam , Frank Demers , Richard F. Guarino , Dana E Johnson
发明人： Shyh-Yuan Hwang , Maruti Bhandarkar , Chung-Ming Chi , Waheed Mukaddam , Frank Demers , Richard F. Guarino , Dana E Johnson
CPC分类号： C07C2/66 , C07C7/04 , C07C7/10 , C07C7/12 , C07C7/13 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/70 , C07C2529/82 , Y02P20/125 , C07C15/085 , C07C11/06 , C07C15/04
摘要： Improved integrated processes for the production of alkyl aromatic compounds are disclosed wherein aromatic compounds which may be treated for removal of deleterious substances are reacted with olefin compounds, which may also be treated for contaminant removal, in the presence of acidic zeolite catalyst(s) to produce the desired alkyl aromatic compound(s). The aromatic and preferably also the olefin feeds are treated substantially to remove contaminants, particularly the nitrogen compounds contained therein, before they are brought together for reaction in the presence of the zeolite catalyst(s). In accordance with the present invention, it has been found that feed pretreatment for removal of nitrogen compounds significantly improves the run length and life of the acidic zeolite catalyst(s). The feed pretreatment of this invention may include the steps of distillation, extraction, and/or adsorption by solid adsorbent, which may be regenerated in accordance with further embodiments of this invention.
摘要翻译： 公开了用于生产烷基芳族化合物的改进的一体化方法，其中可以处理去除有害物质的芳族化合物与烯烃化合物反应，烯烃化合物也可以在酸性沸石催化剂存在下进行处理以除去污染物， 产生所需的烷基芳族化合物。 在沸石催化剂的存在下，芳族化合物和烯烃进料基本上被处理以除去污染物，特别是其中所含的氮化合物，然后将它们聚集在一起进行反应。 根据本发明，已经发现用于除去氮化合物的进料预处理显着地改善了酸性沸石催化剂的运行长度和使用寿命。 本发明的进料预处理可以包括根据本发明的其它实施方案可以再生的固体吸附剂的蒸馏，萃取和/或吸附的步骤。
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公开(公告)号：US20080135399A1
公开(公告)日：2008-06-12
申请号：US10588930
申请日：2006-08-09
CPC分类号： B01J19/121 , B01J2219/0884 , B01J2219/0888 , C02F1/325 , C02F2101/36 , C02F2101/363 , C02F2101/366 , C02F2201/3226 , C02F2201/326
摘要： Apparatus and methods are disclosed for using an ultraviolet laser system to decompose selected chemical substances in water. More particularly, this invention provides methods and apparatus whereby various environmental pollutants in water are rapidly decomposed to very low concentrations, consistent with environmental discharge regulations, use requirements, and/or applicable health standards, by means of exposure to ultraviolet laser irradiation (10, 20), either with or without one or more catalysts and/or other chemical additives to facilitate or enhance the decomposition process.
摘要翻译： 公开了使用紫外激光系统分解水中所选择的化学物质的装置和方法。 更具体地说，本发明提供了通过暴露于紫外线激光照射（10）的方法和装置，其中水中的各种环境污染物通过暴露于紫外线激光照射而迅速分解成非常低的浓度，符合环境排放法规，使用要求和/或适用的卫生标准 20），具有或不具有一种或多种催化剂和/或其它化学添加剂以促进或增强分解过程。
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公开(公告)号：US20070170121A1
公开(公告)日：2007-07-26
申请号：US10588933
申请日：2005-03-22
申请人： Waheed Mukaddam , Allan Thompson , Charles Moores
发明人： Waheed Mukaddam , Allan Thompson , Charles Moores
IPC分类号： C02F1/32
CPC分类号： C02F1/325 , A62D2203/10 , C02F1/722 , C02F1/725 , C02F2101/36 , C02F2101/363 , C02F2101/366 , C02F2201/3221 , C02F2201/3226 , C02F2201/326 , C02F2209/005 , C02F2209/40 , H05B3/0052
摘要： Apparatus and methods are disclosed for using an ultraviolet laser system to decompose selected chemical substances in water. More particularly, this invention provides methods and apparatus whereby various environmental pollutants in water are rapidly decomposed to very low concentrations, consistent with environmental discharge regulations, use requirements, and/or applicable health standards, by means of exposure to ultraviolet laser irradiation (10, 20), either with or without one or more catalysts and/or other chemical additives to facilitate or enhance the decomposition process.
摘要翻译： 公开了使用紫外激光系统分解水中所选择的化学物质的装置和方法。 更具体地说，本发明提供了通过暴露于紫外线激光照射（10）的方法和装置，其中水中的各种环境污染物通过暴露于紫外线激光照射而迅速分解成非常低的浓度，符合环境排放法规，使用要求和/或适用的卫生标准 20），具有或不具有一种或多种催化剂和/或其它化学添加剂以促进或增强分解过程。
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公开(公告)号：US4357175A
公开(公告)日：1982-11-02
申请号：US281455
申请日：1981-07-08
申请人： Chester G. Buffington , Herbert H. Fang , Barry A. Friedfeld , Thaddeus J. Kaniecki , John W. Kennedy , Chong-tan Liu , Morton Sternberg , Henry H. Feng , Paul Y. Chen , Waheed Mukaddam , Pattamadai E. Narasimhan
发明人： Chester G. Buffington , Herbert H. Fang , Barry A. Friedfeld , Thaddeus J. Kaniecki , John W. Kennedy , Chong-tan Liu , Morton Sternberg , Henry H. Feng , Paul Y. Chen , Waheed Mukaddam , Pattamadai E. Narasimhan
CPC分类号： B08B9/08 , B08B3/08 , C11D7/5018 , C11D7/264 , C11D7/28
摘要： An environmentally acceptable method for cleaning the interior of vessels comprises contacting the interior of a vessel with a solvent for the contaminant contained therein to produce a contaminated solvent, collecting the contaminated solvent from the vessel, separating essentially all of the contaminant from the contaminated solvent to recover essentially all of the solvent essentially free of the contaminant and produce a contaminant composition which is incineratable or can be made incineratable by blending with a combustible composition, such as fuel oil.The contaminant may be separated from the contaminated solvent by distillation; in which case the overhead product may be washed with sulfuric acid and then neutralized with a base.
摘要翻译： 用于清洁容器内部的环境可接受的方法包括使容器的内部与其中容纳的污染物的溶剂接触以产生污染的溶剂，从容器收集污染的溶剂，将基本上所有的污染物与被污染的溶剂分离成 回收基本上没有污染物的所有溶剂，并产生污染物组合物，其可焚烧或可通过与可燃组合物如燃料油混合而制成。 污染物可以通过蒸馏与污染的溶剂分离; 在这种情况下，塔顶产物可以用硫酸洗涤，然后用碱中和。
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