-
公开(公告)号：US4196002A
公开(公告)日：1980-04-01
申请号：US953986
申请日：1978-10-23
申请人： Steven R. Levinson , Anthony Adin
发明人： Steven R. Levinson , Anthony Adin
CPC分类号： G03C1/83 , G03C1/49854
摘要： A photothermographic element can comprise a support and on the support or in the support an antihalation or filter component that comprises a heat bleachable material comprising (i) at least one hexaarylbiimidazole with (ii) at least one dye, especially an antihalation or filter dye, that is reactive with the product of the hexaarylbiimidazole formed upon heating the material to a temperature above about 90.degree. C. This provides an antihalation or filter material that becomes at least 40% colorless within about 20 minutes, typically within about 30 seconds, upon heating to a temperature as described. The antihalation or filter material can be a heat bleachable dye layer of a photothermographic element.
摘要翻译： 光热敏成像元件可以包括支撑体，支撑体和载体上的防晕或过滤组分，其包含热可漂洗材料，其包含（i）至少一种六芳基联咪唑与（ii）至少一种染料，特别是防晕或过滤染料， 其与在加热材料时形成的六芳基联咪唑的产物反应至高于约90℃的温度。这提供了防光或过滤材料，其在加热时在约20分钟内，通常在约30秒内变成至少40％无色 达到所述的温度。 防晕或过滤材料可以是光热敏成像元件的热可漂洗染料层。
-
2.发明授权Heat sensitive reactive products of hexaarylbiimidazole and antihalation dyes 失效六芳基联咪唑和防晕晕染料的热敏反应产物
公开(公告)号：US4201590A
公开(公告)日：1980-05-06
申请号：US954011
申请日：1978-10-23
申请人： Steven R. Levinson , Anthony Adin
发明人： Steven R. Levinson , Anthony Adin
CPC分类号： G03C1/49854 , G03C1/83 , Y10S430/165
摘要： A heat bleachable material comprises (i) at least one hexaarylbiimidazole with (ii) at least one dye, especially an antihalation or filter dye, that is reactive with the product of the hexaarylbiimidazole formed upon heating the material to a temperature above about 90.degree. C. This provides a material that becomes at least 40% colorless within about 20 minutes, typically within about 30 seconds, upon heating to a temperature as described. The dye-containing material is especially useful for antihalation and filter purposes in a photographic element. The material can be a heat bleachable dye layer of a photothermographic element. The heat bleachable dye layer can also be useful in a thermographic element.
摘要翻译： 热可漂洗材料包括（i）至少一种六芳基联咪唑与（ii）至少一种染料，特别是防晕或过滤染料，其与加热材料时形成的六芳基联咪唑的产物反应至高于约90℃ 这提供了在加热到如上所述的温度时在约20分钟内，通常在约30秒内变成至少40％无色的材料。 含染料的材料在照相元件中特别适用于防晕和过滤目的。 该材料可以是光热敏成像元件的热漂白染料层。 热可漂洗染料层也可用于热成像元件。
-
公开(公告)号：US5013642A
公开(公告)日：1991-05-07
申请号：US437004
申请日：1989-11-15
CPC分类号： G03C1/29 , Y10S430/145
摘要： A photographic element is disclosed comprising a support having thereon a silver halide emulsion layer spectrally sensitized with(a) a first sensitizing dye according to the formula: ##STR1## Z.sub.1 and Z.sub.2 each independently represents the atoms necessary to complete a substituted or unsubstituted 5- or 6-membered heterocyclic nucleus,R.sub.1 and R.sub.2 each independently represents substituted or unsubstituted alkyl or substituted or unsubstituted aryl.R.sub.3, R.sub.4, R.sub.5, and R.sub.6 each independently represents hydrogen, substituted or unsubstituted alkyl, substituted or unsubstituted aryl, andX represents a counterion, and(b) a second sensitizing dye having a maximum sensitivity at a wavelength of about 5 to 100 nm less than the wavelength of maximum sensitivity of the first sensitizing dye.
-
公开(公告)号：US4334005A
公开(公告)日：1982-06-08
申请号：US20898
申请日：1979-03-15
申请人： Anthony Adin , James C. Fleming
发明人： Anthony Adin , James C. Fleming
CPC分类号： G03C1/67 , Y10S430/137
摘要： A radiation-sensitive element is disclosed including a radiation-sensitive layer comprised of a cobalt(III)complex and a photoreductant. A process is disclosed in which the photoreductant is converted to a reducing agent by exposure to electromagnetic radiation longer than 300 nanometers. The reducing agent is then reacted with a cobalt(III)complex. Images can be recorded directly within the radiation-sensitive layer or in a separate image-recording element or layer by use of the residual cobalt(III)complex not exposed or one or more of the reaction products produced by exposure. By using the ammonia liberated from ammine ligand containing cobalt(III)complexes on exposure in combination with imagewise and uniform exposures, positive or negative images can be formed in diazo image-recording layers or elements associated with the radiation-sensitive layer. By the selection of amine-responsive reducing agent precursors, the amines released by the cobalt(III)complexes cause an amplified image.
摘要翻译： 公开了一种辐射敏感元件，其包括由钴（III）络合物和光致感光体组成的辐射敏感层。 公开了一种方法，其中通过暴露于长于300纳米的电磁辐射将光致感光体转化为还原剂。 然后还原剂与钴（III）络合物反应。 可以通过使用未暴露的残留的钴（III）络合物或通过曝光产生的一种或多种反应产物，将图像直接记录在辐射敏感层内或在单独的图像记录元件或层中。 通过使用从暴露于曝光后的氨基配体释放的氨与成像均匀的曝光结合使用，可以在重叠图像记录层或与辐射敏感层相关的元件上形成正或负的图像。 通过选择胺响应性还原剂前体，由钴（III）络合物释放的胺引起放大图像。
-
5.发明授权Cobalt (III) complex imaging compositions having improved photographic properties 失效具有改善的照相特性的复合成像组合物（III）
公开(公告)号：US4292399A
公开(公告)日：1981-09-29
申请号：US87191
申请日：1979-10-22
申请人： Anthony Adin
发明人： Anthony Adin
CPC分类号： G03C1/67 , Y10S430/137
摘要： There is disclosed an image-forming composition and element comprising a cobalt(III) complex, a reducing agent precursor which, in the presence of reduction products of the complex, forms a reducing agent for the complex, and an organic oxidizing agent to improve the image properties of the composition.
摘要翻译： 公开了一种成像组合物和元素，其包含钴（III）络合物，还原剂前体，其在络合物的还原产物存在下形成络合物的还原剂和有机氧化剂以改善 图像属性的组成。
-
公开(公告)号：US4273860A
公开(公告)日：1981-06-16
申请号：US971460
申请日：1978-12-20
申请人： Anthony Adin
发明人： Anthony Adin
CPC分类号： G03C1/67 , G03C5/56 , Y10S430/137
摘要： There is disclosed a cobalt(III) complex-containing photographic composition, element and process which can be made negative-working or positive-working. Featured are an exposure activatible image precursor composition and a photoinhibitor composition capable of inhibiting image formation in the image precursor composition.
摘要翻译： 公开了一种含有钴（III）配合物的照相组合物，可以制成负性或正性的元素和方法。 特征是能够抑制图像前体组合物中的图像形成的曝光活性图像前体组合物和光抑制剂组合物。
-
7.发明授权CO(III) Complex containing radiation sensitive element with diazo recording layer 失效CO（III）复合物含有具有重氮记录层的辐射敏感元件
公开(公告)号：US4195998A
公开(公告)日：1980-04-01
申请号：US846240
申请日：1977-10-27
申请人： Anthony Adin , James C. Fleming
发明人： Anthony Adin , James C. Fleming
摘要： A radiation-sensitive element is disclosed including a radiation-sensitive layer comprised of a cobalt(III)complex and a photoreductant. A process is disclosed in which the photoreductant is converted to a reducing agent by exposure to electromagnetic radiation longer than 300 nanometers. The reducing agent is then reacted with a cobalt(III)complex. Images can be recorded directly within the radiation-sensitive layer or in a separate image-recording element or layer by use of the residual cobalt(III)complex not exposed or one or more of the reaction products produced by exposure. By using the ammonia liberated from ammine ligand-containing cobalt(III)complexes on exposure in combination with imagewise and uniform exposures, positive or negative images can be formed in diazo image-recording layers or elements associated with the radiation-sensitive layer.
摘要翻译： 公开了一种辐射敏感元件，其包括由钴（III）络合物和光致感光体组成的辐射敏感层。 公开了一种方法，其中通过暴露于长于300纳米的电磁辐射将光致感光体转化为还原剂。 然后还原剂与钴（III）络合物反应。 可以通过使用未暴露的残留的钴（III）络合物或通过曝光产生的一种或多种反应产物，将图像直接记录在辐射敏感层内或在单独的图像记录元件或层中。 通过使用从含有配体的钴（III）配合物中释放的氨与曝光相结合的图像和均匀曝光，可以在重叠图像记录层或与辐射敏感层相关的元件上形成正或负像。
-
公开(公告)号：US06291154B1
公开(公告)日：2001-09-18
申请号：US08010912
申请日：1993-01-29
IPC分类号： G03C100
CPC分类号： G03C1/29
摘要： A silver halide photographic element, and a method of making such an element, comprising a tabular grain silver halide emulsion containing at least one green spectral sensitizing dye of formula I, and at least one green spectral sensitizing dye of formula II: wherein R1 and R2 may be the same or different and are selected from substituted or unsubstituted C1 or C2 alkyl, substituted or unsubstituted C1 or C2 alkoxy, halogen, substituted or unsubstituted amido, or carbamoyl or substituted or unsubstituted aryl, provided that R1 and R2 are not both aryl, and the benzo back rings may optionally be further substituted; X3 is a substituted or unsubstituted C1 to C3 alkyl or alkenyl; X1 and X2 are acid or acid salt substituted C1 to C6 alkyl or alkenyl which may be further substituted or unsubstituted; M+ is a positive ion as required to balance the charge; where R3 and R4 may be the same or different and represent substituted or unsubstituted alkyl or alkenyl of 1 to 4 carbon atoms; R5 and R6 may be the same or different and both represent strong electron withdrawing groups; R8 and R9 are independently hydrogen, halogen, or a substituted or unsubstituted methyl or ethyl, or a strong electron withdrawing group; X4 and X5 are substituted or unsubstituted C1 to C6 alkyl or alkenyl at least one of which has an acid or acid salt substituent; N+ is a positive ion as needed to balance the charge.
摘要翻译： 卤化银照相元件和制造这种元件的方法，其包含含有至少一种式I的绿色光谱增感染料的片状粒状卤化银乳剂和至少一种式II的绿色光谱增感染料：其中R1和R2 可以相同或不同，并且选自取代或未取代的C1或C2烷基，取代或未取代的C1或C2烷氧基，卤素，取代或未取代的酰氨基或氨基甲酰基或取代或未取代的芳基，条件是R1和R2不同时为芳基 苯并环后环可以任选被进一步取代; X 3是取代或未取代的C 1至C 3烷基或烯基; X 1和X 2是酸或酸盐取代的C 1至C 6烷基或可被进一步取代或未取代的链烯基; M + 平衡电荷所需的正离子;其中R 3和R 4可以相同或不同并且表示取代或未取代的1至4个碳原子的烷基或烯基; R 5和R 6可以 相同或不同，均表示强吸电子基团; R8和R9独立地为氢，卤素或取代或未取代的甲基或乙基或强吸电子基团; X4和X5为取代或未取代的C1至C6烷基或 烯基，其中至少一个具有酸或酸盐取代基; N +是平衡电荷所需的正离子。
-
9.发明授权Radiographic elements that satisfy image and tone requirements with minimal silver 失效满足图像和色调要求的射线照相元件，最小银
公开(公告)号：US5800976A
公开(公告)日：1998-09-01
申请号：US864421
申请日：1997-05-28
CPC分类号： G03C5/16 , G03C1/35 , G03C1/0051 , G03C1/04 , G03C1/053 , G03C2200/58 , Y10S430/167
摘要： A dual-coated radiographic element is disclosed comprised of a blue tinted film support having coated on each of its faces a spectrally sensitized high bromide tabular grain emulsion. The properties of a maximum density of at least 3.0, an average contrast of at least 2.7, and a b* value more negative than -5.0 at a silver coating coverage on each major surface of the support of less than 12 mg/dm.sup.2, are imparted by (1) the support having a neutral density of at least 0.18, (2) tabular grains accounting for at least 90 percent of total grain projected area having a mean thickness of 0.2 micrometer or less and a coefficient of variation of equivalent circular diameter less than 20 percent, (3) a covering power enhancing compound containing at least one divalent sulfur atom adsorbed to surfaces of the silver halide grains, (4) a water soluble polymer chosen from the class consisting of polyacrylamide and dextran, in a weight ratio of the polymer to the gelatino-vehicle of at least 0.1:1, and (5) hardening of the gelatino-vehicle being chosen to allow a weight gain following processing and before drying of greater than 200 percent, based on the total weight of gelatino-vehicle.
摘要翻译： 公开了一种双重涂层射线照相元件，其包括在其每个面上涂覆有光谱增感的高溴化物片状颗粒乳剂的蓝色着色膜载体。 赋予至少3.0的最大密度，至少2.7的平均对比度和在载体的每个主表面上的银涂层覆盖率小于-5.0的ab *值的性质小于12mg / dm 2 通过（1）具有至少0.18的中性密度的载体，（2）片状颗粒占总颗粒投影面积的至少90％，平均厚度为0.2微米或更小，并且等效圆直径的变化系数较小 （3）覆盖能量增强化合物，其含有至少一个二价硫原子吸附在卤化银颗粒的表面，（4）选自聚丙烯酰胺和葡聚糖的水溶性聚合物，其重量比为 所述聚合物至明胶载体为至少0.1:1，和（5）明胶载体的硬化被选择为允许加工后的干重之前的重量增加大于200％，基于明胶 - 车辆。
-
10.发明授权Radiation sensitive element with absorber dye to enhance spectral sensitivity range 失效辐射敏感元件与吸收剂染料增强光谱灵敏度范围
公开(公告)号：US5298379A
公开(公告)日：1994-03-29
申请号：US906621
申请日：1992-06-30
申请人： Anthony Adin , Richard L. Parton
发明人： Anthony Adin , Richard L. Parton
IPC分类号： G03C1/08 , G03C1/10 , G03C1/12 , G03C1/20 , G03C1/28 , G03C1/494 , G03C1/825 , G03C1/83 , G03C5/00 , G03C5/02 , G03C5/16 , G03C1/815
摘要： A radiation detecting element, particularly a photographic element having a radiation detecting composition, in particular a silver halide emulsion. The composition provides the element with a wavelength of peak sensitivity, .lambda.peaksens, and a decreasing sensitivity around .lambda.peaksens. An absorber dye of defined characteristics is chosen, which has the effect of decreasing the change in sensitivity which the element otherwise has without the absorber dye (that is, the absorber dye increases the wavelength range over which the sensitivity is relatively constant). The element is preferably sensitive to infra-red.
摘要翻译： 辐射检测元件，特别是具有放射线检测组合物，特别是卤化银乳剂的照相元件。 该组合物为元件提供峰值灵敏度（λ）峰值的波长和（λ）峰值附近的灵敏度降低。 选择具有确定特性的吸收剂染料，其具有降低灵敏度变化的效果，除了吸收剂染料（即，吸收剂染料增加灵敏度相对恒定的波长范围）之外，元素否则具有这种变化。 元素优选对红外线敏感。
-
-
-
-
-
-
-
-
-
搜索结果
44 条记录 (耗时 0.024 秒)