Abstract:
METHOD OF CARBOXYLATING AN ORGANIC COMPOUND OF THE GROUP OF RC$CH, RCH2CN, INDENE OR CYCLOPENTADIENE WHERE R IS HYDROCARBYL COMPRISING CONTACTING UNDER ANHYDROUS CONDITIONS IN AN ENERT ATMOSPHERE AND IN THE PRESENCE OF AN INERT, APROTIC, DIPOLAR, LIQUID SOLVENT, SAID COMPOUND WITH A CARBONATED METAL PHENOXIDE, THE METAL PHENOXIDE OF THE FORMULA:
(R1-PHENYL)-O-X
WHERE X IS SODIUM OR POTASSIUM, R1 IS HYDROGEN OR ALKYL, AND SUBSEQUENTLY ACIDIFYING THE RESULTANT INTERMEDIATE PRODUCT TO FORM THE CARBOXYLATED PRODUCT.
Abstract:
Antistatic fuel composition comprising a mixture of hydrocarbons in the gasoline, kerosene and/or furnace oil boiling ranges and a minor amount of a reaction product of an aliphatic monoamine having the formula RNH2 in which R is an aliphatic radical having from eight to 20 carbon atoms and either a fluorinated polystyrene having the empirical formula: (C16H3F25)x in which x is an average integer between 3 to 5, or a fluorinated polypropylene having the empirical formula: (C3HF5)x in which x has a value from 20 to 40, and a method for preparing the above-noted aliphatic monoamine derivatives.
Abstract:
Lubricating oil compositions containing antioxidant mixtures of heterocyclic nitrogenous aromatic compounds derived from uintaite which function to prevent the oxidative thickening of lubricant oils at high temperatures.
Abstract:
Method of carboxylating an organic compound of the group of RC*CH, RCH2CN, indene or cyclopentadiene where R is hydrocarbyl comprising contacting under anhydrous conditions in an inert atmosphere and in the presence of an inert, aprotic, dipolar, liquid solvent, said compound with a carbonated metal phenoxide, the metal phenoxide of the formula: WHERE X is sodium or potassium, R1 is hydrogen or alkyl, and subsequently acidifying the resultant intermediate product to form the carboxylated product.
Abstract:
Method of carboxylating a compound of the group of R-C CH, RCH2CN, indene, cyclopentadiene or fluorene, where R is hydrocarbyl, comprising contacting said compound with carbon dioxide under substantially anhydrous conditions in the presence of a base of the formula: WHERE X is sodium or potassium, R1 is hydrogen or alkyl and subsequently acidifying the resultant reaction product to form the carboxylated product.