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公开(公告)号：US20090318681A1
公开(公告)日：2009-12-24
申请号：US12518396
申请日：2007-12-11
IPC分类号： C07D257/10 , C07D487/18
CPC分类号： C07F13/005 , B01J31/1805 , B01J31/1815 , B01J31/2213 , B01J2531/0252 , B01J2531/845 , C07C251/24 , C07C2601/14 , C07D257/10 , C07F15/065
摘要： Provided is a metal complex represented by the following formula (A-1) or (B-1) as a metal complex useful for a redox reaction catalyst or some other article that is excellent in heat resistance and acid resistance:
摘要翻译： 提供作为可用于氧化还原反应催化剂的金属络合物或其耐热性和耐酸性优异的其它制品的由下式（A-1）或（B-1）表示的金属络合物：
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公开(公告)号：US20090062110A1
公开(公告)日：2009-03-05
申请号：US12278180
申请日：2007-01-01
CPC分类号： B01J31/2243 , B01J31/1815 , B01J31/223 , B01J35/002 , B01J37/082 , B01J2531/0205 , B01J2531/0241 , B01J2531/025 , B01J2531/16 , B01J2531/56 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07D257/10
摘要： A polynuclear metal complex having in each molecule not only at least one large cyclic ligand having 5 to 15 coordinating atoms but also multiple metal atoms is subjected to any of heating treatment, radiation exposure treatment and electric discharge treatment, thereby providing a polynuclear metal complex exhibiting a ratio of weight loss by the treatment of 5 to 90 wt. % and a carbon content after the treatment of 5 wt. % or more.
摘要翻译： 在每个分子中不仅具有至少一个具有5至15个配位原子的大环配体，而且具有多个金属原子的多核金属络合物经受加热处理，辐射暴露处理和放电处理中的任一种，从而提供多核金属络合物， 通过处理5至90wt。的重量损失比率。 ％，处理后的碳含量为5wt。 ％ 或者更多。
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公开(公告)号：US08546291B2
公开(公告)日：2013-10-01
申请号：US12811025
申请日：2008-09-05
IPC分类号： B01J31/22 , C07D471/22 , C07D487/22 , C07F15/06 , C07F19/00 , C07F15/04 , C07F1/08 , C08F26/06
CPC分类号： H01M4/8652 , C07D207/335 , C07D471/04 , C07D471/22 , C07D487/22 , H01G9/2018 , H01L51/0083 , H01L51/009 , H01M4/9008 , H01M4/9075 , H01M4/9091 , H01M4/923 , H01M4/925 , H01M4/928 , H01M8/0289 , H01M8/1016 , Y02E10/542 , Y02E60/521
摘要： A compound represented by formula (1): wherein Y1 to Y4 each independently represent any one of the following groups: in which Rα represents a hydrogen atom or a monovalent hydrocarbon group; P1 to P4 each independently represent a group of atoms necessary for forming a heterocyclic ring together with each of Y1 to Y4 and the two carbon atoms adjacent to each of Y1 to Y4, respectively; P5 and P6 each independently represent a group of atoms necessary for forming a cyclic skeleton together with the carbon atom to which Z1 bonds or Z2 bonds and the two carbon atoms adjacent to the carbon atom to which Z1 bonds or Z2 bonds; P1 and P2, P2 and P6, P6 and P4, P4 and P3, P3 and P5, and P5 and P1 may further combine with each other to form a ring; Q1 and Q2 each independently represent a connecting group or a direct binding; and Z1 and Z2 each independently represent any one of the following groups; —NRβ2, —ORβ, —SRβ, —PRβ2 in which Rβ represents a hydrogen atom or a monovalent hydrocarbon group, and when plural Rβs are present, these plural Rβs may be the same or different from each other.
摘要翻译： 由式（1）表示的化合物：其中Y 1至Y 4各自独立地表示以下基团中的任一个：其中Ralpha表示氢原子或一价烃基; P1〜P4各自独立地表示与Y 1〜Y 4中的每一个以及Y1〜Y4中的每个相邻的2个碳原子一起形成杂环所需的原子团。 P5和P6各自独立地表示与Z1键或Z2键以及与Z1键或Z2键相邻的碳原子相邻的两个碳原子一起形成环状骨架所必需的一组原子; P1和P2，P2和P6，P6和P4，P4和P3，P3和P5，P5和P1可以进一步组合形成环; Q1和Q2各自独立地表示连接基团或直接结合; Z1和Z2各自独立地表示以下基团中的任何一个; -NRbeta2，-ORbeta，-SRbeta，-PRbeta2，其中Rbeta表示氢原子或一价烃基，当存在多个Rbetas时，这些多个Rbetas可以相同或不同。
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公开(公告)号：US20100105909A1
公开(公告)日：2010-04-29
申请号：US12530174
申请日：2008-03-10
CPC分类号： C07D213/30 , B01J31/1805 , B01J31/1815 , B01J31/183 , B01J31/223 , B01J2531/0252 , B01J2531/16 , B01J2531/56 , B01J2531/72 , B01J2531/842 , B01J2531/845 , C07D471/04
摘要： A modified metal complex obtained by subjecting a metal complex containing an organic compound having one nitrogen-containing aromatic heterocycle and four or more structures of a phenol, thiophenol, aniline or nitrogen-containing aromatic heterocyclic ring or an organic compound having two or more phenol rings and three or more nitrogen-containing aromatic heterocycles, in its molecule as a ligand, to a heating, radiation irradiation or discharge treatment until a mass reduction rate after the treatment becomes from 1 to 90 mass %, thereby the complex shows a carbon content after the treatment of 5 mass % or more.
摘要翻译： 一种改性金属络合物，其通过使含有一个含氮芳族杂环的有机化合物和四种或更多种酚，苯硫酚，苯胺或含氮芳族杂环的结构的金属络合物或具有两个或多个酚环的有机化合物 在其分子中含有3个以上的含氮芳香族杂环作为配体，进行加热，放射线照射或放电处理，直到处理后的质量降低率为1〜90质量％，由此，复合物显示出碳后的碳含量 治疗5％以上。
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公开(公告)号：US20110015059A1
公开(公告)日：2011-01-20
申请号：US12811025
申请日：2008-09-05
IPC分类号： B01J31/22 , C07D471/22 , C07D487/22 , C07F15/06 , C07F19/00 , C07F15/04 , C07F1/08 , C08F26/06
CPC分类号： H01M4/8652 , C07D207/335 , C07D471/04 , C07D471/22 , C07D487/22 , H01G9/2018 , H01L51/0083 , H01L51/009 , H01M4/9008 , H01M4/9075 , H01M4/9091 , H01M4/923 , H01M4/925 , H01M4/928 , H01M8/0289 , H01M8/1016 , Y02E10/542 , Y02E60/521
摘要： A compound represented by formula (1): wherein Y1 to Y4 each independently represent any one of the following groups: in which Rα represents a hydrogen atom or a monovalent hydrocarbon group; P1 to P4 each independently represent a group of atoms necessary for forming a heterocyclic ring together with each of Y1 to Y4 and the two carbon atoms adjacent to each of Y1 to Y4, respectively; P5 and P6 each independently represent a group of atoms necessary for forming a cyclic skeleton together with the carbon atom to which Z1 bonds or Z2 bonds and the two carbon atoms adjacent to the carbon atom to which Z1 bonds or Z2 bonds; P1 and P2, P2 and P6, P6 and P4, P4 and P3, P3 and P5, and P5 and P1 may further combine with each other to form a ring; Q1 and Q2 each independently represent a connecting group or a direct binding; and Z1 and Z2 each independently represent any one of the following groups; —NRβ2, —ORβ, —SRβ, —PRβ2 in which Rβ represents a hydrogen atom or a monovalent hydrocarbon group, and when plural Rβs are present, these plural Rβs may be the same or different from each other.
摘要翻译： 由式（1）表示的化合物：其中Y 1至Y 4各自独立地表示以下基团中的任一个：其中Rα表示氢原子或一价烃基; P1〜P4各自独立地表示与Y 1〜Y 4中的每一个以及Y1〜Y4中的每个相邻的2个碳原子一起形成杂环所需的原子团。 P5和P6各自独立地表示与Z1键或Z2键以及与Z1键或Z2键相邻的碳原子相邻的两个碳原子一起形成环状骨架所必需的一组原子; P1和P2，P2和P6，P6和P4，P4和P3，P3和P5，P5和P1可以进一步组合形成环; Q1和Q2各自独立地表示连接基团或直接结合; Z1和Z2各自独立地表示以下基团中的任何一个; -NR＆bgr; 2，-OR＆bgr; -SR＆bgr; -PR＆bgr; 2其中R＆bgr; 表示氢原子或一价烃基，当存在多个R b时，这些多个R a可相同或不同。
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公开(公告)号：US20100129698A1
公开(公告)日：2010-05-27
申请号：US12530187
申请日：2008-03-10
申请人： Tatsuhiro Okada , Nobuyoshi Koshino , Tadafumi Matsunaga , Hideyuki Higashimura , Katsuhiro Suenobu , Masatoshi Iwata
发明人： Tatsuhiro Okada , Nobuyoshi Koshino , Tadafumi Matsunaga , Hideyuki Higashimura , Katsuhiro Suenobu , Masatoshi Iwata
IPC分类号： H01M4/86
CPC分类号： H01M4/9008 , B01J31/1805 , B01J31/1815 , B01J31/183 , B01J31/223 , B01J2531/0216 , B01J2531/0252 , B01J2531/16 , B01J2531/56 , B01J2531/72 , B01J2531/842 , B01J2531/845 , H01M4/8605 , H01M4/8882 , H01M2008/1095
摘要： An electrode catalyst for fuel cell, containing a multinuclear complex, in which the multinuclear complex contains 2 to 4 transition metal atoms coordinated with a ligand having 5 to 15 coordination atoms in its molecule; and an electrode catalyst for fuel cell, comprising a mononuclear metal complex containing, as a ligand, an organic compound containing two or more phenol rings and three or more aromatic heterocycles.
摘要翻译： 一种含有多核络合物的燃料电池用电极催化剂，其中多核络合物含有与分子中具有5〜15个配位原子的配体配位的2〜4个过渡金属原子; 以及燃料电池用电极催化剂，其包含含有作为配体的含有2个以上酚环和3个以上芳香族杂环的有机化合物的单核金属络合物。
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公开(公告)号：US20100105853A1
公开(公告)日：2010-04-29
申请号：US12530413
申请日：2008-03-10
IPC分类号： C08F130/04 , C07F15/02 , C07F13/00
CPC分类号： C07D213/30 , B01J31/1815 , B01J31/183 , B01J31/2243 , B01J2531/0252 , B01J2531/16 , B01J2531/72 , B01J2531/84 , C07D409/14 , C07D471/04 , C08F110/02 , C08F110/06
摘要： A metal complex represented by the following formula (1): wherein R1 to R6 each independently represent a hydrogen atom or a substituent; Y1 and Y2 each independently represent any one of the following groups: wherein Rα represents a hydrogen atom or a hydrocarbon group having 1 to 4 carbon atoms; P1 and P2 each represent a group of atoms necessary for forming a heterocyclic ring together with Y1 or Y2 and the two carbon atoms at a position adjacent to Y1 or Y2; P1 and P2 may be linked to each other to form a ring; M represents a transition metal element or typical metal element; m represents 1 or 2; X represents a counter ion or a neutral molecule; n represents the number of X's in the complex, and an integer of 0 or more; and Q1 and Q2 each independently represent an aromatic heterocyclic group.
摘要翻译： 由下式（1）表示的金属络合物：其中R 1至R 6各自独立地表示氢原子或取代基; Y1和Y2各自独立地表示以下基团中的任一个：其中Rα表示氢原子或具有1至4个碳原子的烃基; P1和P2各自表示与Y1或Y2一起形成杂环所需的一组原子，在与Y1或Y2相邻的位置上的两个碳原子; P1和P2可以彼此连接以形成环; M表示过渡金属元素或典型的金属元素; m表示1或2; X表示抗衡离子或中性分子; n表示复合物中X的数目，0以上的整数; 并且Q1和Q2各自独立地表示芳族杂环基。
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公开(公告)号：US08519131B2
公开(公告)日：2013-08-27
申请号：US12530174
申请日：2008-03-10
CPC分类号： C07D213/30 , B01J31/1805 , B01J31/1815 , B01J31/183 , B01J31/223 , B01J2531/0252 , B01J2531/16 , B01J2531/56 , B01J2531/72 , B01J2531/842 , B01J2531/845 , C07D471/04
摘要： A modified metal complex obtained by subjecting a metal complex containing an organic compound having one nitrogen-containing aromatic heterocycle and four or more structures of a phenol, thiophenol, aniline or nitrogen-containing aromatic heterocyclic ring or an organic compound having two or more phenol rings and three or more nitrogen-containing aromatic heterocycles, in its molecule as a ligand, to a heating, radiation irradiation or discharge treatment until a mass reduction rate after the treatment becomes from 1 to 90 mass %, thereby the complex shows a carbon content after the treatment of 5 mass % or more.
摘要翻译： 一种改性金属络合物，其通过使含有含有一个含氮芳族杂环的有机化合物和四种或更多种酚，苯硫酚，苯胺或含氮芳族杂环的结构的金属络合物或具有两个或多个酚环的有机化合物 在其分子中含有3个以上的含氮芳香族杂环作为配体，进行加热，放射线照射或放电处理，直到处理后的质量降低率为1〜90质量％，由此，复合物显示出碳后的碳含量 治疗5％以上。
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公开(公告)号：US08329929B2
公开(公告)日：2012-12-11
申请号：US12530413
申请日：2008-03-10
CPC分类号： C07D213/30 , B01J31/1815 , B01J31/183 , B01J31/2243 , B01J2531/0252 , B01J2531/16 , B01J2531/72 , B01J2531/84 , C07D409/14 , C07D471/04 , C08F110/02 , C08F110/06
摘要： A metal complex represented by the following formula (1): wherein R1 to R6 each independently represent a hydrogen atom or a substituent; Y1 and Y2 each independently represent any one of the following groups: wherein Rα represents a hydrogen atom or a hydrocarbon group having 1 to 4 carbon atoms; P1 and P2 each represent a group of atoms necessary for forming a heterocyclic ring together with Y1 or Y2 and the two carbon atoms at a position adjacent to Y1 or Y2; P1 and P2 may be linked to each other to form a ring; M represents a transition metal element or typical metal element; m represents 1 or 2; X represents a counter ion or a neutral molecule; n represents the number of X's in the complex, and an integer of 0 or more; and Q1 and Q2 each independently represent an aromatic heterocyclic group.
摘要翻译： 由下式（1）表示的金属络合物：其中R 1至R 6各自独立地表示氢原子或取代基; Y1和Y2各自独立地表示以下基团中的任一个：其中Rα表示氢原子或具有1至4个碳原子的烃基; P1和P2各自表示与Y1或Y2一起形成杂环所需的一组原子，在与Y1或Y2相邻的位置上的两个碳原子; P1和P2可以彼此连接以形成环; M表示过渡金属元素或典型的金属元素; m表示1或2; X表示抗衡离子或中性分子; n表示复合物中X的数目，0以上的整数; 并且Q1和Q2各自独立地表示芳族杂环基。
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公开(公告)号：US20120021897A1
公开(公告)日：2012-01-26
申请号：US13202858
申请日：2010-02-19
IPC分类号： B01J31/22 , C07F15/06 , C07D487/22 , C07F1/08 , C07F3/06 , C07D471/22 , C07D498/22 , C07F15/04
CPC分类号： C07D471/22 , B01J31/2243 , B01J2231/70 , B01J2531/0216 , B01J2531/0241 , B01J2531/16 , B01J2531/26 , B01J2531/845 , B01J2531/847 , C07D487/22 , C07D498/22 , C07D513/22 , H01L51/0083 , H01L51/009 , H01L51/0091 , H01L51/0092 , H01M4/9008
摘要： A compound represented by the following formula (1): wherein, Y1, Y2, Y3 and Y4 represent a group represented by any of the above formulae; P1, P2, P3 and P4 are an atomic group required for forming an aromatic heterocyclic ring; P5 and P6 are an atomic group required for forming an aromatic ring; Z1 and Z2 represent ORα, —SRα or —NRα2, wherein Rα represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms; Q1 and Q2 represent a direct bond or a linking group; a P1-containing ring and a P2-containing ring are bonded to form Q1-containing fused structure; a P3-containing ring and a P4-containing ring are bonded to form Q2-containing fused structure; can be used as a ligand of a metal complex, and the metal complex is useful for a catalyst.
摘要翻译： 由下式（1）表示的化合物：其中，Y1，Y2，Y3和Y4表示由上述任何一个表示的基团; P1，P2，P3和P4是形成芳族杂环所需的原子团; P5和P6是形成芳环所需的原子团; Z1和Z2表示ORα，-SRα或-NRα2，其中Rα表示氢原子或具有1至4个碳原子的烷基; Q1和Q2表示直接键或连接基团; 键合含有P1的环和含有P2的环，形成含有Q1的稠合结构; 键合含有P3的环和含有P4的环，形成含有Q2的稠合结构; 可以用作金属络合物的配体，并且金属络合物可用于催化剂。
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