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公开(公告)号：US12046759B2
公开(公告)日：2024-07-23
申请号：US17898050
申请日：2022-08-29
发明人： Gleb Yushin , Justin Yen , Jens Steiger , Eniko Zsoldos , Mareva Fevre , Adam Kajdos , Weimin Wang
IPC分类号： H01M4/38 , H01M4/134 , H01M4/1395 , H01M4/62 , H01M4/66 , H01M4/88 , H01M10/0525
CPC分类号： H01M4/8828 , H01M4/134 , H01M4/1395 , H01M4/386 , H01M4/622 , H01M4/625 , H01M4/661 , H01M4/663 , H01M4/667 , H01M4/668 , H01M10/0525 , Y02E60/10 , Y02E60/50
摘要： In an embodiment, a Li-ion battery electrode comprises a conductive interlayer arranged between a current collector and an electrode active material layer. The conductive interlayer comprises first conductive additives and a first polymer binder, and the electrode active material layer comprises a plurality of active material particles mixed with a second polymer binder (which may be the same as or different from the first polymer binder) and second conductive additives (which may be the same as or different from the first conductive additives). In a further embodiment, the Li-ion battery electrode may be fabricated via application of successive slurry formulations onto the current collector, with the resultant product then being calendared (or densified).
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公开(公告)号：US11931810B2
公开(公告)日：2024-03-19
申请号：US17656065
申请日：2022-03-23
发明人： Gleb Yushin , Wenqiang Hu , Samik Jhulki , Wenbin Fu , Kostiantyn Turcheniuk
CPC分类号： B22F9/22 , B22F1/0547 , B22F1/062 , B22F9/20 , C07F3/06 , C22C18/00 , B22F2301/30 , B22F2304/05 , B82Y30/00 , B82Y40/00
摘要： Aspects relate to method of zinc-comprising nanowire fabrication, the method comprising forming a starting material comprising zinc metal or zinc metal alloy and at least one reactive metal, and exposing the starting material to one or more alcohols to obtain a reaction product comprising zinc-comprising nanowires, wherein the at least one reactive metal is more reactive than zinc to the one or more alcohols.
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公开(公告)号：US11721831B2
公开(公告)日：2023-08-08
申请号：US14464873
申请日：2014-08-21
IPC分类号： H01M10/0525 , H01M10/054 , H01M10/44 , H01M10/42 , H01M50/691
CPC分类号： H01M10/0525 , H01M10/054 , H01M10/4235 , H01M10/446 , H01M50/691 , Y02T10/70 , Y10T29/49108
摘要： Metal-ion battery cells are provided that take advantage of the disclosed “doping” process. The cells may be fabricated from anode and cathode electrodes, a separator, and an electrolyte. A metal-ion additive may be incorporated into (i) one or more of the electrodes, (ii) the separator, or (iii) the electrolyte. The metal-ion additive provides additional donor ions corresponding to the metal ions stored and released by anode and cathode active material particles. An activation potential may then be applied to the anode and cathode electrodes to release the additional donor ions into the battery cell.
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公开(公告)号：US11658331B2
公开(公告)日：2023-05-23
申请号：US17649418
申请日：2022-01-31
发明人： Gleb Yushin , Feixiang Wu , Hyea Kim
IPC分类号： H01M10/052 , H01M4/136 , H01M4/1397 , H01M4/04 , H01M4/36 , H01M4/58 , H01M10/0568
CPC分类号： H01M10/052 , H01M4/0404 , H01M4/0428 , H01M4/0471 , H01M4/136 , H01M4/1397 , H01M4/366 , H01M4/5815 , H01M10/0568 , Y02T10/70 , Y10T156/10
摘要： Lithium-ion batteries are provided that variously comprise anode and cathode electrodes, an electrolyte, a separator, and, in some designs, a protective layer. In some designs, at least one of the electrodes may comprise a composite of (i) Li2S and (ii) conductive carbon that is embedded in the core of the composite. In some designs, the protective layer may be disposed on at least one of the electrodes via electrolyte decomposition. Various methods of fabrication for lithium-ion battery electrodes and particles are also provided.
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公开(公告)号：US11575129B2
公开(公告)日：2023-02-07
申请号：US17454962
申请日：2021-11-15
发明人： Gleb Yushin , Eugene Michael Berdichevsky , Alexander Thomas Jacobs , Alper Nese , Damian Harris , Bogdan Zdyrko
摘要： Battery electrode compositions and methods of fabrication are provided that utilize composite particles. Each of the composite particles may comprise, for example, a high-capacity active material and a porous, electrically-conductive scaffolding matrix material. The active material may store and release ions during battery operation, and may exhibit (i) a specific capacity of at least 220 mAh/g as a cathode active material or (ii) a specific capacity of at least 400 mAh/g as an anode active material. The active material may be disposed in the pores of the scaffolding matrix material. According to various designs, each composite particle may exhibit at least one material property that changes from the center to the perimeter of the scaffolding matrix material.
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公开(公告)号：US11515528B2
公开(公告)日：2022-11-29
申请号：US17692030
申请日：2022-03-10
IPC分类号： H01M4/36 , H01M4/38 , H01M4/587 , H01M4/62 , H01M4/133 , H01M4/137 , H01M4/60 , H01M4/134 , H01B1/18 , H01B1/24 , H01M4/1395 , H01M10/0525 , B82Y30/00 , H01M4/1393
摘要： Described herein are improved composite anodes and lithium-ion batteries made therefrom. Further described are methods of making and using the improved anodes and batteries. In general, the anodes include a porous composite having a plurality of agglomerated nanocomposites. At least one of the plurality of agglomerated nanocomposites is formed from a dendritic particle, which is a three-dimensional, randomly-ordered assembly of nanoparticles of an electrically conducting material and a plurality of discrete non-porous nanoparticles of a non-carbon Group 4A element or mixture thereof disposed on a surface of the dendritic particle. At least one nanocomposite of the plurality of agglomerated nanocomposites has at least a portion of its dendritic particle in electrical communication with at least a portion of a dendritic particle of an adjacent nanocomposite in the plurality of agglomerated nanocomposites.
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公开(公告)号：US11101458B2
公开(公告)日：2021-08-24
申请号：US16419806
申请日：2019-05-22
发明人： Gleb Yushin , Bogdan Zdyrko , Addison Shelton , Eugene Berdichevsky , Igor Luzinov , Alexander Jacobs , Eerik Hantsoo , George Gomes
IPC分类号： H01M4/36 , H01M4/04 , H01M4/13 , H01M4/139 , H01M4/62 , H01M10/054 , H01M4/38 , H01M4/48 , H01M10/052
摘要： A battery electrode composition is provided comprising composite particles, with each composite particle comprising active material and a scaffolding matrix. The active material is provided to store and release ions during battery operation. For certain active materials of interest, the storing and releasing of the ions causes a substantial change in volume of the active material. The scaffolding matrix is provided as a porous, electrically-conductive scaffolding matrix within which the active material is disposed. In this way, the scaffolding matrix structurally supports the active material, electrically interconnects the active material, and accommodates the changes in volume of the active material.
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公开(公告)号：US10892486B2
公开(公告)日：2021-01-12
申请号：US16022572
申请日：2018-06-28
发明人： Gleb Yushin , Kostiantyn Turcheniuk , Yiran Xiao , Ah-Young Song , Oleg Borodin , Naoki Nitta
IPC分类号： H01M4/58 , H01M10/052 , H01M10/0562 , H01M4/36 , H01M4/46 , C01F17/00 , H01M4/88 , H01M4/04 , H01M4/40 , C01D15/00
摘要： In an embodiment, a metal or metal-ion battery cell, includes anode and cathode electrodes, a separator electrically separating the anode and the cathode, and a solid electrolyte ionically coupling the anode and the cathode, wherein the solid electrolyte comprises a material having one or more rearrangeable chalcogen-metal-hydrogen groups that are configured to transport at least one metal-ion or metal-ion mixture through the solid electrolyte, wherein the solid electrolyte exhibits a melting point below about 350° C. In an example, the solid electrolyte may be produced by mixing different dry metal-ion compositions together, arranging the mixture inside of a mold, and heating the mixture while arranged inside of the mold at least to a melting point (e.g., below about 350° C.) of the mixture so as to produce a material comprising one or more rearrangeable chalcogen-metal-hydrogen groups.
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公开(公告)号：US10109885B2
公开(公告)日：2018-10-23
申请号：US14706740
申请日：2015-05-07
发明人： Gleb Yushin , Bogdan Zdyrko , Hyea Kim , Igor Luzinov , Yuriy Bandera , Eugene Berdichevsky
IPC分类号： H01M10/0568 , H01M4/134 , H01M2/16 , H01M10/052 , H01M10/058 , H01M4/38
摘要： Batteries such as Li-ion batteries are provided that comprise anode and cathode electrodes, an electrolyte ionically coupling the anode and the cathode, and a separator electrically separating the anode and the cathode. In some designs, the electrolyte may comprise, for example, a mixture of (i) a Li-ion salt with (ii) at least one other metal salt having a metal with a standard reduction potential below −2.3 V vs. Standard Hydrogen Electrode (SHE). In other designs, the electrolyte may be disposed in conjunction with an electrolyte solvent that comprises, for example, about 10 to about 100 wt. % ether. In still other designs, the battery may further comprise anode and cathode interfacial layers (e.g., solid electrolyte interphase (SEI)) disposed between the respective electrode and the electrolyte and having different types of fragments of electrolyte solvent molecules as compared to each other.
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公开(公告)号：US12113164B2
公开(公告)日：2024-10-08
申请号：US18315245
申请日：2023-05-10
IPC分类号： H01M10/0525 , H01M10/054 , H01M10/42 , H01M10/44 , H01M50/691
CPC分类号： H01M10/0525 , H01M10/054 , H01M10/4235 , H01M10/446 , H01M50/691 , Y02T10/70 , Y10T29/49108
摘要： Metal-ion battery cells are provided that take advantage of the disclosed “doping” process. The cells may be fabricated from anode and cathode electrodes, a separator, and an electrolyte. A metal-ion additive may be incorporated into (i) one or more of the electrodes, (ii) the separator, or (iii) the electrolyte. The metal-ion additive provides additional donor ions corresponding to the metal ions stored and released by anode and cathode active material particles. An activation potential may then be applied to the anode and cathode electrodes to release the additional donor ions into the battery cell.
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