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    Method and apparatus for regenerating catalyst during oxygenates to olefins reaction
    6.
    发明授权
    Method and apparatus for regenerating catalyst during oxygenates to olefins reaction 有权
    在含氧化合物到烯烃反应过程中再生催化剂的方法和装置

    公开(公告)号：US08178741B2

    公开(公告)日：2012-05-15

    申请号：US12793340

    申请日：2010-06-03

    申请人： Chunshe J. Cao ,  James H. Beech, Jr. ,  Michael P. Nicoletti ,  Thomas H. Colle ,  Teng Xu ,  Stephen N. Vaughn

    发明人： Chunshe J. Cao ,  James H. Beech, Jr. ,  Michael P. Nicoletti ,  Thomas H. Colle ,  Teng Xu ,  Stephen N. Vaughn

    IPC分类号： C07C1/00 ,  B01J20/34 ,  B01J19/00

    CPC分类号： B01J38/02 ,  B01J29/90 ,  B01J38/32 ,  C07C1/20 ,  C07C2529/85 ,  Y02P20/584 ,  C07C11/02

    摘要： Disclosed herein is a method of recovery of the activity of a molecular sieve catalyst following use of the catalyst in an OTO conversion process. This is achieved by a regeneration apparatus and a method of regenerating a molecular sieve catalyst, comprising two stages. In a pretreatment stage, the catalyst is pretreated under pretreatment conditions by heating the catalyst to a temperature of between 320° C. to 700° C. in an oxygen depleted medium for a residence time of between 1 minute to two hours; and, in a regeneration stage, the catalyst is regenerated under regeneration conditions by heating the catalyst at a temperature of between 200° C. to 700° C. in an oxidizing medium for a residence time of between 1 to 60 minutes.

    摘要翻译： 本文公开了在OTO转化方法中使用催化剂后回收分子筛催化剂的活性的方法。 这是通过再生装置和再生分子筛催化剂的方法实现的，包括两个阶段。 在预处理阶段，催化剂在预处理条件下通过将催化剂在耗氧贫乏的介质中在320℃至700℃之间的温度下进行预处理，停留时间为1分钟至2小时; 并且在再生阶段，催化剂在再生条件下通过在氧化介质中在200℃至700℃的温度下加热催化剂，停留时间为1至60分钟而再生。

    Method And Apparatus For Regenerating Catalyst During Oxygenates To Olefins Reaction
    7.
    发明申请
    Method And Apparatus For Regenerating Catalyst During Oxygenates To Olefins Reaction 有权
    氧化催化剂再生催化剂对烯烃反应的方法与装置

    公开(公告)号：US20110021857A1

    公开(公告)日：2011-01-27

    申请号：US12793340

    申请日：2010-06-03

    申请人： Chunshe J. Cao ,  James H. Beech, JR. ,  Michael P. Nicoletti ,  Thomas H. Colle ,  Teng Xu ,  Stephen N. Vaughn

    发明人： Chunshe J. Cao ,  James H. Beech, JR. ,  Michael P. Nicoletti ,  Thomas H. Colle ,  Teng Xu ,  Stephen N. Vaughn

    IPC分类号： C07C1/00 ,  B01J20/34 ,  B01J19/00

    CPC分类号： B01J38/02 ,  B01J29/90 ,  B01J38/32 ,  C07C1/20 ,  C07C2529/85 ,  Y02P20/584 ,  C07C11/02

    摘要： Disclosed herein is a method of recovery of the activity of a molecular sieve catalyst following use of the catalyst in an OTO conversion process. This is achieved by a regeneration apparatus and a method of regenerating a molecular sieve catalyst, comprising two stages. In a pretreatment stage, the catalyst is pretreated under pretreatment conditions by heating the catalyst to a temperature of between 320° C. to 700° C. in an oxygen depleted medium for a residence time of between 1 minute to two hours; and, in a regeneration stage, the catalyst is regenerated under regeneration conditions by heating the catalyst at a temperature of between 200° C. to 700° C. in an oxidizing medium for a residence time of between 1 to 60 minutes.

    摘要翻译： 本文公开了在OTO转化方法中使用催化剂后回收分子筛催化剂的活性的方法。 这是通过再生装置和再生分子筛催化剂的方法实现的，包括两个阶段。 在预处理阶段，催化剂在预处理条件下通过将催化剂在耗氧贫乏的介质中在320℃至700℃之间的温度下进行预处理，停留时间为1分钟至2小时; 并且在再生阶段，催化剂在再生条件下通过在氧化介质中在200℃至700℃的温度下加热催化剂，停留时间为1至60分钟而再生。

    Catalyst pretreatment with C4-C7 olefins in an oxygenate to olefins reaction system
    9.
    发明授权
    Catalyst pretreatment with C4-C7 olefins in an oxygenate to olefins reaction system 失效
    催化剂在含氧化合物到烯烃反应体系中用C4-C7烯烃预处理

    公开(公告)号：US07057083B2

    公开(公告)日：2006-06-06

    申请号：US10712952

    申请日：2003-11-12

    申请人： Teng Xu ,  Nicolas P. Coute ,  Kenneth Ray Clem ,  Keith H. Kuechler

    发明人： Teng Xu ,  Nicolas P. Coute ,  Kenneth Ray Clem ,  Keith H. Kuechler

    IPC分类号： C07C1/00

    CPC分类号： C07C1/20 ,  B01J29/85 ,  C07C2529/84 ,  C07C2529/85 ,  Y02P30/42 ,  C07C11/02 ,  C07C11/08

    摘要： This invention relates to processes for converting oxygenates to olefins that include a step of pretreating molecular sieve used in the conversion reaction with a C4–C7 olefin composition, which contains one or more C4–C7 olefins. Fresh or regenerated molecular sieve, which is low in carbon content, is contacted or pretreated with the olefin composition to form a hydrocarbon co-catalyst within the pore structure of the molecular sieve, and the pretreated molecular sieve containing the co-catalyst is used to convert oxygenate to a lighter olefin product.

    摘要翻译： 本发明涉及将含氧化合物转化为烯烃的方法，其包括用C 4 -C 7烯烃组合物预处理转化反应中使用的分子筛的步骤，其中含有一个 或更多的C 4 -C 7烯烃。 碳含量低的新鲜或再生分子筛与烯烃组合物接触或预处理，以在分子筛的孔结构内形成烃助催化剂，并将含有助催化剂的预处理分子筛用于 将含氧化合物转化为较轻的烯烃产物。

    Catalyst pretreatment with dimethyl ether in an oxygenate to olefins reaction system
    10.
    发明授权
    Catalyst pretreatment with dimethyl ether in an oxygenate to olefins reaction system 失效
    催化剂预处理用二甲醚在含氧化合物到烯烃反应体系中

    公开(公告)号：US07045672B2

    公开(公告)日：2006-05-16

    申请号：US10712668

    申请日：2003-11-12

    申请人： Teng Xu ,  Kenneth Ray Clem ,  Keith H. Kuechler

    发明人： Teng Xu ,  Kenneth Ray Clem ,  Keith H. Kuechler

    IPC分类号： C07C1/00

    CPC分类号： C07C1/20 ,  B01J29/85 ,  C07C2529/84 ,  C07C2529/85 ,  Y02P20/52 ,  Y02P30/42 ,  C07C11/06 ,  C07C11/04 ,  C07C11/02

    摘要： This invention relates to processes for converting oxygenates to olefins and olefins to polyolefins. The processes include a step of pretreating molecular sieve used in the conversion of oxygenate to olefin with a dimethyl ether composition. Fresh or regenerated molecular sieve, which is low in carbon content, is contacted or pretreated with the dimethyl ether composition to form a hydrocarbon co-catalyst within the pore structure of the molecular sieve, and the pretreated molecular sieve containing the co-catalyst is used to convert oxygenate to a lighter olefin product.

    摘要翻译： 本发明涉及将含氧化合物转化为烯烃和烯烃到聚烯烃的方法。 该方法包括用二甲基醚组合物预处理用于将含氧化合物转化为烯烃的分子筛的步骤。 碳含量低的新鲜或再生分子筛与二甲醚组合物接触或预处理，以在分子筛的孔结构内形成烃助催化剂，并使用含有助催化剂的预处理分子筛 将含氧化合物转化为较轻的烯烃产物。