High-solids coating composition for improved rheology control containing
inorganic microparticles
    2.
    发明授权
    High-solids coating composition for improved rheology control containing inorganic microparticles 失效
    用于改善含有无机微粒的流变学控制的高固含量涂料组合物

    公开(公告)号:US4526910A

    公开(公告)日:1985-07-02

    申请号:US529312

    申请日:1983-09-06

    IPC分类号: C09D7/12 C08K3/36

    摘要: Disclosed is an essentially solvent-based, organic, high-solids coating composition containing (A) a film-forming binder system containing a crosslinkable resin having a weight average molecular weight of from about 500 to about 10,000; (B) substantially colorless, substantially inorganic microparticles stably dispersed in the coating composition; and (C) a solvent system for the crosslinkable resin. The substantially inorganic microparticles prior to incorporation in the coating composition range in size from about 1 to about 150 nanometers and are in the form of a sol of the microparticles in which the surface of the inorganic microparticles is essentially free of carbon-containing molecules chemically bonded to the inorganic microparticles.

    摘要翻译: 公开了一种基本上溶剂的有机高固含量涂料组合物,其包含(A)含有重均分子量为约500至约10,000的交联性树脂的成膜粘合剂体系; (B)稳定分散在涂料组合物中的基本上无色的,基本上无机的微粒; 和(C)可交联树脂的溶剂体系。 在掺入涂料组合物中之前,基本上无机微粒的尺寸范围为约1至约150纳米,并且为微粒溶胶的形式,其中无机微粒的表面基本上不含化学键合的含碳分子 到无机微粒。

    Color plus clear coating system utilizing inorganic microparticles
    3.
    发明授权
    Color plus clear coating system utilizing inorganic microparticles 失效
    彩色加透明涂层系统利用无机微粒

    公开(公告)号:US4652470A

    公开(公告)日:1987-03-24

    申请号:US842507

    申请日:1986-03-21

    摘要: Disclosed is a method of coating a substrate comprising the steps of (A) coating the substrate with one or more applications of a basecoating composition containing (1) an organic film-forming resin, (2) substantially colorless, substantially inorganic microparticles stably dispersed in the basecoating composition, (3) a solvent system for the film-forming resin, and (4) pigment particles to form a basecoat; and (B) coating the basecoat with one or more applications of a topcoating composition containing (1) an organic film-forming resin, and (2) a solvent system for the organic film-forming resin of the topcoating composition, to form a transparent topcoat. The substantially inorganic microparticles prior to incorporation in the basecoating composition range in size from about 1 to about 150 nanometers.

    摘要翻译: 公开了一种涂覆基材的方法,其包括以下步骤:(A)用一种或多种底漆涂料组合物涂覆基材,所述底漆组合物含有(1)有机成膜树脂,(2)基本上无色的,基本上无机的微粒,其稳定分散在 底漆组合物,(3)成膜树脂的溶剂体系,(4)颜料颗粒形成底涂层; 和(B)用一种或多种涂覆底涂层的表面涂层组合物涂覆,所述表面涂层组合物含有(1)有机成膜树脂,和(2)表面涂料组合物的有机成膜树脂的溶剂体系,形成透明的 面漆。 在引入底漆组合物之前,基本上无机微粒的尺寸范围为约1至约150纳米。

    Pigmentary hardener-containing curable silicate compositions
    7.
    发明授权
    Pigmentary hardener-containing curable silicate compositions 失效
    含有色素固化剂的可固化硅酸盐组合物

    公开(公告)号:US4240838A

    公开(公告)日:1980-12-23

    申请号:US12269

    申请日:1979-02-15

    CPC分类号: C04B28/24 C09D1/02

    摘要: This invention relates to pigmentary hardener-containing curable silicate compositions having improved water resistance, wherein the pigmentary hardener has the formula M.sub.x M.sub.y 'O.sub.z where M is a divalent or trivalent metal ion, M' is an ion of a metal from Groups III, IV or VIB of the Periodic Table of Elements, provided M and M' are not the same metal ion, x is 1 or 2, y is 1, 2 or 3 and z is an integer the value of which satisfies the oxidation state of the pigmentary hardener.

    摘要翻译: 本发明涉及具有改善的耐水性的含颜料硬化剂的可固化硅酸盐组合物,其中所述颜料硬化剂具有式M x M y O z,其中M是二价或三价金属离子,M'是来自III,IV族的金属的离子, 元素周期表的VIB,M和M'不是相同的金属离子,x是1或2,y是1,2或3,z是一个整数,其值满足颜料硬化剂的氧化态 。

    Curable compositions comprising aqueous solutions of water-soluble
silicates and water-soluble latent insolubilizing agents
    8.
    发明授权
    Curable compositions comprising aqueous solutions of water-soluble silicates and water-soluble latent insolubilizing agents 失效
    包含水溶性硅酸盐水溶液和水溶性潜在不溶解剂的可固化组合物

    公开(公告)号:US4137087A

    公开(公告)日:1979-01-30

    申请号:US740983

    申请日:1976-11-11

    IPC分类号: C04B28/26 C09D1/04

    CPC分类号: C04B28/26

    摘要: Curable compositions which form cured products having excellent durability, stain resistance, resistance to heat and flame, and water resistance as well as other desirable properties are prepared by forming aqueous solutions of water-soluble silicates and water-soluble latent insolubilizing agents formed from a metal ion selected from the group consisting of Al.sup.+++, Fe.sup.+++, Cr.sup.+++ and Sn.sup.++ and a ligand selected from the group consisting of ethylenediaminetetraacetate, diethylenetriaminepentaacetate, N-(hydroxyethyl)ethylenediaminetriacetate, nitrilotriacetate and 1,3-propanediaminetetraacetate.The compositions have excellent stability and may be employed in various applications such as coatings, castings, and molding applications. The compositions are particularly useful in coating applications.

    摘要翻译: 通过形成由水溶性硅酸盐形成的水溶液和由金属形成的水溶性潜在不溶解剂,可以制备形成具有优异耐久性,耐污染性,耐热性和耐火性,耐水性以及其它所需性能的固化产物的可固化组合物 离子选自Al +++,Fe +++,Cr +++和Sn ++,以及选自乙二胺四乙酸酯,二亚乙基三胺五乙酸酯,N-(羟乙基)乙二胺三乙酸酯,次氮基三乙酸酯和1,3-丙二胺四乙酸酯的配体。

    Metal condensed phosphate hardener coated with reaction product from a
metal aluminate and/or a metal borate
    9.
    发明授权
    Metal condensed phosphate hardener coated with reaction product from a metal aluminate and/or a metal borate 失效
    用金属铝酸盐和/或金属硼酸盐涂覆有反应产物的金属缩合磷酸盐固化剂

    公开(公告)号:US4383866A

    公开(公告)日:1983-05-17

    申请号:US407021

    申请日:1982-08-11

    摘要: Disclosed is a metal condensed phosphate comprising a core of metal condensed phosphate and a coating on the core comprising a reaction product of a metallate and acid. The amount of the reaction product comprising the coating generally ranges from about 0.1 percent to about 50 percent by weight based on the combined weight of the metal condensed phosphate and the reaction product.Also disclosed is a method of preparing a coated, metal condensed phosphate comprising combining an aqueous slurry of metal condensed phosphate with an aqueous metallate while maintaining the pH of the slurry in a range of from about 4 to about 10.

    摘要翻译: 公开了一种金属缩合磷酸盐,其包含金属缩合磷酸盐的核心和核心上的包衣,其包含金属盐和酸的反应产物。 基于金属缩合磷酸盐和反应产物的总重量,包含涂层的反应产物的量通常为约0.1重量%至约50重量%。 还公开了一种制备涂覆的金属缩合磷酸盐的方法,包括将金属缩合磷酸盐的水性浆料与含水金属盐组合,同时将浆料的pH保持在约4至约10的范围内。

    Semisolid water-based coating compositions
    10.
    发明授权
    Semisolid water-based coating compositions 失效
    半固体水性涂料组合物

    公开(公告)号:US4304693A

    公开(公告)日:1981-12-08

    申请号:US132918

    申请日:1980-03-24

    IPC分类号: C09D5/04 C09D201/00 C08L1/28

    CPC分类号: C09D5/04 C09D201/00

    摘要: This invention relates to coating compositions which are "solid" prior to application, yet, which when applied to a substrate, flow and level in a manner similar to conventional coating compositions. The coating compositions of the invention comprise a gelled coating composition, capable of application and flow on a solid substrate comprising: (a) a water reducible polymer, (b) water, (c) an electrolyte, (d) a colloidal gelling agent, gelable by interaction with the electrolyte, in an amount sufficient, when interacted with said electrolyte, to gel the composition to form a stable semisolid and to provide a composition reducible to a coating application viscosity upon the application of a relatively small shearing force at a relatively small shearing rate; which gelled coating composition, after being sheared to a coating application viscosity, does not recover substantial colloidal gelling agent contributed gel structure and (e) an amount of a gel structure formation rate increasing compound which corresponds, or is hydrolyzable in situ to effectively provide a compound which corresponds to the formula:R.sub.x M(OH).sub.y-xwhere M is selected from boron, aluminum, silicon, tin, titanium, zirconium, vanadium, niobium, hafnium, and tatalum; x is 0 or 1; y is the valence of M; and R is an organic moiety attached to M through a carbon-M bond; condensate thereof; or a combination thereof; said amount being an amount sufficient to decrease the time required to form said gelled composition.

    摘要翻译: 本发明涉及在施用之前为“固体”的涂料组合物,但是当以与常规涂料组合物相似的方式将其施用于基材时,流动和水平。 本发明的涂料组合物包含能够在固体基质上施用和流动的凝胶涂料组合物,其包含:(a)可水稀释的聚合物,(b)水,(c)电解质,(d)胶态胶凝剂, 当与所述电解质相互作用时,其与电解质相互作用可以胶凝,以使组合物凝胶化以形成稳定的半固体,并且在相对较小的剪切力下施加可降低涂层应用粘度的组合物 小剪切速率; 胶凝涂料组合物在经过剪切涂布后的粘度下,不能回收大量的胶凝胶凝胶作用的凝胶结构和(e)一定量的凝胶结构形成速率增加化合物,其对应于或可水解原位以有效提供 化合物,其对应于下式:RxM(OH)yx其中M选自硼,铝,硅,锡,钛,锆,钒,铌,铪和钽; x为0或1; y是M的化合价; 并且R是通过碳-M键与M连接的有机部分; 冷凝物 或其组合; 所述量是足以减少形成所述胶凝组合物所需时间的量。