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    Flame-retardant electrolytic capacitor
    3.
    发明授权
    Flame-retardant electrolytic capacitor 有权
    阻燃电解电容器

    公开(公告)号：US09496092B2

    公开(公告)日：2016-11-15

    申请号：US14411414

    申请日：2013-07-01

    申请人： NIPPON CHEMI-CON CORPORATION ,  TOSOH F-TECH, INC.

    发明人： Masashi Ozawa ,  Junichi Kawakami ,  Hideyuki Mimura ,  Hisao Eguchi

    IPC分类号： H01G11/54 ,  H01G9/145 ,  H01G11/58 ,  H01G9/035

    CPC分类号： H01G9/145 ,  H01G9/035 ,  H01G11/54 ,  H01G11/58

    摘要： Provided is a flame-retardant electrolytic capacitor which is capable of maintaining flame-retardant effect even after a prolonged period of time. This is an electrolytic capacitor comprising an anode foil that is provided with an oxide film on the surface, a cathode foil, a separator, and an electrolytic solution that contains a solute in a solvent, wherein a phosphoric acid ester amide represented by the following general formula (1) is contained in the electrolytic solution: in which n is 1 or 2, and R1 and R2 each independently represent a linear or branched alkyl group having 1 to 10 carbon atoms, and Rf represents a linear or branched fluoroalkyl group having 1 to 10 carbon atoms or a linear or branched alkyl group having 1 to 10 carbon atoms).

    FLAME-RETARDANT ELECTROLYTIC CAPACITOR
    4.
    发明申请
    FLAME-RETARDANT ELECTROLYTIC CAPACITOR 有权
    阻燃电解电容器

    公开(公告)号：US20150325381A1

    公开(公告)日：2015-11-12

    申请号：US14411414

    申请日：2013-07-01

    申请人： NIPPON CHEMI-CON CORPORATION ,  TOSOH F-TECH, INC.

    发明人： Masashi Ozawa ,  Junichi Kawakami ,  Hideyuki Mimura ,  Hisao Eguchi

    IPC分类号： H01G9/145

    CPC分类号： H01G9/145 ,  H01G9/035 ,  H01G11/54 ,  H01G11/58

    摘要： Provided is a flame-retardant electrolytic capacitor which is capable of maintaining flame-retardant effect even after a prolonged period of time. This is an electrolytic capacitor comprising an anode foil that is provided with an oxide film on the surface, a cathode foil, a separator, and an electrolytic solution that contains a solute in a solvent, wherein a phosphoric acid ester amide represented by the following general formula (1) is contained in the electrolytic solution: in which n is 1 or 2, and R1 and R2 each independently represent a linear or branched alkyl group having 1 to 10 carbon atoms, and Rf represents a linear or branched fluoroalkyl group having 1 to 10 carbon atoms or a linear or branched alkyl group having 1 to 10 carbon atoms).

    摘要翻译： 提供一种即使在长时间内也能够保持阻燃效果的阻燃电解电容器。 这是一种电解电容器，其包括在表面上设置有氧化物膜的阳极箔，阴极箔，隔膜和在溶剂中含有溶质的电解液，其中由以下通式表示的磷酸酯酰胺 式（1）包含在电解液中：其中n为1或2，R 1和R 2各自独立地表示具有1至10个碳原子的直链或支链烷基，Rf表示具有1个直链或支链的氟代烷基 至10个碳原子或具有1至10个碳原子的直链或支链烷基）。

    METHOD FOR STABILIZING LIPF6, ELECTROLYTE SOLUTION FOR NONAQUEOUS SECONDARY BATTERIES HAVING EXCELLENT THERMAL STABILITY, AND NONAQUEOUS SECONDARY BATTERY HAVING EXCELLENT THERMAL STABILITY
    5.
    发明申请
    METHOD FOR STABILIZING LIPF6, ELECTROLYTE SOLUTION FOR NONAQUEOUS SECONDARY BATTERIES HAVING EXCELLENT THERMAL STABILITY, AND NONAQUEOUS SECONDARY BATTERY HAVING EXCELLENT THERMAL STABILITY 有权
    用于稳定LIPF6的方法，具有极好的热稳定性的非水二次电池的电解液，以及具有极好的热稳定性的非水二次电池

    公开(公告)号：US20150140445A1

    公开(公告)日：2015-05-21

    申请号：US14406884

    申请日：2013-06-13

    申请人： TOSOH F-TECH, INC.

    发明人： Masahiro Aoki ,  Hideyuki Mimura ,  Hisao Eguchi

    IPC分类号： H01M10/0567 ,  H01G11/56 ,  H01M10/0568 ,  C07F9/24 ,  H01M10/052

    CPC分类号： H01M10/0567 ,  C07F9/091 ,  C07F9/11 ,  C07F9/1411 ,  C07F9/224 ,  C07F9/24 ,  C07F9/2458 ,  C07F9/2462 ,  C07F9/2466 ,  C07F9/247 ,  C07F9/650952 ,  C07F9/6533 ,  C07F9/6544 ,  H01G11/56 ,  H01G11/58 ,  H01M10/052 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2300/0025 ,  H01M2300/0037 ,  Y02E60/122 ,  Y02E60/13 ,  Y02T10/7011 ,  Y02T10/7022

    摘要： [Problem] To provide: a method for stabilizing a solution that contains LiPF6 by increasing thermal stability of LiPF6 without changing the structure thereof; an electrolyte solution for nonaqueous secondary batteries, which has increased thermal stability; and a nonaqueous secondary battery which has increased thermal stability.[Solution] To have a solution containing LiPF6 contain a phosphoric acid ester amide represented by general formula (I) in such an amount that the molar ratio of the phosphoric acid ester amide relative to LiPF6 is 0.001-2. (In the formula, m represents an integer of 1 or 2; each of R1 and R2 represents a branched or linear alkyl group having 1 to 6 carbon atoms and/or a hydrocarbon group having an unsaturated bond, provided that R1 and R2 may have a substituent that is selected from the group consisting of an alkoxy group, an amino group, an alkylthio group, a saturated heterocyclic group, an unsaturated heterocyclic group, and a fluorine atom, and R1 and R2 may combine together to form a 5 to 8 membered cyclic structure; and R3 represents a branched or linear alkyl group having 1 to 6 carbon atoms or a branched or linear fluorine-containing alkyl group having 1 to 6 carbon atoms)

    摘要翻译： [问题]提供：通过增加LiPF 6的热稳定性而不改变其结构来稳定含有LiPF 6的溶液的方法; 非水系二次电池用电解液，其热稳定性提高; 和具有增加的热稳定性的非水二次电池。 [溶液]为了使含有LiPF 6的溶液含有通式（I）所示的磷酸酯酰胺，其量使得磷酸酯酰胺相对于LiPF 6的摩尔比为0.001-2。 （式中，m表示1或2的整数，R1和R2各自表示碳原子数1〜6的支链或直链烷基，和/或具有不饱和键的烃基，只要R 1和R 2可具有 选自烷氧基，氨基，烷硫基，饱和杂环基，不饱和杂环基和氟原子的取代基，R1和R2可以组合在一起形成5至8个 R3表示碳原子数1〜6的支链或直链烷基或碳原子数1〜6的支链或直链状含氟烷基）

    FLUORINE-CONTAINING PHOSPHATE ESTER-AMIDE, AND FLAME RETARDANT RESIN, FLAME RETARDANT LIQUID AND FLAME RETARDANT SOLVENT FOR ORGANIC SYNTHESIS CONTAINING SAME
    6.
    发明申请
    FLUORINE-CONTAINING PHOSPHATE ESTER-AMIDE, AND FLAME RETARDANT RESIN, FLAME RETARDANT LIQUID AND FLAME RETARDANT SOLVENT FOR ORGANIC SYNTHESIS CONTAINING SAME 有权
    含氟磷酸酯酰胺和阻燃树脂，阻燃剂液体和阻燃剂用于有机合成

    公开(公告)号：US20150053901A1

    公开(公告)日：2015-02-26

    申请号：US14385862

    申请日：2013-03-22

    申请人： TOSOH F- TECH, INC.

    发明人： Hideyuki Mimura ,  Hiroaki Fujita ,  Hisao Eguchi

    IPC分类号： C07F9/59 ,  C09K21/12 ,  C08G18/24 ,  C08G18/72 ,  C08G18/32 ,  C07F9/24 ,  C08J9/00

    CPC分类号： C07F9/59 ,  C07F9/2408 ,  C07F9/2454 ,  C07F9/2458 ,  C08G18/24 ,  C08G18/32 ,  C08G18/72 ,  C08J9/0038 ,  C08J2375/04 ,  C09K21/12 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/4235

    摘要： [Problem] To provide a fluorine-containing phosphate ester-amide which has high flame retardancy such as exhibiting flame retardant effects at a small quantity of addition, and sufficient hydrolysis resistance.[Solution] A fluorine-containing phosphate ester-amide represented by general formula (1). (In the formula, R1 and R2 are the same or different and represent a branched or linear alkyl group having 1 to 20 carbon atoms in which at least one carbon bonded to a nitrogen atom is a secondary or tertiary carbon, wherein R1 and R2 may have a substituent group selected from the group consisting of an alkoxy group, a hydroxy group, an amino group, a methyl amino group, an ethyl amino group, a dimethyl amino group, diethyl amino group and a fluorine atom. In addition, R1 and R2 may be bonded together to form a five- to eight-membered cyclic structure. X and Y are the same or different and represent a hydrogen atom or a fluorine atom, and n and m represent an integer of 1 to 6.)

    摘要翻译： [问题]提供一种具有高阻燃性的含氟磷酸酯 - 酰胺，例如在少量添加下显示出阻燃效果，并且具有足够的耐水解性。 [溶液]由通式（1）表示的含氟磷酸酯 - 酰胺。 （式中，R 1和R 2相同或不同，表示碳原子数1〜20的支链或直链烷基，其中至少一个与氮原子键合的碳为仲或叔碳，其中R1和R2可以 具有选自烷氧基，羟基，氨基，甲基氨基，乙基氨基，二甲基氨基，二乙基氨基和氟原子的取代基，此外，R1和 R2可以结合在一起形成五元至八元环状结构，X和Y相同或不同，表示氢原子或氟原子，n和m表示1〜6的整数。）