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公开(公告)号：US4097350A
公开(公告)日：1978-06-27
申请号：US588398
申请日：1975-06-19
IPC分类号： C08F2/00 , C08F2/46 , C08F2/48 , C08F2/54 , C08F20/00 , C08F20/26 , C08F220/00 , C08F220/04 , C08F220/10 , C08F265/04 , C08F267/04 , C08F290/00 , C08F299/00 , C09D4/06 , C09J4/02
CPC分类号： C08F267/04 , C08F2/48 , C08F265/04 , C09D4/06 , Y10T428/31649 , Y10T428/31699 , Y10T428/31797 , Y10T428/31935
摘要： Actinic radiation curable compositions comprise chemically bonded portions of at least one free radical polymerizable hydroxyalkyl ester of an alpha, beta unsaturated carboxylic acid, at least one non-halogenated cyclic anhydride, at least one epoxide and a halogenated free radical initiator which is activatable by actinic radiation. Upon exposure to actinic radiation, these compositions are cured with very little or no inhibition by atmospheric oxygen.
摘要翻译： 光化学可辐射固化组合物包含至少一种α，β不饱和羧酸的自由基可聚合羟基烷基酯，至少一种非卤代环状酸酐，至少一种环氧化物和卤化自由基引发剂的化学键合部分，其可被光化剂 辐射。 暴露于光化辐射后，这些组合物在很少或不受大气氧的抑制下固化。
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公开(公告)号：US4097417A
公开(公告)日：1978-06-27
申请号：US466264
申请日：1974-05-02
IPC分类号： C08F2/00 , C08F2/48 , C08F2/50 , C08F2/54 , C08F20/00 , C08F20/10 , C08F290/00 , C08F299/00 , C08F299/04 , C08G63/52 , C09D5/24 , G03G5/10 , G03G5/14 , H01L13/00 , C08F2/46 , C08F8/00
CPC分类号： G03G5/105 , C08F2/50 , C08F299/0485 , C08G63/52 , C09D5/24 , G03G5/107 , Y10T428/3162 , Y10T428/31681 , Y10T428/31692 , Y10T428/31696 , Y10T428/31699 , Y10T428/31826 , Y10T428/31855 , Y10T428/3188
摘要： A photocurable electroconductive coating composition adapted to be crosslinked and insolubilized by actinic radiation comprises an acrylic monomer, a photoactivatable free radical polymerization initiator and a salt of a copolymerizable organic compound, wherein at least one of the monomers contains more than one polymerizable ethylenically unsaturated group. The cured coatings are insoluble in aqueous and organic solvents and are conductors of electricity suitable for conductive underlayers of photoconductive imaging elements and as antistatic coatings.
摘要翻译： 适于通过光化辐射交联和不溶解的光固化导电涂料组合物包括丙烯酸单体，可光活化的自由基聚合引发剂和可共聚有机化合物的盐，其中至少一种单体含有多于一个可聚合的烯属不饱和基团。 固化的涂层不溶于水性和有机溶剂，并且是适用于光导成像元件的导电底层和作为抗静电涂层的电导体。
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公开(公告)号：US4052527A
公开(公告)日：1977-10-04
申请号：US766026
申请日：1977-02-07
IPC分类号： C08F20/00 , C08F2/46 , C08F20/22 , C09J133/04 , C09J133/16
CPC分类号： C09J133/16 , Y10S430/111 , Y10S522/904 , Y10S522/913 , Y10T428/31699 , Y10T428/31797 , Y10T428/31906 , Y10T428/31928
摘要： The present invention is directed to hot melt pressure sensitive adhesive compositions formed by copolymerizing at least one 3-(chlorinated aryloxy)-2-hydroxypropyl ester of an alpha, beta unsaturated carboxylic acid with acrylate based copolymerizable monomers, heating the resultant ethylenically saturated prepolymer to a temperature sufficient to render it fluid and flowable; coating onto a substrate and exposing to ultraviolet radiation.
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公开(公告)号：US5286821A
公开(公告)日：1994-02-15
申请号：US852855
申请日：1992-03-17
申请人： Martin M. Skoultchi
发明人： Martin M. Skoultchi
IPC分类号： C08F4/00 , C08F4/52 , C09J4/00 , C09J4/02 , C09J4/06 , C09J151/00 , C09J151/04 , H05K3/38 , C08F20/10
CPC分类号： C09J4/00 , C08F4/52 , C09J4/06 , H05K3/386 , Y10S525/939 , Y10T428/31855
摘要： A two-part initiator system useful in acrylic adhesive compositions comprising in one part a stable organoboron amine complex and in the second part an aldehyde destabilizer or activator. This initiator is particularly useful in elastomeric acrylic adhesive compositions and provides room temperature, relatively slow curing systems with good adhesive properties making them useful in applications where longer open times are required.
摘要翻译： 用于丙烯酸粘合剂组合物的两部分引发剂体系包括一部分稳定的有机硼胺络合物，在第二部分中包含醛去稳定剂或活化剂。 该引发剂在弹性丙烯酸类粘合剂组合物中特别有用，并提供具有良好粘合性质的室温相对较慢的固化体系，使其在需要较长开放时间的应用中有用。
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公开(公告)号：US5376746A
公开(公告)日：1994-12-27
申请号：US137855
申请日：1993-10-15
申请人： Martin M. Skoultchi
发明人： Martin M. Skoultchi
IPC分类号： C08F4/00 , C08F4/52 , C09J4/00 , C09J4/02 , C09J4/06 , C09J151/00 , C09J151/04 , H05K3/38 , C07F5/02 , C07C47/00
CPC分类号： C09J4/00 , C08F4/52 , C09J4/06 , H05K3/386 , Y10S525/939 , Y10T428/31855
摘要： A two-part initiator system useful in acrylic adhesive compositions comprising in one part a stable organoboron amine complex and in the second part an aldehyde destabilizer or activator. This initiator is particularly useful in elastomeric acrylic adhesive compositions and provides room temperature, relatively slow curing systems with good adhesive properties making them useful in applications where longer open times are required.
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6.发明授权Transparent two-part acrylic adhesive composition and the method of use thereof 失效透明双组分丙烯酸粘合剂组合物及其使用方法
公开(公告)号：US5310835A
公开(公告)日：1994-05-10
申请号：US130069
申请日：1993-09-30
CPC分类号： C09J4/00
摘要： In a two-part adhesive composition wherein one-part comprises a polymerizable acrylic monomer and an organoboron amine complex and the second-part contains an organic acid destabilizer and optional acrylic polymer, the improvement wherein a transparent or clear bond is provided in the cured adhesive composition by having about 45% or more by weight of the total acrylic monomer in the composition comprising selected phenyl containing acrylic compounds.
摘要翻译： 在两部分粘合剂组合物中，其中一部分包含可聚合丙烯酸类单体和有机硼胺络合物，第二部分含有有机酸去稳定剂和任选的丙烯酸类聚合物，其改进在于固化粘合剂中提供透明或透明粘合 组合物通过在包含所选择的含苯基的丙烯酸化合物的组合物中具有约45重量％或更多的总丙烯酸类单体。
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公开(公告)号：US5143884A
公开(公告)日：1992-09-01
申请号：US810319
申请日：1991-12-19
IPC分类号： C09J4/00
CPC分类号： C09J4/00
摘要： A two-part initiator system useful in acrylic adhesive compositions comprising in one-part a stable organoboron amine complex and in the second part an organic acid destabilizer or activator. This initiator is particularly useful in elastomeric acrylic adhesive compositions and provides a fast, room temperature cure with good stability and exhibiting both high tensile strength and high peel strength.
摘要翻译： 用于丙烯酸粘合剂组合物的两部分引发剂体系包括一部分稳定的有机硼胺络合物，在第二部分中包含有机酸去稳定剂或活化剂。 该引发剂在弹性丙烯酸类粘合剂组合物中特别有用，并提供快速的室温固化，具有良好的稳定性，并具有高拉伸强度和高剥离强度。
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公开(公告)号：US4354008A
公开(公告)日：1982-10-12
申请号：US260968
申请日：1981-05-06
申请人： Martin M. Skoultchi
发明人： Martin M. Skoultchi
IPC分类号： C09J133/06 , C08L33/08
CPC分类号： C09J133/066
摘要： A pressure sensitive, hot melt adhesive is prepared by reacting a normally tacky acrylic-based random copolymer containing from 0.5 to 10% by weight of a chelating comonomer with a chelatable transition metal salt. Preferably the adhesives are oven cured for a short time after application. The chelating comonomer is a beta-hydroxypropyl (meth)acrylate ester of an ortho-hydroxy aromatic acid such as 2-hydroxy-3-(2-hydroxy-benzoyloxy)propyl methacrylate. The metallic salt (e.g. zirconium, ferric, cobalt, or aluminum acetylacetonate) contains a metal ion having a valence greater than 1 and a coordination number greater than 2 and an anion capable of forming a volatile by-product. One or more thermally reversible chelate rings incorporating the metal ion are formed thus crosslinking the polymer chains.
摘要翻译： 通过使含有0.5至10重量％的螯合共聚单体的常规粘性丙烯酸基无规共聚物与可螯合的过渡金属盐反应来制备压敏热熔粘合剂。 优选地，粘合剂在施用后经短时间烘箱固化。 螯合共聚单体是邻羟基芳族酸的β-羟丙酯（甲基）丙烯酸酯，例如甲基丙烯酸2-羟基-3-（2-羟基 - 苯甲酰氧基）丙酯。 金属盐（例如，锆，三价铁，钴或乙酰丙酮铝）含有价态大于1且配位数大于2的金属离子和能形成挥发性副产物的阴离子。 形成结合有金属离子的一个或多个热可逆螯合环，从而交联聚合物链。
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9.发明授权
公开(公告)号：US4054480A
公开(公告)日：1977-10-18
申请号：US579782
申请日：1975-05-22
IPC分类号： C08F20/00 , C08F20/10 , C08F290/00 , C08F299/00 , C09J4/00 , C09J4/02 , C09J5/04 , C08F2/00 , C08F3/62 , C08F18/00
CPC分类号： C09J4/00
摘要： Anaerobic curing compositions useful as anaerobic adhesives and sealants are described. These compositions comprise mixtures of polymerizable acrylic and substituted acrylic monomers together with a catalyst comprising an alpha-hydroxy sulfone compound. As an alternate embodiment of the invention, certain organic peroxides may be added to the composition to further prolong the shelf life thereof and to increase the shear strength of the resulting adhesive bond.
摘要翻译： 描述了用作厌氧粘合剂和密封剂的厌氧固化组合物。 这些组合物包括可聚合的丙烯酸和取代的丙烯酸单体与包含α-羟基砜化合物的催化剂的混合物。 作为本发明的替代实施方案，可以将某些有机过氧化物加入到组合物中以进一步延长其保质期并提高所得粘合剂粘合的剪切强度。
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公开(公告)号：US5106928A
公开(公告)日：1992-04-21
申请号：US692766
申请日：1991-04-29
CPC分类号： C09J4/00 , Y10T428/31855
摘要： A two-part initiator system useful in acrylic adhesive compositions comprising in one-part a stable organoboron amine complex and in the second part an organic acid destabilizer or activator. This initiator is particularly useful in elastomeric acrylic adhesive compositions and provides a fast, room temperature cure with good stability and exhibiting both high tensile strength and high peel strength.
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