公开(公告)号：US3591628A

公开(公告)日：1971-07-06

申请号：US3591628D

申请日：1968-12-18

Applicant: TEXACO INC

Inventor： PATMORE EDWIN L

IPC: C07C51/15 ,  C07C255/32 ,  C07C51/14

CPC classification number: C07C255/00 ,  C07C51/15 ,  C07C2603/18 ,  C07C61/29 ,  C07C61/39

Abstract: A METHOD OF CARBOXYLATING INDENE, CYCLOPENTADIENE, FLUORENE AND HYDROCARBYL CYANIDE BY CONTACTING SAID COMPOUNDS WITH CARBON DIOXIDE UNDER SUBSTANTIALLY ANHYDROUS CONDITIONS IN THE PRESENCE OF A GUANIDINE OF THE FORMULA:

R1-N(-R2)-C(=N-R3)-N(-R3)-R4

WHERE R1 THROUGH R5 ARE HYDROGEN OR ALKYL OF FROM 1 TO 5 CARBONS AND ACIDIFYING THE RESULTANT REACTION MIXTURE TO FORM THE CARBOXYLIC ACID DERIVATIVE AND RECOVERING SAID DERIVATIVE THEREFROM.

公开(公告)号：US3694494A

公开(公告)日：1972-09-26

申请号：US3694494D

申请日：1971-02-03

Applicant: TEXACO INC

Inventor： PATMORE EDWIN L

IPC: C07C51/02 ,  C07C51/15 ,  C07C61/28

CPC classification number: C07C255/00 ,  C07C51/15 ,  C07C61/29 ,  C07C61/39

Abstract: A method of carboxylating indene, cyclopentadiene, fluorene and hydrocarbyl cyanide by contacting said compounds with carbon dioxide under substantially anhydrous conditions in the presence of a guanidine of the formula: WHERE R1 through R5 are hydrogen or alkyl of from one to five carbons and acidifying the resultant reaction mixture to form the carboxylic acid derivative and recovering said derivative therefrom.

Abstract translation: 在下式的胍存在下，在基本无水条件下使所述化合物与二氧化碳接触，使茚，环戊二烯，芴和烃基氰化合物羧化的方法：

公开(公告)号：US3867297A

公开(公告)日：1975-02-18

申请号：US32950573

申请日：1973-02-05

Applicant: TEXACO INC

Inventor： NEBZYDOSKI JOHN W ,  BROCKWAY HARRY ,  PATMORE EDWIN L ,  OBERENDER FREDERICK G

IPC: C10M169/00 ,  C10M1/38

CPC classification number: C10M3/00 ,  C10M2207/025 ,  C10M2207/28 ,  C10M2207/281 ,  C10M2207/282 ,  C10M2207/283 ,  C10M2207/284 ,  C10M2207/285 ,  C10M2207/286 ,  C10M2209/084 ,  C10M2209/109 ,  C10M2215/04 ,  C10M2215/064 ,  C10M2215/065 ,  C10M2215/26 ,  C10M2217/023 ,  C10M2219/108 ,  C10M2223/04 ,  C10M2223/041 ,  C10M2223/042 ,  C10M2229/041 ,  C10N2230/08 ,  C10N2240/02 ,  C10N2240/08 ,  C10N2240/12 ,  C10N2240/121

Abstract: A method of producing an alkyl amine salt of thiocyanic acid having enhanced load-carrying properties when employed in synthetic ester lubricating oils comprising contacting an alkyl amine with ammonium thiocyanate or monoalkyl ammonium thiocyanate at an elevated temperature while continuously blowing the reaction mixture with an oxygen containing gas and recovering the formed alkyl ammonium thiocyanate salt, the oxygen containing gas being introduced into the reaction mixture in a total amount of between about 0.2 and 5.0 moles per equivalent weight of amine; and synthetic ester oil compositions containing a load-carrying additive amount of the alkyl ammonium thiocyanate prepared by said method.

Abstract translation: 一种制备硫氰酸烷基胺盐的方法，其用于合成酯润滑油时具有增强的承载性能，包括使烷基胺与硫氰酸铵或硫氰酸单烷基铵在升高的温度下接触，同时用含氧的 气体并回收形成的硫氰酸烷基铵盐，将含氧气体以每当量胺为约0.2至5.0摩尔的总量引入反应混合物中; 以及含有负载量的硫氰酸烷基铵的合成酯油组合物，其通过所述方法制备。

公开(公告)号：US3694496A

公开(公告)日：1972-09-26

申请号：US3694496D

申请日：1971-02-03

Applicant: TEXACO INC

Inventor： PATMORE EDWIN L

IPC: C07C51/15 ,  C07C63/44

CPC classification number: C07C255/00 ,  C07C51/15 ,  C07C2603/18 ,  C07C61/29 ,  C07C61/39

Abstract: A method of carboxylating indene, cyclopentadiene, fluorene and hydrocarbyl cyanide by contacting said compounds with carbon dioxide under substantially anhydrous conditions in the presence of a guanidine of the formula: WHERE R1 through R5 are hydrogen or alkyl of from one to five carbons and acidifying the resultant reaction mixture to form the carboxylic acid derivative and recovering said derivative therefrom.

公开(公告)号：US3696146A

公开(公告)日：1972-10-03

申请号：US3696146D

申请日：1971-11-10

Applicant: EDWIN L PATMORE ,  WILLIAM R SIEGART ,  HARRY CHAFETZ ,  TEXACO INC

Inventor： PATMORE EDWIN L ,  SIEGART WILLIAM R ,  CHAFETZ HARRY

IPC: C07C51/15 ,  C07C53/00 ,  C07C63/00

CPC classification number: C07C255/00 ,  C07C51/15 ,  C07C61/39 ,  C07C61/29 ,  C07C57/42

Abstract: Method of carboxylating an organic compound of the group of RC*CH, RCH2CN, indene or cyclopentadiene where R is hydrocarbyl comprising contacting under anhydrous conditions in an inert atmosphere and in the presence of an inert, aprotic, dipolar, liquid solvent, said compound with a carbonated metal phenoxide, the metal phenoxide of the formula: WHERE X is sodium or potassium, R1 is hydrogen or alkyl, and subsequently acidifying the resultant intermediate product to form the carboxylated product.

Abstract translation: 羧基化RC 3BOND CH，RCH 2 CN，茚或环戊二烯的有机化合物的方法，其中R是烃基，包括在无水条件下在惰性气氛中和在惰性，非质子，偶极，液体溶剂的存在下接触，所述化合物与 碳酸化金属酚盐，下式的金属酚盐：

公开(公告)号：US3689539A

公开(公告)日：1972-09-05

申请号：US3689539D

申请日：1971-02-03

Applicant: TEXACO INC

Inventor： PATMORE EDWIN L ,  SIEGART WILLIAM R ,  CHAFETZ HARRY

IPC: C07C51/15 ,  C07C57/42 ,  C07C51/00

CPC classification number: C07C255/00 ,  C07C51/15 ,  C07C2603/18 ,  C07C57/30 ,  C07C57/42 ,  C07C61/39 ,  C07C61/29

Abstract: Method of carboxylating a compound of the group of R-C CH, RCH2CN, indene, cyclopentadiene or fluorene, where R is hydrocarbyl, comprising contacting said compound with carbon dioxide under substantially anhydrous conditions in the presence of a base of the formula: WHERE X is sodium or potassium, R1 is hydrogen or alkyl and subsequently acidifying the resultant reaction product to form the carboxylated product.

Abstract translation: 羧基化R-C CENT CH，RCH2CN，茚，环戊二烯或芴基的化合物的方法，其中R是烃基，包括在基本无水条件下，在下式的碱存在下使所述化合物与二氧化碳接触：

公开(公告)号：US3595907A

公开(公告)日：1971-07-27

申请号：US3595907D

申请日：1968-12-18

Applicant: TEXACO INC

Inventor： PATMORE EDWIN L ,  SIEGART WILLIAM R ,  CHAFETZ HARRY

IPC: C07C51/14 ,  C07C51/15

CPC classification number: C07C255/00 ,  C07C51/15 ,  C07C2603/18 ,  C07C57/42 ,  C07C61/39 ,  C07C57/30 ,  C07C61/29

Abstract: METHOD OF CARBOXYLATING A COMPOUND OF THE GROUP OF R.C=CH,RCH2CN, INDENE, CYCLOPENADIENE OR FLUORENE, WHERE R IS HYDROCARBYL, COMPRISING CONTACTING SAID COMPOUND WITH CARBON DIOXIDE UNDER SUBSTANTIALLY ANHYDROUS CONDITIONS IN THE PRESENCE OF A BASE OF THE FORMULA:

R1,(X-O-)BENZENE

WHERE X IS SODIUM OR POTASSIUM, R**1 IS HYDROGEN OR ALKYL AND SUBSEQUENTLY ACIDIFYING THE RESULTANT REACTION PRODUCT TO FORM THE CARBOXYLATED PRODUCT.

公开(公告)号：US3658874A

公开(公告)日：1972-04-25

申请号：US3658874D

申请日：1969-01-27

Applicant: TEXACO INC

Inventor： PATMORE EDWIN L ,  SIEGART WILLIAM R ,  CHAFETZ HARRY

IPC: C07B61/00 ,  C07C51/15 ,  C07C57/18 ,  C07C51/00 ,  C07C121/40 ,  C07C121/66

CPC classification number: C07C255/00 ,  C07C51/15 ,  C07C57/18 ,  C07C61/29 ,  C07C57/42

Abstract: METHOD OF CARBOXYLATING AN ORGANIC COMPOUND OF THE GROUP OF RC$CH, RCH2CN, INDENE OR CYCLOPENTADIENE WHERE R IS HYDROCARBYL COMPRISING CONTACTING UNDER ANHYDROUS CONDITIONS IN AN ENERT ATMOSPHERE AND IN THE PRESENCE OF AN INERT, APROTIC, DIPOLAR, LIQUID SOLVENT, SAID COMPOUND WITH A CARBONATED METAL PHENOXIDE, THE METAL PHENOXIDE OF THE FORMULA:

(R1-PHENYL)-O-X

WHERE X IS SODIUM OR POTASSIUM, R1 IS HYDROGEN OR ALKYL, AND SUBSEQUENTLY ACIDIFYING THE RESULTANT INTERMEDIATE PRODUCT TO FORM THE CARBOXYLATED PRODUCT.

公开(公告)号：US3408351A

公开(公告)日：1968-10-29

申请号：US57490166

申请日：1966-08-25

Applicant: TEXACO INC

Inventor： HARRY CHAFETZ ,  PATMORE EDWIN L

IPC: C07D221/12

CPC classification number: C07D221/12