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1.发明授权Isomerization of paraffins with strong solid acid catalyst and adamantane 失效具有强固体酸催化剂和ADAMANTANE的PARAFFINS的异构化
公开(公告)号：US5157199A
公开(公告)日：1992-10-20
申请号：US677905
申请日：1991-04-01
IPC分类号： B01J27/053 , C07B61/00 , C07C5/27 , C07C9/16
CPC分类号： C07C5/2794
摘要： A process for isomerizing a paraffin feed comprising contacting the feed with a strong, solid acid catalyst comprising a sulfated Group IVB metal oxide and at least one Group VIII metal in the presence of hydrogen and an adamantane compound.
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2.发明授权Group VIII metal containing tungsten oxide silica modified zirconia as acid catalyst 失效含有氧化钨二氧化硅改性氧化锆的Ⅷ族金属作为酸催化剂
公开(公告)号：US5648589A
公开(公告)日：1997-07-15
申请号：US426378
申请日：1995-04-21
IPC分类号： B01J23/652 , C07B61/00 , C07C5/27 , C10G45/62 , C07C5/13
CPC分类号： C10G45/62 , B01J23/6527
摘要： The invention is directed to a catalyst composition comprising a Group VIII metal, preferably a Group VIII noble metal, and a zirconia support impregnated with silica and tungsten oxide and its use in an isomerization process.
摘要翻译： 本发明涉及包含Ⅷ族金属，优选Ⅷ族贵金属和浸渍有二氧化硅和氧化钨的氧化锆载体的催化剂组合物及其在异构化方法中的用途。
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3.发明授权Group VIII metal containing tungsten oxide silica modified zirconia as acid catalyst 失效含有氧化钨二氧化硅改性氧化锆的Ⅷ族金属作为酸催化剂
公开(公告)号：US5422327A
公开(公告)日：1995-06-06
申请号：US143423
申请日：1993-10-26
IPC分类号： B01J23/652 , C07B61/00 , C07C5/27 , C10G45/62 , B01J21/00
CPC分类号： C10G45/62 , B01J23/6527
摘要： The invention is directed to a catalyst composition comprising a Group VIII metal, preferably a Group VIII noble metal, and a zirconia support impregnated with silica and tungsten oxide and its use in an isomerization process.
摘要翻译： 本发明涉及包含Ⅷ族金属，优选Ⅷ族贵金属和浸渍有二氧化硅和氧化钨的氧化锆载体的催化剂组合物及其在异构化方法中的用途。
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4.发明授权
公开(公告)号：US5397806A
公开(公告)日：1995-03-14
申请号：US148749
申请日：1993-11-05
CPC分类号： B01J21/066 , B01J21/063 , B01J23/75 , C10G2/332 , B01J37/033
摘要： A method of preparing catalyst compositions of cobalt composited with ternary metal oxide supports of substituted titania having the general formula Co/Ti.sub.1-x M.sub.x O.sub.2 where x ranges from 0.01 to 0.14 and M is selected from the group consisting of silicon, zirconium, and tantalum and wherein the titania is an anatase polymorph stable under oxidative regeneration temperatures from about 400.degree. to about 750.degree. C.
摘要翻译： 制备与具有通式Co / Ti1-xMxO2的取代二氧化钛的三元金属氧化物载体复合的催化剂组合物的方法，其中x为0.01至0.14，M选自硅，锆和钽，其中 二氧化钛是在约400℃至约750℃的氧化再生温度下稳定的锐钛矿型多晶型
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5.发明授权
公开(公告)号：US5185378A
公开(公告)日：1993-02-09
申请号：US785118
申请日：1991-10-30
申请人： Stuart L. Soled , Sabato Miseo , Enrique Iglesia , Rocco A. Fiato
发明人： Stuart L. Soled , Sabato Miseo , Enrique Iglesia , Rocco A. Fiato
CPC分类号： C07C1/044 , B01J23/80 , C07C2523/04 , C07C2523/06 , C07C2523/72 , C07C2523/745 , C07C2523/80
摘要： New copper-potassium promoted iron-zinc catalysts wherein the iron:zinc atomic ratio is 5:1 or greater, exhibit improved activity, selectivity and stability in the synthesis of alpha-olefins from hydrogen and carbon monoxide.
摘要翻译： 新的铜 - 钾促进的铁 - 锌催化剂，其中铁：锌原子比为5:1或更大，在氢和一氧化碳合成α-烯烃中表现出改进的活性，选择性和稳定性。
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6.发明授权Method for stabilizing titania supported cobalt catalyst and the catalyst for use in Fischer-Tropsch process 失效用于稳定二氧化钛负载的钴催化剂的方法和用于费 - 托方法的催化剂
公开(公告)号：US5169821A
公开(公告)日：1992-12-08
申请号：US791730
申请日：1991-11-14
CPC分类号： C04B35/62675 , B01J21/063 , B01J21/066 , B01J23/75 , C01G23/047 , C01G25/00 , C01G35/006 , C01G51/006 , C04B35/46 , C10G2/332 , B01J37/033 , C01P2002/54 , C01P2002/72 , C01P2006/12 , C01P2006/32 , C04B2235/3232 , C04B2235/3244 , C04B2235/3251 , C04B2235/3418 , C04B2235/441 , C04B2235/444 , C04B2235/5409
摘要： A method of preparing catalyst compositions of cobalt composited with ternary metal oxide supports of substituted titania having the general formula Co/Ti.sub.x M.sub.1-x O.sub.2 where x ranges from 0.01 to 0.14 and M is selected from the group consisting of silicon, zirconium, and tantalum and wherein the titania is an anatase polymorph stable under oxidative regeneration temperatures from about 400.degree. to about 750.degree. C.
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7.发明授权Selective fixed-bed fischer-tropsch synthesis with high surface area Cu and K promoted, iron/manganese spinels 失效选择性固定床费托合成高表面积Cu和K促进，铁/锰尖晶石
公开(公告)号：US5118715A
公开(公告)日：1992-06-02
申请号：US576251
申请日：1990-08-31
IPC分类号： B01J23/00 , B01J23/889 , C07C1/04
CPC分类号： B01J23/005 , B01J23/8892 , C07C1/044 , C07C2521/02 , C07C2521/06 , C07C2521/08 , C07C2521/16 , C07C2523/34 , C07C2523/745 , C07C2523/889 , C07C2527/232 , C07C2529/04
摘要： Pelletized, high surface area, Cu and Group IA or IIA dual metal promoted Mn-Fe spinels which are reduced and operated in a fixed-bed reactor provide exceptionally high catalytic activity and selectivity in the conversion of CO/H.sub.2 to high molecular weight hydrocarbons. These copper and Group IA or IIA metal promoted iron-manganese catalysts maintain good activity and selectivity to C.sub.5 + hydrocarbons, and give low selectivity to CO2.
摘要翻译： 造粒，高表面积，Cu和IA或IIA双金属促进的Mn-Fe尖晶石在固定床反应器中还原和操作，在CO / H2转化为高分子量烃时具有特别高的催化活性和选择性。 这些铜和IAA或IIA族金属促进的铁锰催化剂对C5 +烃保持良好的活性和选择性，并且对CO 2的选择性低。
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8.发明授权Iron-zinc based catalysts for the conversion of synthesis gas to alpha-olefins 失效用于将合成气转化成α-烯烃的基于铁 - 锌的催化剂
公开(公告)号：US5100856A
公开(公告)日：1992-03-31
申请号：US591304
申请日：1990-10-01
申请人： Stuart L. Soled , Sabato Miseo , Enrique Iglesia , Rocco A. Fiato
发明人： Stuart L. Soled , Sabato Miseo , Enrique Iglesia , Rocco A. Fiato
CPC分类号： C07C1/044 , B01J23/80 , C07C2523/04 , C07C2523/06 , C07C2523/72 , C07C2523/745 , C07C2523/80
摘要： New copper-potassium promoted iron-zinc catalysts wherein the iron:zinc atomic ratio is 5:1 or greater, exhibit improved activity, selectivity and stability in the synthesis of alpha-olefins from hydrogen and carbon monoxide.
摘要翻译： 新的铜 - 钾促进的铁 - 锌催化剂，其中铁：锌原子比为5:1或更大，在氢和一氧化碳合成α-烯烃中表现出改进的活性，选择性和稳定性。
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9.发明授权Cobalt-ruthenium catalysts for Fischer-Tropsch synthesis and process for their preparation 失效用于费 - 托合成的钴 - 钌催化剂及其制备方法
公开(公告)号：US4738948A
公开(公告)日：1988-04-19
申请号：US881347
申请日：1986-07-02
申请人： Enrique Iglesia , Stuart L. Soled , Rocco A. Fiato
发明人： Enrique Iglesia , Stuart L. Soled , Rocco A. Fiato
CPC分类号： C07C1/0445 , B01J23/8913 , B01J37/14 , B01J37/18 , B01J21/063 , B01J38/10 , C07C2521/06 , C07C2523/46 , C07C2523/75 , C07C2523/89 , Y02P20/584
摘要： A hydrogen regenerable hydrocarbon synthesis catalyst useful for preparing higher hydrocarbons from synthesis gas is prepared by depositing cobalt and ruthenium on a refractory carrier and oxidizing and reducing the catalytic metals to form a catalyst in which the cobalt and ruthenium are in intimate contact.
摘要翻译： 通过将钴和钌沉积在耐火载体上并氧化和还原催化金属以形成其中钴和钌紧密接触的催化剂来制备可用于从合成气制备高级烃的氢可再生烃合成催化剂。
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10.发明授权Copper promoted cobalt-manganese spinel catalyst and method for making the catalyst for Fischer-Tropsch synthesis 失效铜促进的钴 - 锰尖晶石催化剂和制备费 - 托合成催化剂的方法
公开(公告)号：US5162284A
公开(公告)日：1992-11-10
申请号：US740252
申请日：1991-08-05
申请人： Stuart L. Soled , Enrique Iglesia , Rocco A. Fiato
发明人： Stuart L. Soled , Enrique Iglesia , Rocco A. Fiato
IPC分类号： B01J23/00 , B01J23/889 , C07C1/04
CPC分类号： B01J23/005 , B01J23/8892 , C07C1/0435 , C07C2523/34 , C07C2523/75 , C07C2523/889 , Y10S502/524
摘要： A copper promoted cobalt manganese spinel useful for Fischer-Tropsch synthesis of olefins and higher paraffins is prepared from an aqueous solution of cobalt and manganese salts of at least one alpha-hydroxy aliphatic carboxylic acid.
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