公开(公告)号：US09963589B2

公开(公告)日：2018-05-08

申请号：US14897393

申请日：2014-07-24

申请人： TORAY Industries, Inc.

发明人： Maki Nagano ,  Ayako Fuse ,  Nobuyuki Tomioka

IPC分类号： B32B27/38 ,  C08J5/24 ,  C08L63/00 ,  C08G59/24 ,  C08G59/28 ,  C08G59/38 ,  C08G59/50 ,  C08G59/32

CPC分类号： C08L63/00 ,  C08G59/245 ,  C08G59/3218 ,  C08G59/502 ,  C08J5/24 ,  C08J2363/00 ,  C08J2400/22 ,  C08J2400/26 ,  C08J2453/00 ,  C08J2477/00 ,  C08J2481/06 ,  C08L2205/025 ,  C08L101/00

摘要： An epoxy resin composition comprising the following constituents [A], [B], and [C]:[A] an epoxy resin having a structure represented by a formula (1); in which a ring Z represents a condensed polycyclic aromatic hydrocarbon ring, R1 and R2 represent a substituent, R3 represents a hydrogen atom or a methyl group, k is an integer of 0 to 4, m is an integer of 0 or more, and n is an integer of 1 or more; [B] at least one resin selected from the group consisting of the following [Bx], [By] and [Bz]; [Bx] a bisphenol type epoxy resin; [By] an amine type epoxy resin; and [Bz] a thermoplastic resin; [C] a polyamine curing agent. Provided is an epoxy resin composition which provides a cured product having excellent heat resistance, toughness and elastic modulus.

公开(公告)号：US20140309337A1

公开(公告)日：2014-10-16

申请号：US14353441

申请日：2012-12-25

申请人： TORAY INDUSTRIES, INC.

发明人： Maki Nagano ,  Yuko Shimizu ,  Nobuyuki Tomioka

IPC分类号： C08L63/00

CPC分类号： C08L63/00 ,  C08G59/28 ,  C08G59/32 ,  C08G59/5033 ,  C08J5/24 ,  C08J2363/00 ,  C08L53/00 ,  C08L101/00

摘要： Provided are: a fiber-reinforced composite material which is suppressed in morphology variation due to the molding conditions, while having excellent mode I interlaminar fracture toughness and excellent wet heat resistance; an epoxy resin composition for obtaining the fiber-reinforced composite material; and a prepreg which is obtained using the epoxy resin composition. An epoxy resin composition for fiber-reinforced composite materials, which contains at least the following constituent elements [A]-[F], and which is characterized by containing 5-25 parts by mass of constituent element [C] and 2-15 parts by mass of constituent element [E] per 100 parts by mass of the total epoxy resin blended therein. [A] A bifunctional amine type epoxy resin. [B] A tetrafunctional amine type epoxy resin. [C] A bisphenol F type epoxy resin having an epoxy equivalent weight of 450-4,500. [D] An aromatic amine curing agent. [E] A block copolymer having a reactive group that can be reacted with as epoxy resin. [F] Thermoplastic resin particles that are insoluble in an epoxy resin.

摘要翻译： 提供：纤维增强复合材料，其由于成型条件而抑制形态变化，同时具有优异的模式I层间断裂韧性和优异的耐湿热性; 用于获得纤维增强复合材料的环氧树脂组合物; 和使用该环氧树脂组合物得到的预浸料坯。 至少含有以下组成元素[A] - [F]的纤维增强复合材料用环氧树脂组合物，其特征在于，含有5〜25质量份的构成元素[C]和2〜15份 的构成元素[E] / 100质量份混合的总环氧树脂。 [A]双官能胺型环氧树脂。 [B]四官能胺型环氧树脂。 [C]环氧当量为450〜4500的双酚F型环氧树脂。 [D]芳香胺固化剂。 [E]具有可与环氧树脂反应的反应性基团的嵌段共聚物。 [F]不溶于环氧树脂的热塑性树脂颗粒。

公开(公告)号：US10829587B2

公开(公告)日：2020-11-10

申请号：US15762643

申请日：2016-07-21

申请人： Toray Industries, Inc.

发明人： Maki Nagano ,  Ayako Fuse ,  Nobuyuki Tomioka

IPC分类号： C08G59/24 ,  C08J5/24 ,  C08L63/00 ,  C08K5/41 ,  C08G59/20 ,  C08L101/00 ,  C08K5/315 ,  C08G59/50 ,  C08G59/28 ,  C08G59/30

摘要： An epoxy resin composition produces a cured product having improved elastic modulus and improved nominal strain at compressive fracture. The epoxy resin composition is a fiber-reinforced composite material having excellent compression strength and interlayer toughness. The epoxy resin composition contains at least the following constituent components [A], [B] and [C]. [A] A specific ortho type epoxy resin. [B] At least one component selected from the group consisting of: thermoplastic resins that are compatible with the epoxy resin [A]; and core-shell type polymers. [C] An amine curing agent.

公开(公告)号：US09243139B2

公开(公告)日：2016-01-26

申请号：US14104586

申请日：2013-12-12

申请人： TORAY INDUSTRIES, INC.

发明人： Maki Nagano ,  Nobuyuki Tomioka ,  Takayuki Imaoka ,  Shiro Honda

IPC分类号： B32B27/04 ,  B32B27/38 ,  C08L63/00 ,  C08L63/02 ,  C08G59/42 ,  C08G59/50 ,  C08G59/68 ,  C08J5/24 ,  C08L53/02

CPC分类号： C08L63/00 ,  B32B27/04 ,  B32B27/38 ,  C08G59/4238 ,  C08G59/50 ,  C08G59/686 ,  C08J5/24 ,  C08J2363/00 ,  C08L53/02 ,  Y10T428/24994 ,  Y10T428/24995 ,  C08L2666/08

摘要： An epoxy resin composition comprising an epoxy resin [A], an amine-based curing agent [B] and a block copolymer [C] as components, wherein the epoxy resin [A] contains [Aa] an epoxy resin having at least one structure selected from a condensed polycyclic structure, biphenyl structure and oxazolidone ring structure; [Ab] an epoxy resin selected from a polyfunctional amine type epoxy resin [Ab1] and a liquid bisphenol type epoxy resin [Ab2], and the block copolymer [C] is at least one block copolymer selected from the group consisting of S-B-M, B-M and M-B-M. The present invention provides an epoxy resin composition that can be cured to form a cured product excellent in heat resistance, elastic modulus and toughness.

摘要翻译： 包含环氧树脂[A]，胺基固化剂[B]和嵌段共聚物[C]作为组分的环氧树脂组合物，其中环氧树脂[A]含有具有至少一个结构的环氧树脂 选自缩合多环结构，联苯结构和恶唑烷酮环结构; [Ab]选自多官能胺型环氧树脂[Ab1]和液体双酚型环氧树脂[Ab2]的环氧树脂，嵌段共聚物[C]为选自SBM，BM 和MBM。 本发明提供一种能够固化以形成耐热性，弹性模量和韧性优异的固化物的环氧树脂组合物。