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1.发明授权Melt-processible polymer composition comprising fluoropolymer having long chain branches 有权可熔融加工的聚合物组合物包含具有长链分支的含氟聚合物公开(公告)号：US07375157B2
公开(公告)日：2008-05-20
申请号：US10864054
申请日：2004-06-09
申请人： Stephen E. Amos , Klaus Hintzer , Harald Kaspar , Claude Lavallée
发明人： Stephen E. Amos , Klaus Hintzer , Harald Kaspar , Claude Lavallée
IPC分类号： C08L83/04
CPC分类号： C08L23/0815 , C08F214/182 , C08L27/12 , C08L27/16 , C08L27/18 , C08L67/04 , C08L71/02 , C08L2205/02 , C08L2205/03 , C08L2666/22 , C08L2666/04 , C08L2666/14 , C08L2666/18
摘要： A polymer melt additive that is suitable for use as a processing aid in the extrusion of a non-fluorinated polymer. The polymer melt additive composition includes a fluoropolymer that has a long chain branching index (LCBI) of at least 0.2 and a zero shear rate viscosity at 265° C. of not more than 107 Pa's. The polymer melt additive may additionally include other compounds such as, polyoxyalkylene polymer or polycaprolactone.
摘要翻译： 一种聚合物熔融添加剂，其适用于在非氟化聚合物的挤出中用作加工助剂。 聚合物熔融添加剂组合物包括具有至少0.2的长支链指数（LCBI）和265℃下的零剪切速率粘度为10Pa以下的含氟聚合物。 聚合物熔融添加剂可另外包括其它化合物，如聚氧化烯聚合物或聚己内酯。
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2.发明授权Polymer processing additive containing a multimodal fluoropolymer and melt processable thermoplastic polymer composition employing the same 有权含有多峰含氟聚合物和使用其的可熔融加工的热塑性聚合物组合物的聚合物加工添加剂公开(公告)号：US06277919B1
公开(公告)日：2001-08-21
申请号：US09311107
申请日：1999-05-13
申请人： Maria P. Dillon , Susan S. Woods , Kirsten J. Fronek , Claude Lavallée , Stephen E. Amos , Karl-Dieter Weilandt , Harald Kaspar , Bernhard Hirsch , Klaus Hintzer , Peter J. Scott
发明人： Maria P. Dillon , Susan S. Woods , Kirsten J. Fronek , Claude Lavallée , Stephen E. Amos , Karl-Dieter Weilandt , Harald Kaspar , Bernhard Hirsch , Klaus Hintzer , Peter J. Scott
IPC分类号： C08L2712
CPC分类号： C08L23/04 , C08L23/02 , C08L23/10 , C08L27/12 , C08L27/16 , C08L27/18 , C08L2205/02 , C08L2666/04
摘要： A polymer processing aid composition, a melt processable polymer composition that uses the polymer processing aid, and a method of improving the melt processability of a thermoplastic polymer are provided. The polymer processing aid composition comprises a multimodal fluoropolymer that preferably comprises interpolymerized units derived from an ethylenically unsaturated fluoromonomer tetrafluoroethylene and at least one ethylenically copolymerizable alpha-olefin monomer.
摘要翻译： 提供聚合物加工助剂组合物，使用聚合物加工助剂的可熔融加工的聚合物组合物和改进热塑性聚合物的熔融加工性能的方法。 聚合物加工助剂组合物包含多峰含氟聚合物，其优选包含衍生自烯键式不饱和氟单体四氟乙烯和至少一种烯键式可共聚的α-烯烃单体的共聚单元。
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3.发明授权Melt-processible fluoropolymers having long-chain branches, methods of preparing them and uses thereof 有权具有长链分支的可熔融加成的含氟聚合物，其制备方法和用途公开(公告)号：US08969500B2
公开(公告)日：2015-03-03
申请号：US12597022
申请日：2008-04-24
申请人： Klaus Hintzer , Harald Kaspar
发明人： Klaus Hintzer , Harald Kaspar
IPC分类号： C08F216/12 , C08F214/18 , C08F236/20 , C08K5/09 , C08K5/42
CPC分类号： C08F214/18 , C08F236/20 , C08K5/09 , C08K5/42
摘要： The present disclosure describes fluoropolymers having long chain branches and methods of making these fluoropolymers. These fluoropolymers may have improved melt processing properties. Shaped articles containing these fluoropolymers are also provided.
摘要翻译： 本公开描述了具有长链分支的含氟聚合物和制备这些含氟聚合物的方法。 这些含氟聚合物可具有改进的熔融加工性能。 还提供了含有这些含氟聚合物的成型制品。
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公开(公告)号：US20130281607A1
公开(公告)日：2013-10-24
申请号：US13995615
申请日：2011-12-21
申请人： Klaus Hintzer , Michael Juergens , Gunther J. Kaempf , Harald Kaspar , Kai H. Lochhaas , Andre Streiter , Oleg Shyshkov , Tilman C. Zipplies , Herbert Koenigsmann
发明人： Klaus Hintzer , Michael Juergens , Gunther J. Kaempf , Harald Kaspar , Kai H. Lochhaas , Andre Streiter , Oleg Shyshkov , Tilman C. Zipplies , Herbert Koenigsmann
IPC分类号： C25B3/08
CPC分类号： C08F6/003 , C02F1/26 , C02F1/461 , C02F2001/46138 , C02F2001/46147 , C08F2/10 , C08F2/20 , C08F14/08 , C08F14/18 , C08F2800/10 , Y02P20/582 , C08F2/24
摘要： Described herein is a composition comprising an aqueous polymerization reaction product of fluorinated monomers and wherein the polymerization is initiated (i) in the absence of a fluorinated emulsifier and whereby no fluorinated emulsifier is added during polymerization or (ii) in the presence of an fluorinated emulsifier selected from: [Rf—O-L-COO-]i Xi+ (I) wherein L represents a linear or branched, non-fluorinated, partially fluorinated, or fully fluorinated alkylene group, Rf represents a linear or branched partially or fully fluorinated aliphatic group or a linear or branched partially or fully fluorinated aliphatic group interrupted with at least one oxygen atom, Xi+ represents a cation having the valence i and i is 1, 2 or 3; wherein the reaction product and/or the resulting aqueous phase are substantially free of di- and tri-alkylamines and substantially free of low molecular weight fluoroorganic compounds and methods thereof.
摘要翻译： 本文描述的是包含氟化单体的水性聚合反应产物的组合物，其中聚合反应开始于（i）在不存在氟化乳化剂的情况下，并且由此在聚合过程中不加入氟化乳化剂，或（ii）在氟化乳化剂存在下 选自：[Rf-OL-COO-] i Xi +（I）其中L表示直链或支链，非氟化，部分氟化或完全氟化的亚烷基，Rf表示直链或支链部分或完全氟化的脂族基团或 间隔有至少一个氧原子的直链或支链部分或完全氟化的脂肪族基团，X i +表示i为i且i为1,2或3的阳离子; 其中所述反应产物和/或所得水相基本上不含二烷基胺和三烷基胺，并且基本上不含低分子量氟代有机化合物及其方法。
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5.发明申请PEROXIDE CURABLE FLUOROELASTOMERS CONTAINING MODIFIERS AND IODINE OR BROMINE ENDGROUPS 有权含有改性剂和碘或溴的过氧化物可固化荧光体公开(公告)号：US20130129954A1
公开(公告)日：2013-05-23
申请号：US13813691
申请日：2011-07-26
IPC分类号： C08F14/18
CPC分类号： C08F14/18 , C08F214/18 , C08F214/184 , C08F214/222 , C08F214/262 , C08F214/28 , Y10T428/139
摘要： Provided are curable fluoroelastomers. Further provided are methods of making the curable elastomers, curable fluoroelastomer compositions and methods of making them and shaped articles made from the curable fluoroelastomer compositions.
摘要翻译： 提供可固化的含氟弹性体。 进一步提供制备可固化弹性体，可固化含氟弹性体组合物及其制备方法和由可固化含氟弹性体组合物制成的成型制品的方法。
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6.发明申请POLYMERIZABLE COMPOSITIONS FREE OF ORGANIC EMULSIFIER AND POLYMERS AND METHODS OF MAKING THEREOF 审中-公开无机有机聚合物和聚合物的可聚合组合物及其制备方法公开(公告)号：US20130090441A1
公开(公告)日：2013-04-11
申请号：US13704064
申请日：2011-06-09
申请人： Jimmie R. Baran, JR. , Duane D. Fansler , Klaus Hintzer , William J. Hunt , Harald Kaspar , Tilman C. Zipplies
发明人： Jimmie R. Baran, JR. , Duane D. Fansler , Klaus Hintzer , William J. Hunt , Harald Kaspar , Tilman C. Zipplies
IPC分类号： C08F2/10
CPC分类号： C08F2/10 , C08F2/20 , C08F2/22 , C08K3/36 , C08K2201/011
摘要： Described herein is a polymerizable composition substantially free of an organic emulsifier, methods of making, and articles thereof. The polymerizable composition comprises: a continuous phase; a polymerizable monomer; an initiator; and inorganic nanoparticles, wherein the inorganic nanoparticles are substantially free of groups that will copolymerize with the polymerizable monomer.
摘要翻译： 本文描述的是基本上不含有机乳化剂，制备方法及其制品的可聚合组合物。 可聚合组合物包括：连续相; 可聚合单体; 发起者 和无机纳米颗粒，其中无机纳米颗粒基本上不含可与可聚合单体共聚的基团。
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公开(公告)号：US08404790B2
公开(公告)日：2013-03-26
申请号：US13403724
申请日：2012-02-23
申请人： Klaus Hintzer , Michael Jürgens , Harald Kaspar , Kai H. Lochhaas , Andreas R. Maurer , Werner Schwertfeger , Tilman C. Zipplies
发明人： Klaus Hintzer , Michael Jürgens , Harald Kaspar , Kai H. Lochhaas , Andreas R. Maurer , Werner Schwertfeger , Tilman C. Zipplies
IPC分类号： C08F14/18
摘要： A method of making a fluoropolymer in the presence of a fluorinated surfactant.
摘要翻译： 在氟化表面活性剂存在下制备含氟聚合物的方法。
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公开(公告)号：US07795332B2
公开(公告)日：2010-09-14
申请号：US11420416
申请日：2006-05-25
申请人： Klaus Hintzer , Michael Jürgens , Harald Kaspar , Herbert Koenigsmann , Kai Helmut Löchhaas , Andreas R. Maurer , Werner Schwertfeger , Tilman Zipplies , George G. I. Moore , Jay F. Schulz , Richard M. Flynn
发明人： Klaus Hintzer , Michael Jürgens , Harald Kaspar , Herbert Koenigsmann , Kai Helmut Löchhaas , Andreas R. Maurer , Werner Schwertfeger , Tilman Zipplies , George G. I. Moore , Jay F. Schulz , Richard M. Flynn
IPC分类号： C08L1/00
CPC分类号： C08L27/12 , C08L71/02 , Y02C20/30 , C08L2666/22
摘要： A method for removing a fluorinated carboxylic acid or salt thereof from an aqueous liquid by contacting the aqueous liquid with adsorbent particles. The fluorinated carboxylic acid or salt thereof is selected from the group consisting of partially fluorinated carboxylic acids or salts thereof and fully fluorinated carboxylic acids or salts thereof.
摘要翻译： 通过使含水液体与吸附剂颗粒接触从水性液体中除去氟化羧酸或其盐的方法。 氟化羧酸或其盐选自部分氟化的羧酸或其盐和完全氟化的羧酸或其盐。
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9.发明申请Melt-Processible Fluoropolymers Having Long-Chain Branches, Methods of Preparing Them and Uses Thereof 有权具有长链分支的可熔融加工的含氟聚合物，其制备方法和用途公开(公告)号：US20100121012A1
公开(公告)日：2010-05-13
申请号：US12597022
申请日：2008-04-24
申请人： Klaus Hintzer , Harald Kaspar
发明人： Klaus Hintzer , Harald Kaspar
IPC分类号： C08F14/18
CPC分类号： C08F214/18 , C08F236/20 , C08K5/09 , C08K5/42
摘要： The present disclosure describes fluoropolymers having long chain branches and methods of making these fluoropolymers. These fluoropolymers may have improved melt processing properties. Shaped articles containing these fluoropolymers are also provided.
摘要翻译： 本公开描述了具有长链分支的含氟聚合物和制备这些含氟聚合物的方法。 这些含氟聚合物可具有改进的熔融加工性能。 还提供了含有这些含氟聚合物的成型制品。
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公开(公告)号：US20070015864A1
公开(公告)日：2007-01-18
申请号：US11420386
申请日：2006-05-25
申请人： Klaus Hintzer , Michael Jurgens , Harald Kaspar , Herbert Koenigsmann , Kai Lochhaas , Andreas Maurer , Werner Schwertfeger , Tilman Zipplies , Ludwig Mayer , Michael Dadalas , George Moore , Jay Schulz , Richard Flynn
发明人： Klaus Hintzer , Michael Jurgens , Harald Kaspar , Herbert Koenigsmann , Kai Lochhaas , Andreas Maurer , Werner Schwertfeger , Tilman Zipplies , Ludwig Mayer , Michael Dadalas , George Moore , Jay Schulz , Richard Flynn
IPC分类号： C08L27/12
CPC分类号： C08L27/12 , C08L71/02 , Y02C20/30 , C08L2666/22
摘要： A method of making a fluoropolymer dispersion by first providing a fluoropolymer dispersion comprising fluoropolymer particles and one or more fluorinated surfactants selected from fluorinated carboxylic acids or salts thereof having the general formula: [Rf—O-L-COO−]iXi+ (I) wherein L represents a linear partially or fully fluorinated alkylene group or an aliphatic hydrocarbon group, Rf represents a linear partially or fully fluorinated aliphatic group or a linear partially or fully fluorinated aliphatic group interrupted with one or more oxygen atoms, Xi+ represents a cation having the valence i and i is 1, 2 or 3; Then adding one or more non-fluorinated surfactants selected from anionic and non-ionic surfactants followed by reducing the total amount of the one or more fluorinated surfactants to an amount of not more than 500 ppm, for example not more than 250 ppm based on the total weight of the dispersion while maintaining or increasing the amount of solids in the dispersion.
摘要翻译： 首先提供含氟聚合物颗粒和一种或多种选自氟化羧酸或其盐的含氟表面活性剂的含氟聚合物分散体的制备氟聚合物分散体的方法，所述氟化聚合物分散体具有以下通式：<？in-line-formula description =“In-Line Formulas” （I）结束=“引导”→[R f> OL O> - ））））））））））））））））））））））））） <？in-line-formula description =“In-line formula”end =“tail”？>其中L表示线性部分或完全氟化的亚烷基或脂族烃基，R f表示 线性部分或全氟化的脂族基团或被一个或多个氧原子间隔的线性部分或完全氟化的脂肪族基团，表示i为i且i为1,2或3的阳离子; 然后加入一种或多种选自阴离子和非离子表面活性剂的非氟化表面活性剂，然后将一种或多种氟化表面活性剂的总量减少至不超过500ppm，例如不超过250ppm，基于 分散体的总重量，同时保持或增加分散体中固体的量。
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