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    Process for polymerizing or copolymerizing olefins
    1.
    发明授权
    Process for polymerizing or copolymerizing olefins 失效
    烯烃聚合或共聚方法

    公开(公告)号：US4370455A

    公开(公告)日：1983-01-25

    申请号：US101470

    申请日：1979-12-10

    申请人： Takashi Ueda ,  Syuji Minami ,  Mamoru Kioka ,  Norio Kashiwa

    发明人： Takashi Ueda ,  Syuji Minami ,  Mamoru Kioka ,  Norio Kashiwa

    IPC分类号： C08F4/00 ,  C08F4/60 ,  C08F10/00 ,  C08F4/02

    CPC分类号： C08F10/00

    摘要： In a process for producing a polymer or copolymer of an alpha-olefin which comprises continuously polymerizing or copolymerizing the alpha-olefin or the alpha-olefin with up to 5 mole % of a diolefin in the presence of a catalyst comprising a transition metal catalyst component and an organoaluminum catalyst component, the improvement wherein:(I) said polymerization or copolymerization is carried out in the presence of a catalyst composed of (A) a solid magnesium compound obtained by reacting (i) an adduct between a magnesium halide and an electron donor, with (ii) an organometallic compound of a metal of Groups I to III of the Mendelejeff's periodic table, (B) a liquid transition metal compound, and (C) an organoaluminum compound, and(II) said continuous polymerization or copolymerization is carried out while feeding the compound (B) separately from the other compounds (A) and (C) into a polymerization or copolymerization zone.

    摘要翻译： 在制备α-烯烃的聚合物或共聚物的方法中，其包括在包含过渡金属催化剂组分的催化剂存在下，使α-烯烃或α-烯烃与至多5摩尔％的二烯烃连续聚合或共聚 和有机铝催化剂组分的改进，其中：（I）所述聚合或共聚在催化剂存在下进行，所述催化剂由（A）通过（i）卤化镁和电子之间的加合物反应获得的固体镁化合物 （ii）Mendelejeff周期表第I至III族金属的有机金属化合物，（B）液体过渡金属化合物和（C）有机铝化合物，和（II）所述连续聚合或共聚是 在将化合物（B）与其它化合物（A）和（C）分开地进料到聚合或共聚区中的同时进行。

    Continuous process for production of olefin polymers or copolymers
    2.
    发明授权
    Continuous process for production of olefin polymers or copolymers 失效
    用于生产烯烃聚合物或共聚物的连续方法

    公开(公告)号：US4328328A

    公开(公告)日：1982-05-04

    申请号：US100098

    申请日：1979-12-04

    申请人： Syuji Minami ,  Takashi Ueda ,  Mamoru Kioka ,  Norio Kashiwa

    发明人： Syuji Minami ,  Takashi Ueda ,  Mamoru Kioka ,  Norio Kashiwa

    IPC分类号： C08F4/00 ,  C08F4/02 ,  C08F4/60 ,  C08F4/62 ,  C08F4/639 ,  C08F4/64 ,  C08F10/00 ,  C08F10/02

    CPC分类号： C08F10/00 ,  C08F4/022

    摘要： In a continuous process for producing a polymer or copolymer of an alpha-olefin in a hydrocarbon solvent in the presence of a catalyst comprising a transition metal compound and an organoaluminum compound, the improvement wherein[I] polymerization or copolymerization is carried out in the presence of a catalyst composed of(A) a magnesium compound in the liquid state which is soluble in said hydrocarbon solvent and is free from an organoaluminum compound and a transition metal compound, said magnesium compound being obtained from specific reactants,(B) a transition metal compound in the liquid state, and(C) an organoaluminum compound, and[II] said polymerization or copolymerization is carried out while feeding said compound (C) into a polymerization or copolymerization zone separately from said other compounds (A) and (B), or while adding a part or the whole of said compound (C) to a liquid mixture of said other compounds (A) and (B) and feeding the resulting mixture into said zone, or while feeding a mixture of the compounds (A), (B) and (C) into said zone.

    摘要翻译： 在包含过渡金属化合物和有机铝化合物的催化剂存在下，在烃溶剂中制备α-烯烃的聚合物或共聚物的连续方法中，其中[I]聚合或共聚在存在下进行 由（A）液态的镁化合物（其可溶于所述烃溶剂并且不含有机铝化合物和过渡金属化合物）组成的催化剂，所述镁化合物由特定反应物获得，（B）过渡金属 以及（C）有机铝化合物，和[II]在将所述化合物（C）与所述其它化合物（A）和（B）分开地进入聚合或共聚区的同时进行聚合或共聚， 或者将所述化合物（C）的一部分或全部添加到所述其它化合物（A）和（B）的液体混合物中，并将所得混合物进料到所述区域 或者将化合物（A），（B）和（C）的混合物进料到所述区域中。

    Process for polymerizing alpha-olefins
    3.
    发明授权
    Process for polymerizing alpha-olefins 失效
    α-烯烃聚合方法

    公开(公告)号：US6121393A

    公开(公告)日：2000-09-19

    申请号：US418879

    申请日：1995-04-07

    申请人： Mamoru Kioka ,  Norio Kashiwa ,  Tomohiko Kimura ,  Mitsuo Tomura ,  Toshiki Sotoyama

    发明人： Mamoru Kioka ,  Norio Kashiwa ,  Tomohiko Kimura ,  Mitsuo Tomura ,  Toshiki Sotoyama

    IPC分类号： C08F2/18

    CPC分类号： C08F10/00

    摘要： A process for polymerizing an alpha-olefin using either a catalyst formed by contacting a highly active solid titanium catalyst component, an organo-metallic compound of a metal of Group 1 to 3 of the periodic table, an organic halogen compound or a transition metal compound, and an organosilicon compound or a sterically hindered amine in an inert medium in the absence of an alpha olefin, or a catalyst prepared by preliminarily polymerizing an alpha olefin in the presence of a catalyst comprising the above four catalyst components, provided that the last one is an optional component. This process achieves the industrially advantage that the catalysts are highly active, and give a polymer having excellent stereoregularity.

    摘要翻译： 使用通过使高活性固体钛催化剂组分，元素周期表第1族至第3族的金属的有机金属化合物，有机卤素化合物或过渡金属化合物接触而形成的催化剂聚合α-烯烃的方法 ，以及在不存在α-烯烃的惰性介质中的有机硅化合物或空间位阻胺，或在包含上述四种催化剂组分的催化剂存在下通过预先聚合α-烯烃制备的催化剂，条件是最后一个 是一个可选组件。 该工艺实现了工业上的优点，即催化剂具有高活性，并产生具有优异的立构规整性的聚合物。

    Process for producing ethylene copolymer
    4.
    发明授权
    Process for producing ethylene copolymer 失效
    生产乙烯共聚物的方法

    公开(公告)号：US5091353A

    公开(公告)日：1992-02-25

    申请号：US423586

    申请日：1989-10-17

    申请人： Mamoru Kioka ,  Norio Kashiwa

    发明人： Mamoru Kioka ,  Norio Kashiwa

    IPC分类号： C08F4/00 ,  C08F4/60 ,  C08F4/638 ,  C08F4/64 ,  C08F4/654 ,  C08F10/00 ,  C08F210/02 ,  C08F210/16

    CPC分类号： C08F210/16 ,  Y10S526/909

    摘要： An improved process for producing an ethylene copolymer composed of a major proportion of ethylene and a minor proportion of an alpha-olefin having 3 to 10 carbon atoms and having a density of 0.910 to 0.945 g/cm.sup.3 and an ethylene content of 85 to 99.5 mole %. The use of a titanium catalyst component (A) which meets a parametric combination of specific requirements is essential in this process. The process can industrially advantageously give a low to medium density ethylene copolymer of high quality with high productivity while advantageously circumventing the operational troubles which have been difficult to avoid by conventional processes.

    摘要翻译： 一种制备乙烯共聚物的改进方法，该乙烯共聚物由主要比例的乙烯和少量的具有3-10个碳原子的α-烯烃组成，密度为0.910至0.945g / cm3，乙烯含量为85-99.5摩尔 ％。 使用符合特定要求的参数组合的钛催化剂组分（A）在该方法中是至关重要的。 该方法可以在工业上有利地以高生产率产生高质量的低至中密度乙烯共聚物，同时有利地避免了常规方法难以避免的操作麻烦。

    Process for producing olefin polymers and catalyst composition therefor
    5.
    发明授权
    Process for producing olefin polymers and catalyst composition therefor 失效
    制备烯烃聚合物的方法及其催化剂组合物

    公开(公告)号：US4673719A

    公开(公告)日：1987-06-16

    申请号：US563320

    申请日：1983-12-20

    申请人： Mamoru Kioka ,  Norio Kashiwa

    发明人： Mamoru Kioka ,  Norio Kashiwa

    IPC分类号： C08F4/00 ,  C08F4/60 ,  C08F4/64 ,  C08F4/658 ,  C08F10/00 ,  C08F10/02

    CPC分类号： C08F10/00

    摘要： In a process for producing olefin polymers or copolymers which comprises polymerizing olefins or copolymerizing olefins with each other or with dienes in the presence of [A] a solid titanium catalyst component containing magnesium, titanium and halogen as essential ingredients and [B] an organometallic compound of a metal selected from the group consisting of metals of Groups I to III of the periodic table; the improvement wherein said catalyst component [A] is obtained by contacting (i) a magnesium compound in the liquid state with (ii) a titanium compound in the liquid state to form a solid product or first preparing a liquid mixture of the magnesium compound (i) and the titanium compound (ii) and then forming a solid product therefrom, said reaction of forming the solid product being carried out in the presence of at least one electron donor (iii) selected from the group consisting of aliphatic carboxylic acids with 1 to 6 carbon atoms, aryloxy group-containing alcohols, alkylene glycol diethers, aluminum trialkoxides and aluminum triaryloxides, said solid product being not contacted, during or after its formation, with an ester selected from the group consisting of esters of polycarboxylic acids and esters of polyhydroxy compounds.

    摘要翻译： 在制备烯烃聚合物或共聚物的方法中，其包括在[A]含有镁，钛和卤素作为必需成分的固体钛催化剂组分的存在下彼此聚合烯烃或共聚烯烃或与二烯共聚，[B]有机金属化合物 的选自元素周期表第I至III族的金属的金属; 其中所述催化剂组分[A]是通过使（i）液态镁化合物与（ii）液态的钛化合物接触形成固体产物或首先制备镁化合物的液体混合物 i）和钛化合物（ii），然后由其形成固体产物，所述形成固体产物的反应在至少一种选自脂肪族羧酸与1族的电子给体（iii）的存在下进行， 至少6个碳原子，含芳氧基的醇，亚烷基二醇二醚，三烷氧基铝和三芳基铝，所述固体产物在其形成期间或之后不与选自以下的酯接触：多羧酸和酯的酯 多羟基化合物。

    Process and catalyst composition for producing olefin polymers
    6.
    发明授权
    Process and catalyst composition for producing olefin polymers 失效
    用于生产烯烃聚合物的方法和催化剂组合物

    公开(公告)号：US5075396A

    公开(公告)日：1991-12-24

    申请号：US331221

    申请日：1989-03-31

    申请人： Norio Kashiwa ,  Akinori Toyota ,  Mamoru Kioka

    发明人： Norio Kashiwa ,  Akinori Toyota ,  Mamoru Kioka

    IPC分类号： C08F4/00 ,  C08F4/46 ,  C08F4/60 ,  C08F4/64 ,  C08F4/658 ,  C08F10/00

    CPC分类号： C08F10/00

    摘要： A process for producing a polymer or copolymer of an olefin which comprises polymerizing or copolymerizing at least one olefin with or without a diolefin in the presence of a catalyst composed of (A) a magnesium-containing solid titanium catalyst component containing magnesium, titanium, a halogen and an electron donor as essential ingredients and (B) an organoaluminum compound catalyst component; characterized in that(1) said catalyst further comprises (C) an organic silicon compound catalyst component having an Si--O--C or Si--N--C bond, and(2) said electron donor in the catalyst component (A) is a cyclic mono- or poly-ester such as diethyl furane-3,4-dicarboxylate, di-n-butyl 3,4-dihydro-2H-pyrane-5,6-dicarboxylate, di-isobutyl pyrrole-2,3-dicarboxylic, di-n-butyl thiophene-2,3-dicarboxylate, n-octyl pyrrolidine-2,3-dicarboxylate, and so on.

    Solid catalyst for olefin polymerization and processes for its production
    9.
    发明授权
    Solid catalyst for olefin polymerization and processes for its production 失效
    用于烯烃聚合的固体催化剂及其生产方法

    公开(公告)号：US4921825A

    公开(公告)日：1990-05-01

    申请号：US245399

    申请日：1988-08-23

    申请人： Mamoru Kioka ,  Norio Kashiwa

    发明人： Mamoru Kioka ,  Norio Kashiwa

    IPC分类号： C08F4/642 ,  C08F4/60 ,  C08F4/64 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F110/02 ,  C08F210/16

    CPC分类号： C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  Y10S526/943

    摘要： This invention is a catalyst for polymerization of olefins, comprising a compound of a transition metal of Group IVB of the periodic table, an aluminoxane and a particulate organic or inorganic compound carrier.This catalyst shows very high activity in the polymerization and copolymerization of olefins and gives polymers having a high bulk density, a uniform particle size, a low content of fine particles and a narrow molecular weight distribution and in the case of copolymers, a narrow composition distribution as well.

    摘要翻译： PCT No.PCT / JP87 / 01047 Sec。 371日期1988年8月23日 102（e）日期1988年8月23日PCT提交1987年12月28日PCT公布。 公开号WO88 / 05058 日本特许公报1988年7月14日。本发明是烯烃聚合催化剂，其包括周期表第IVB族过渡金属的化合物，铝氧烷和有机或无机化合物颗粒。 该催化剂在烯烃的聚合和共聚中显示出非常高的活性，并且得到具有高堆积密度，均匀粒径，低含量的细颗粒和窄分子量分布的聚合物，在共聚物的情况下，组成分布窄 以及。