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1.发明授权Isomerization of paraffins with strong solid acid catalyst and adamantane 失效具有强固体酸催化剂和ADAMANTANE的PARAFFINS的异构化
公开(公告)号：US5157199A
公开(公告)日：1992-10-20
申请号：US677905
申请日：1991-04-01
IPC分类号： B01J27/053 , C07B61/00 , C07C5/27 , C07C9/16
CPC分类号： C07C5/2794
摘要： A process for isomerizing a paraffin feed comprising contacting the feed with a strong, solid acid catalyst comprising a sulfated Group IVB metal oxide and at least one Group VIII metal in the presence of hydrogen and an adamantane compound.
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公开(公告)号：USRE33080E
公开(公告)日：1989-10-03
申请号：US896229
申请日：1986-08-14
申请人： George M. Kramer
发明人： George M. Kramer
IPC分类号： C07C5/27
CPC分类号： C07C5/2794
摘要： A process is described for non-cyclic paraffin isomerization under strong acid conditions in which an adamantane hydrocarbon is used to substantially increase the reaction rate of the isomerization.
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公开(公告)号：USD366302S
公开(公告)日：1996-01-16
申请号：US30895
申请日：1994-11-14
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公开(公告)号：US5298157A
公开(公告)日：1994-03-29
申请号：US925337
申请日：1992-08-04
申请人： George M. Kramer , Edwin R. Ernst , Chang S. Hsu
发明人： George M. Kramer , Edwin R. Ernst , Chang S. Hsu
CPC分类号： C10G1/00
摘要： A process for depolymerizing coal at low temperatures by contacting finely divided coal with a hard acid and soft base.
摘要翻译： 通过使细分散的煤与硬酸和软碱接触来在低温下解聚煤的方法。
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公开(公告)号：US4518798A
公开(公告)日：1985-05-21
申请号：US428930
申请日：1982-09-30
IPC分类号： C07C67/38 , B01J31/00 , C07B61/00 , C07C51/00 , C07C51/14 , C07C53/122 , C07C67/00 , C07C69/22 , C07C51/145 , C07C67/347
CPC分类号： C07C51/14
摘要： Esters or carboxylic acids are prepared from olefins containing at least two carbon atoms by reacting the olefin with carbon monoxide in the presence of:(i) a first complex of a selected Lewis acid with the ester or carboxylic acid, whichever is the reaction product recovered;(ii) a second complex of the Lewis acid with an alcohol, if an ester is being prepared, or with water, if a carboxylic acid is being prepared; and(iii) a metal carbonyl compound containing a Group IB transition metal in the first oxidation state; andby recovering the reaction product(s).The preferred olefin is propylene, the preferred ester to be prepared is methylisobutyrate, the preferred metal is copper and the preferred Lewis acid is boron trifluoride.
摘要翻译： 酯或羧酸由含有至少两个碳原子的烯烃制备，通过使烯烃与一氧化碳在以下存在下反应：（i）选择的路易斯酸与酯或羧酸的第一配合物，以取反应产物为准 ; （ii）如果正在制备酯，则路易斯酸与醇的第二配合物，如果正在制备羧酸，则与水反应; 和（iii）含有第一氧化态的IB族过渡金属的金属羰基化合物; 并通过回收反应产物。 优选的烯烃是丙烯，所制备的优选的酯是甲基异丁酸酯，优选的金属是铜，优选的路易斯酸是三氟化硼。
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公开(公告)号：US5492618A
公开(公告)日：1996-02-20
申请号：US289725
申请日：1994-08-12
摘要： An improved process for recovering hard acids and soft bases used to decompose coal in which finely divided coal particles are contacted with a hard acid in the presence of a soft base at temperatures of from 0.degree. to 100.degree. C., said hard acid being characterized by a heat of reaction with dimethylsulfide of from 10 kcal/mol to 30 kcal/mol and said soft base being characterized by a heat of reaction with boron trifluoride of from 10 kcal/mol to 17 kcal/mol, followed by extracting the decomposed coal to remove said hard acid and soft base wherein the improvement comprises performing said extraction at a temperature of about 0.degree. to about 50.degree. C. using dimethylcarbonate as the extraction solvent.
摘要翻译： 一种用于回收硬化酸和软碱的改进方法，其用于分解煤，其中细软的煤颗粒在软碱存在下在硬度为0至100℃的温度下与硬酸接触，所述硬酸被表征 通过与二甲硫醚反应的热量为10kcal / mol至30kcal / mol，所述软碱的特征在于与三氯化硼的反应热为10kcal / mol至17kcal / mol，随后提取分解的煤 以除去所述硬酸和软碱，其中改进包括使用碳酸二甲酯作为提取溶剂在约0℃至约50℃的温度下进行所述萃取。
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公开(公告)号：US5296133A
公开(公告)日：1994-03-22
申请号：US925362
申请日：1992-08-04
申请人： George M. Kramer , Daniel P. Leta , William A. Lamberti , Mark M. Disko , Sutinder K. Behal , Edwin R. Ernst
发明人： George M. Kramer , Daniel P. Leta , William A. Lamberti , Mark M. Disko , Sutinder K. Behal , Edwin R. Ernst
摘要： A process for preparing a low ash coal wherein coal is depolymerized at low temperature by contacting finely divided coal with a hard acid and soft base, and extracting the depolymerized coal to remove mineral contaminants.
摘要翻译： 一种制备低灰分煤的方法，其中煤通过使细分散的煤与硬酸和软碱接触而在低温下解聚，并且提取解聚的煤以除去矿物污染物。
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公开(公告)号：US4362669A
公开(公告)日：1982-12-07
申请号：US124306
申请日：1980-02-25
CPC分类号： C07F9/224 , B01D59/34 , C07F5/003 , C07F9/5304
摘要： Novel compositions of matter are disclosed having the general formula UO.sub.2 AA'L.sub.n, in which A and A' are anions whose conjugate acids have boiling points less than about 200.degree. C. and pK.sub.a values of 4.8 or less, L is a neutral ligand (1) having a boiling point of greater than about 200.degree. C. and an equilibrium constant for its exchange reaction with complexed tetrahydrofuran of greater than about 10.sup.-3, or (2) having an equilibrium constant for its exchange reaction with complexed tetrahydrofuran of greater than about 10.sup.3, and n is an integer of from 1 to 4.
摘要翻译： 公开了具有通式UO2AA'Ln的新型物质组合物，其中A和A'是共轭酸的沸点小于约200℃，pKa值为4.8以下的阴离子，L为中性配体（1 ），其与四氢呋喃的络合反应的平衡常数大于约10-3，或（2）具有与四氢呋喃络合物的交换反应的平衡常数大于约10-3的平衡常数。 约103，n为1〜4的整数。
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公开(公告)号：US3946088A
公开(公告)日：1976-03-23
申请号：US514002
申请日：1974-10-11
CPC分类号： C07C5/2721
摘要： A hydrocarbon feed is isomerized in liquid phase in the presence of a metal halide catalyst, a hydrogen halide solvent and hydrogen at a temperature ranging from at least 50.degree.C and not greater than the critical temperature of the mixture of the hydrocarbon feed and the hydrogen halide. The partial pressure of the hydrocarbon feed-hydrogen halide mixture is maintained to be at least equal to the critical pressure of the hydrocarbon feed and not greater than the critical pressure of the mixture of the hydrocarbon feed and the hydrogen halide. The molar ratio of the hydrogen halide to the hydrocarbon feed is at least 1:1 and the molar ratio of hydrogen halide to metal halide catalyst ranges from about 10:1 to about 40:1. The preferred catalyst is aluminum chloride or aluminum bromide. The preferred solvent is hydrogen chloride or hydrogen bromide.
摘要翻译： 在金属卤化物催化剂，卤化氢溶剂和氢气的存在下，烃原料在液相中异构化，温度范围为至少50℃，不高于烃进料和氢气的混合物的临界温度 卤化物。 烃进料 - 卤化氢混合物的分压保持至少等于烃进料的临界压力，并且不大于烃进料和卤化氢的混合物的临界压力。 卤化氢与烃进料的摩尔比至少为1:1，卤化氢与金属卤化物催化剂的摩尔比为约10:1至约40:1。 优选的催化剂是氯化铝或溴化铝。 优选的溶剂是氯化氢或溴化氢。
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公开(公告)号：US5489377A
公开(公告)日：1996-02-06
申请号：US289723
申请日：1994-08-12
申请人： George M. Kramer , Andres M. Fraga
发明人： George M. Kramer , Andres M. Fraga
摘要： An improved process for recovering hard acids and soft bases used to decompose coal in which finely divided coal particles are contacted with a hard acid in the presence of a soft base at temperatures of from 0.degree. to 100.degree. C., said hard acid being characterized by a heat of reaction with dimethylsulfide of from 10 kcal/mol to 30 kcal/mol and said soft base being characterized by a heat of reaction with boron trifluoride of from 10 kcal/mol to 17 kcal/mol, followed by extracting the decomposed coal to remove said hard acid and soft base wherein the improvement comprises performing said extraction at a temperature of about 0.degree. to about 50.degree. C. using dimethylcarbonate as the extraction solvent, and wherein following said dimethylcarbonate extraction, said coal is extracted with water at a temperature of from about 60.degree. to 275.degree. C., and wherein following said water extraction, said coal is soxhlet extracted in sulfolane at a temperature of about 25.degree. to about 350.degree. C., and wherein following said sulfolane extraction, said coal is soxhlet extracted to remove said sulfolane.
摘要翻译： 一种用于回收硬化酸和软碱的改进方法，其用于分解煤，其中细软的煤颗粒在软碱存在下在硬度为0至100℃的温度下与硬酸接触，所述硬酸被表征 通过与二甲硫醚反应的热量为10kcal / mol至30kcal / mol，所述软碱的特征在于与三氯化硼的反应热为10kcal / mol至17kcal / mol，随后提取分解的煤 去除所述硬酸和软碱，其中改进包括使用碳酸二甲酯作为萃取溶剂在约0℃至约50℃的温度下进行所述萃取，并且其中在所述碳酸二甲酯萃取之后，将所述煤在水中以 温度为约60℃至275℃，并且其中在所述水提取之后，所述煤在环丁砜中以约25至约350℃的温度提取索格利特，w 本文在所述环丁砜提取之后，所述煤被索氏提取除去所述环丁砜。
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