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公开(公告)号：US5401817A
公开(公告)日：1995-03-28
申请号：US064630
申请日：1993-05-20
申请人： Syriac J. Palackal , Helmut G. Alt , Konstantinos Patsidis , Tara G. Hill , Gil R. Hawley , Peter P. Chu , M. Bruce Welch , Rolf L. Geerts
发明人： Syriac J. Palackal , Helmut G. Alt , Konstantinos Patsidis , Tara G. Hill , Gil R. Hawley , Peter P. Chu , M. Bruce Welch , Rolf L. Geerts
IPC分类号： B01J31/22 , C07C13/567 , C07C22/04 , C07C49/747 , C07C51/31 , C07C51/373 , C07C51/377 , C07C63/331 , C07C63/49 , C07C65/36 , C07F7/00 , C07F7/08 , C07F7/22 , C07F17/00 , C08F4/60 , C08F4/639 , C08F4/6392 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/00 , C08F110/02 , C08F110/06 , C08F210/16 , C08F4/64
CPC分类号： C08F110/06 , B01J31/143 , B01J31/1608 , B01J31/2295 , C07C13/567 , C07C22/04 , C07C49/747 , C07C51/31 , C07C51/373 , C07C51/377 , C07C63/331 , C07C63/49 , C07C65/36 , C07F17/00 , C07F7/006 , C07F7/0809 , C07F7/0818 , C07F7/2212 , C08F10/00 , C08F4/65927 , B01J2531/40 , B01J2531/48 , C07C2101/10 , C07C2103/18 , C08F110/02 , C08F210/16 , C08F4/63912 , C08F4/63922 , C08F4/65912 , Y02P20/52
摘要： Fluorenyl-containing silyl bridged metallocenes, the process of using such metallocenes to polymerize olefins, and the resulting unusual syndiotactic polypropylene are disclosed.
摘要翻译： 公开了含芴基的甲硅烷基桥接金属茂，使用这种金属茂聚合烯烃的方法，以及所得到的异常间同立构聚丙烯。
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公开(公告)号：US5627118A
公开(公告)日：1997-05-06
申请号：US352933
申请日：1994-12-09
申请人： Syriac J. Palackal , Helmut G. Alt , Konstantinos Patsidis , Tara G. Hill , Gil R. Hawley , Peter P. Chu , M. Bruce Welch , Rolf L. Geerts
发明人： Syriac J. Palackal , Helmut G. Alt , Konstantinos Patsidis , Tara G. Hill , Gil R. Hawley , Peter P. Chu , M. Bruce Welch , Rolf L. Geerts
IPC分类号： B01J31/22 , C07C13/567 , C07C22/04 , C07C49/747 , C07C51/31 , C07C51/373 , C07C51/377 , C07C63/331 , C07C63/49 , C07C65/36 , C07F7/00 , C07F7/08 , C07F7/22 , C07F17/00 , C08F4/60 , C08F4/639 , C08F4/6392 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/00 , C08F110/02 , C08F110/06 , C08F210/16 , B01S31/00 , C07F7/12
CPC分类号： C08F110/06 , B01J31/143 , B01J31/1608 , B01J31/2295 , C07C13/567 , C07C22/04 , C07C49/747 , C07C51/31 , C07C51/373 , C07C51/377 , C07C63/331 , C07C63/49 , C07C65/36 , C07F17/00 , C07F7/006 , C07F7/0809 , C07F7/0818 , C07F7/2212 , C08F10/00 , C08F4/65927 , B01J2531/40 , B01J2531/48 , C07C2101/10 , C07C2103/18 , C08F110/02 , C08F210/16 , C08F4/63912 , C08F4/63922 , C08F4/65912 , Y02P20/52
摘要： Fluorenyl-containing silyl bridged metallocenes, the process of using such metallocenes to polymerize olefins, and the resulting unusual syndiotactic polypropylene are disclosed.
摘要翻译： 公开了含芴基的甲硅烷基桥接金属茂，使用这种金属茂聚合烯烃的方法，以及所得到的异常间同立构聚丙烯。
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3.发明授权
公开(公告)号：US5459218A
公开(公告)日：1995-10-17
申请号：US352478
申请日：1994-12-09
申请人： Syriac J. Palackal , Helmut G. Alt , Konstantinos Patsidis , Tara G. Hill , Gil R. Hawley , Peter P. Chu , M. Bruce Welch , Rolf L. Geerts
发明人： Syriac J. Palackal , Helmut G. Alt , Konstantinos Patsidis , Tara G. Hill , Gil R. Hawley , Peter P. Chu , M. Bruce Welch , Rolf L. Geerts
IPC分类号： B01J31/22 , C07C13/567 , C07C22/04 , C07C49/747 , C07C51/31 , C07C51/373 , C07C51/377 , C07C63/331 , C07C63/49 , C07C65/36 , C07F7/00 , C07F7/08 , C07F7/22 , C07F17/00 , C08F4/60 , C08F4/639 , C08F4/6392 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/00 , C08F110/02 , C08F110/06 , C08F210/16
CPC分类号： C08F110/06 , B01J31/143 , B01J31/1608 , B01J31/2295 , C07C13/567 , C07C22/04 , C07C49/747 , C07C51/31 , C07C51/373 , C07C51/377 , C07C63/331 , C07C63/49 , C07C65/36 , C07F17/00 , C07F7/006 , C07F7/0809 , C07F7/0818 , C07F7/2212 , C08F10/00 , C08F4/65927 , B01J2531/40 , B01J2531/48 , C07C2101/10 , C07C2103/18 , C08F110/02 , C08F210/16 , C08F4/63912 , C08F4/63922 , C08F4/65912 , Y02P20/52
摘要： Fluorenyl-containing silyl bridged metallocenes, the process of using such metallocenes to polymerize olefins, and the resulting unusual syndiotactic polypropylene are disclosed.
摘要翻译： 公开了含芴基的甲硅烷基桥接金属茂，使用这种金属茂聚合烯烃的方法，以及所得到的异常间同立构聚丙烯。
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4.发明授权Organometallic fluorenyl compounds and use thereof in olefin polymerization 失效有机金属芴基化合物和在烯烃聚合中使用它们的
公开(公告)号：US5627247A
公开(公告)日：1997-05-06
申请号：US408468
申请日：1995-03-22
申请人： Helmut G. Alt , Gil R. Hawley , Paul D. Smith , Syriac J. Palackal , Michael Schmid , M. Bruce Welch , Konstantinos Patsidis , Rolf L. Geerts , Eric T. Hsieh , Max P. McDaniel
发明人： Helmut G. Alt , Gil R. Hawley , Paul D. Smith , Syriac J. Palackal , Michael Schmid , M. Bruce Welch , Konstantinos Patsidis , Rolf L. Geerts , Eric T. Hsieh , Max P. McDaniel
IPC分类号： B01J31/22 , C07C13/567 , C07C22/04 , C07C49/747 , C07C51/31 , C07C51/373 , C07C51/377 , C07C63/331 , C07C63/49 , C07C65/36 , C07F7/08 , C07F17/00 , C08F4/639 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , C08F10/04
CPC分类号： B01J31/143 , B01J31/2295 , C07C13/567 , C07C22/04 , C07C49/747 , C07C51/31 , C07C51/373 , C07C51/377 , C07C63/331 , C07C63/49 , C07C65/36 , C07F17/00 , C07F7/0809 , C07F7/0818 , C08F10/00 , C08F210/16 , B01J2531/40 , B01J2531/48 , B01J2531/49 , C07C2101/10 , C07C2101/14 , C07C2101/16 , C07C2103/18 , C08F110/02 , C08F110/06 , C08F4/63912 , C08F4/65912 , C08F4/65925 , Y10S526/943
摘要： Unbridged fluorenyl containing metallocenes are disclosed along with methods for making the metallocenes. Also disclosed are methods for using the metallocenes as polymerization catalysts. In addition, polymers resulting from such polymerizations are disclosed.
摘要翻译： 含有金属茂桥连芴与用于制备金属茂的方法沿着所公开的。 还公开了使用金属茂作为聚合催化剂的方法。 此外，从这种聚合得到的聚合物中公开。
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公开(公告)号：US5436305A
公开(公告)日：1995-07-25
申请号：US734853
申请日：1991-07-23
申请人： Helmut G. Alt , Syriac J. Palackal , Konstantinos Patsidis , M. Bruce Welch , Rolf L. Geerts , Eric T. Hsieh , Max P. McDaniel , Gil R. Hawley , Paul D. Smith
发明人： Helmut G. Alt , Syriac J. Palackal , Konstantinos Patsidis , M. Bruce Welch , Rolf L. Geerts , Eric T. Hsieh , Max P. McDaniel , Gil R. Hawley , Paul D. Smith
IPC分类号： C07F7/02 , B01J31/22 , C07C1/32 , C07C13/567 , C07C17/32 , C07C22/04 , C07C49/747 , C07C51/31 , C07C51/373 , C07C51/377 , C07C63/331 , C07C63/49 , C07C65/36 , C07F7/08 , C07F7/12 , C07F9/52 , C07F17/00 , C08F4/60 , C08F4/639 , C08F4/6392 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F4/74 , C08F10/00 , C08F10/04 , C08F10/08 , C08F10/10 , C08F10/14 , C08F110/02 , C08F110/06 , C08F110/14 , C08F210/16
CPC分类号： B01J31/143 , B01J31/2295 , C07C13/567 , C07C22/04 , C07C49/747 , C07C51/31 , C07C51/373 , C07C51/377 , C07C63/331 , C07C63/49 , C07C65/36 , C07F17/00 , C07F7/0809 , C07F7/0818 , C08F10/00 , B01J2531/40 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07C2101/10 , C07C2103/18 , C08F110/02 , C08F110/06 , C08F210/16 , C08F4/63912 , C08F4/63922 , C08F4/65912 , C08F4/65927
摘要： Fluorenyl-containing metallocenes are disclosed along with methods for making the metallocenes. Also disclosed are methods for using the metallocenes as polymerization catalysts. In addition, polymers resulting from such polymerizations are disclosed.
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公开(公告)号：US07230128B2
公开(公告)日：2007-06-12
申请号：US10260028
申请日：2002-05-10
申请人： Helmut G. Alt , Syriac J. Palackal , Konstantinos Patsidis , M. Bruce Welch , Rolf L. Geerts , Eric T. Hsieh , Max P. McDaniel , Gil R. Hawley , Paul D. Smith
发明人： Helmut G. Alt , Syriac J. Palackal , Konstantinos Patsidis , M. Bruce Welch , Rolf L. Geerts , Eric T. Hsieh , Max P. McDaniel , Gil R. Hawley , Paul D. Smith
CPC分类号： B01J31/143 , B01J31/2295 , B01J2531/40 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/50 , B01J2531/56 , C07C13/567 , C07C22/04 , C07C49/747 , C07C51/31 , C07C51/373 , C07C51/377 , C07C63/331 , C07C63/49 , C07C65/36 , C07C2601/10 , C07C2603/18 , C07F7/0805 , C07F7/081 , C07F17/00 , C08F4/63912 , C08F4/63922 , C08F4/65912 , C08F4/65927 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , Y10S526/943 , C07C65/38 , C08F2500/12 , C08F2500/17 , C08F2500/20 , C08F2500/01 , C08F2500/08 , C08F210/14
摘要： Fluorenyl-containing metallocenes are disclosed along with methods for making the metallocenes. Also disclosed are methods for using the metallocenes as polymerization catalysts. In addition, polymers resulting from such polymerizations are disclosed.
摘要翻译： 公开了含芴基金属茂以及制备金属茂的方法。 还公开了使用金属茂作为聚合催化剂的方法。 此外，公开了由这种聚合产生的聚合物。
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公开(公告)号：US06403734B1
公开(公告)日：2002-06-11
申请号：US09197761
申请日：1998-11-23
申请人： Helmut G. Alt , Syriac J. Palackal , Konstantinos Patsidis , M. Bruce Welch , Rolf L. Geerts , Eric T. Hsieh , Max P. McDaniel , Gil R. Hawley , Paul D. Smith
发明人： Helmut G. Alt , Syriac J. Palackal , Konstantinos Patsidis , M. Bruce Welch , Rolf L. Geerts , Eric T. Hsieh , Max P. McDaniel , Gil R. Hawley , Paul D. Smith
IPC分类号： C08F4642
CPC分类号： B01J31/143 , B01J31/2295 , B01J2531/40 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/50 , B01J2531/56 , C07C13/567 , C07C22/04 , C07C49/747 , C07C51/31 , C07C51/373 , C07C51/377 , C07C63/331 , C07C63/49 , C07C65/36 , C07C2601/10 , C07C2603/18 , C07F7/0805 , C07F7/081 , C07F17/00 , C08F4/63912 , C08F4/63922 , C08F4/65912 , C08F4/65927 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , Y10S526/943 , C07C65/38 , C08F2500/12 , C08F2500/17 , C08F2500/20 , C08F2500/01 , C08F2500/08 , C08F210/14
摘要： Bridged fluorenyl-containing metallocenes of metals of Groups 4-6 and their use in forming homopolymers of alpha olefins or polymers of ethylene and optionally minor amounts of alpha olefins, wherein in each case at least one of the cyclic groups of the bridged ligand is a fluorenyl and the other is selected from indenyl, tetrahydroindenyl, fluorenyl, and in the case of the polymerization of ethylene optionally cyclopentadienyl.
摘要翻译： 第4-6族金属的含桥连的含芴基金属茂及其在形成α-烯烃或乙烯和任选的少量α-烯烃的聚合物的均聚物中的用途，其中在每种情况下桥连配体的至少一个环状基团为 芴基，另一个选自茚基，四氢茚基，芴基，并且在乙烯聚合任选的环戊二烯基的情况下。
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公开(公告)号：US06420579B1
公开(公告)日：2002-07-16
申请号：US08352936
申请日：1994-12-09
申请人： Helmut G. Alt , Syriac J. Palackal , Konstantinos Patsidis , M. Bruce Welch , Rolf L. Geerts , Eric T. Hsieh , Max P. McDaniel , Gil R. Hawley , Paul D. Smith
发明人： Helmut G. Alt , Syriac J. Palackal , Konstantinos Patsidis , M. Bruce Welch , Rolf L. Geerts , Eric T. Hsieh , Max P. McDaniel , Gil R. Hawley , Paul D. Smith
IPC分类号： C07F1700
CPC分类号： B01J31/143 , B01J31/2295 , B01J2531/40 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/50 , B01J2531/56 , C07C13/567 , C07C22/04 , C07C49/747 , C07C51/31 , C07C51/373 , C07C51/377 , C07C63/331 , C07C63/49 , C07C65/36 , C07C2601/10 , C07C2603/18 , C07F7/0805 , C07F7/081 , C07F17/00 , C08F4/63912 , C08F4/63922 , C08F4/65912 , C08F4/65927 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , Y10S526/943 , C07C65/38 , C08F2500/12 , C08F2500/17 , C08F2500/20 , C08F2500/01 , C08F2500/08 , C08F210/14
摘要： Bridged and unbridged fluorenyl-containing metallocenes of the formula R″x(FlRn)(CpRm)MQk wherein Fl is a fluorenyl radical, Cp is a cyclopentadienyl, indenyl, tetrahydroindenyl, or fluorenyl radical, each R is an organo radical, R″ is a structural bridge linking (FlRn) and (CpRm), M is a metal selected from the group consisting of IVB, VB, and VIB metals, each Q is selected from the group consisting of hydrocarbyl or hydrocarbyloxy radicals and halogen, x is 1 or 0, k is an integer sufficient to fill out the remaining valences of M, n is in the range of 0 to 7, and m is 0 to 7, further characterized by the fact that if (CpRm) is unsubstituted fluorenyl and metallocene is an unbridged metallocene, then n is 1 to 7 and if R″ is 1,1-dimethylmethylene and (CpRm) is unsubstituted cyclopentadienyl or 3-methylcyclopentadienyl, then n is 1 to 7.
摘要翻译： 桥接和未桥连的含芴基的茂金属的式R''x（FlRn）（CpRm）MQk其中F1是芴基，Cp是环戊二烯基，茚基，四氢茚基或芴基，每个R是有机基团，R' 是连接（FlRn）和（CpRm）的结构桥，M是选自IVB，VB和VIB金属的金属，每个Q选自烃基或烃氧基和卤素，x是 1或0，k是足以填充M的剩余价数的整数，n在0至7的范围内，m为0至7，其特征还在于如果（CpRm）为未取代的芴基和茂金属 是未桥连金属茂，n为1〜7，如果R“为1,1-二甲基亚甲基，（CpRm）为未取代的环戊二烯基或3-甲基环戊二烯基，n为1〜7。
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公开(公告)号：US6162936A
公开(公告)日：2000-12-19
申请号：US85945
申请日：1998-05-28
申请人： Helmut G. Alt , Syriac J. Palackal , Konstantinos Patsidis , M. Bruce Welch , Rolf L. Geerts , Eric T. Hsieh , Max P. McDaniel , Gil R. Hawley , Paul D. Smith
发明人： Helmut G. Alt , Syriac J. Palackal , Konstantinos Patsidis , M. Bruce Welch , Rolf L. Geerts , Eric T. Hsieh , Max P. McDaniel , Gil R. Hawley , Paul D. Smith
IPC分类号： B01J31/22 , C07C13/567 , C07C22/04 , C07C49/747 , C07C51/31 , C07C51/373 , C07C51/377 , C07C63/331 , C07C63/49 , C07C65/36 , C07F7/08 , C07F17/00 , C08F4/639 , C08F4/6392 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , C07F9/00 , C07F7/00 , C07F7/28
CPC分类号： B01J31/143 , B01J31/2295 , B01J2531/40 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/50 , B01J2531/56 , C07C13/567 , C07C22/04 , C07C49/747 , C07C51/31 , C07C51/373 , C07C51/377 , C07C63/331 , C07C63/49 , C07C65/36 , C07C2601/10 , C07C2603/18 , C07F7/0805 , C07F7/081 , C07F17/00 , C08F4/63912 , C08F4/63922 , C08F4/65912 , C08F4/65927 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , Y10S526/943 , C07C65/38 , C08F2500/12 , C08F2500/17 , C08F2500/20 , C08F2500/01 , C08F2500/08 , C08F210/14
摘要： Fluorenyl-containing metallocenes are disclosed along with methods for making the metallocenes. Also disclosed are methods for using the metallocenes as polymerization catalysts. In addition, polymers resulting from such polymerizations are disclosed.
摘要翻译： 公开了含芴基金属茂以及制备金属茂的方法。 还公开了使用金属茂作为聚合催化剂的方法。 此外，公开了由这种聚合产生的聚合物。
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10.发明授权
公开(公告)号：US5610247A
公开(公告)日：1997-03-11
申请号：US410154
申请日：1995-03-23
申请人： Helmut G. Alt , Syriac J. Palackal , Konstantinos Patsidis , M. Bruce Welch , Rolf L. Geerts , Eric T. Hsieh , Max P. McDaniel , Gil R. Hawley , Paul D. Smith , Jay Janzen , Michael Schmid
发明人： Helmut G. Alt , Syriac J. Palackal , Konstantinos Patsidis , M. Bruce Welch , Rolf L. Geerts , Eric T. Hsieh , Max P. McDaniel , Gil R. Hawley , Paul D. Smith , Jay Janzen , Michael Schmid
IPC分类号： B01J31/22 , C07C13/567 , C07C51/31 , C07C51/373 , C07C51/377 , C07F17/00 , C08F4/639 , C08F4/6392 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , C08F10/02
CPC分类号： B01J31/143 , B01J31/2295 , C07C13/567 , C07C51/31 , C07C51/373 , C07C51/377 , C07F17/00 , C08F10/00 , B01J2531/40 , B01J2531/48 , C07C2101/10 , C07C2101/14 , C07C2103/18 , C08F110/02 , C08F110/06 , C08F210/16 , C08F4/63912 , C08F4/63922 , C08F4/65912 , C08F4/65925 , C08F4/65927 , Y10S526/943
摘要： 9-substituted fluorenyl-containing metallocenes and their use in the polymerization of olefins is disclosed. In addition, novel 9-cyclohexylfluorenyl or 9-phenylfluorenyl compounds are disclosed. Also methods for preparing such 9-substituted fluorenyl compounds are presented.
摘要翻译： 公开了9-取代的含芴基金属茂及其在烯烃聚合中的用途。 此外，公开了新的9-环己基芴基或9-苯基芴基化合物。 还提出了制备这种9-取代的芴基化合物的方法。
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