公开(公告)号：US06451392B1

公开(公告)日：2002-09-17

申请号：US09610292

申请日：2000-07-05

申请人： Tadashi Ootake ,  Kazufumi Ogawa ,  Takaiki Nomura ,  Takako Takebe

发明人： Tadashi Ootake ,  Kazufumi Ogawa ,  Takaiki Nomura ,  Takako Takebe

IPC分类号： C09K1956

CPC分类号： B82Y30/00 ,  C07F7/025 ,  G02F1/133719 ,  G02F1/133788 ,  Y10T428/1014

摘要： A novel chemical adsorbate compound capable of forming a monomolecular thin film is provided. The chemical adsorbate compound is transparent and stable in the visible light range, and has a photosensitive group which causes a photochemical reaction in the ultraviolet light range. Utilizing the chemical adsorbate compound, a liquid crystal alignment film is also provided. The liquid crystal alignment film has an excellent thermal stability and alignment control performance. Utilizing liquid crystal alignment film, a liquid crystal display device is further provided. The liquid crystal display device achieves wide viewing angles and clear display images at small driving voltages. These are achieved by, as one example, providing a chemical adsorbate compound including a chalcone derivative having a COO group at the 4′ position in the chalcone skeleton and an —SiX3 group, where X is a halogen, at the molecular end adjacent to the COO group. Another example of the chemical adsorbate compound is a compound in which a linear hydrocarbon group is ether-linked at the 4 position of the benzene ring in the chalcone skeleton and an —SiX3 group, where X is a halogen, is ether-linked to the hydrocarbon group.

摘要翻译： 提供能形成单分子薄膜的新型化学吸附物质化合物。 化学吸附物质在可见光范围内是透明和稳定的，并且具有在紫外光范围内引起光化学反应的光敏基团。 利用化学吸附物质，还提供液晶取向膜。 液晶取向膜具有优异的热稳定性和取向控制性能。 利用液晶取向膜，还提供了液晶显示装置。 液晶显示装置在较小的驱动电压下实现宽视角和清晰的显示图像。 这些通过作为一个实例来实现，其提供化学吸附物质化合物，其包括在查耳酮骨架中在4'位具有COO基团的查耳酮衍生物和X 1为卤素的-SiX 3基团， 首席运营组。 化学吸附物质化合物的另一个例子是在查耳酮骨架中的苯环的4位和直链烃基被醚连接的化合物和其中X是卤素的-SiX 3基团与 烃基。

公开(公告)号：US06524715B1

公开(公告)日：2003-02-25

申请号：US09786158

申请日：2001-03-01

申请人： Tadashi Ootake ,  Kazufumi Ogawa ,  Takaiki Nomura ,  Takako Takebe

发明人： Tadashi Ootake ,  Kazufumi Ogawa ,  Takaiki Nomura ,  Takako Takebe

IPC分类号： B32B904

CPC分类号： B82Y30/00 ,  C07F7/025 ,  C07F7/12 ,  Y10T428/3154 ,  Y10T428/31663

摘要： A thin film forming chemical absorption material including at least a functional group of the formula CF3—CF2—CH2—O—(benzene)—CH=CH—C(O)—(benzene)— and a —SiX group (X represents halogen) as an end group bonded by siloxane bond. The chemical absorption material can form a monomolecular thin-film having photosensitive groups that are transparent and stable in a visible light region and cause photochemical reaction in an ultraviolet region. A liquid crystal alignment film includes an aggregation of adsorption molecules chemically absorbed directly on a surface with electrodes or chemically adsorbed indirectly thereon through another material layer having a characteristic group the formula above and a —O—Si bond group at a molecular end group. The liquid crystal alignment film is uniformly and strongly anchored on the substrate, has excellent thermal alignment stability, alignment controllability, and a film thickness permitting formation with good productivity.

摘要翻译： 至少包含式CF 3 -CF 2 -CH 2 -O-（苯）-CH = CH-C（O） - （苯）官能团和-SiX基团（X代表卤素）的薄膜形成化学吸收材料 ）作为通过硅氧烷键键合的端基。 化学吸收材料可以形成具有在可见光区域是透明和稳定的光敏基团并在紫外区域引起光化学反应的单分子薄膜。 液晶取向膜包括通过具有上述特征基团的另一材料层和分子端基上的-O-Si键基直接化学吸附在具有电极的表面上或通过其间接化学吸附的吸附分子的聚集体。 液晶取向膜均匀且牢固地锚定在基板上，具有优异的热取向稳定性，取向可控性和允许形成的膜厚度，并且生产率高。

公开(公告)号：US6054190A

公开(公告)日：2000-04-25

申请号：US264590

申请日：1999-03-08

申请人： Kazufumi Ogawa ,  Takaiki Nomura ,  Tadashi Ootake

发明人： Kazufumi Ogawa ,  Takaiki Nomura ,  Tadashi Ootake

IPC分类号： G02F1/1337 ,  C08J7/04

CPC分类号： B82Y30/00 ,  B82Y40/00 ,  G02F1/133719 ,  G02F1/133788

摘要： A method for producing an alignment chemisorption monomolecular film having high efficiency of washing solution and being excellent in alignment property of molecules constituting the alignment monomolecular film. The method comprises the step of forming a monomolecular film by chemisorption on a hydrophilic surface of a base material by bringing the hydrophilic surface into contact with a silane-based surfactant having a carbon chain or a siloxane bond chain so as to cause a chemical reaction between them, thereby bonding one end of the surfactant molecules to the hydrophilic surface, orienting the base material in a predetermined orientation, and then vapor washing the base material in vapor of an organic solvent, and aligning molecules constituting the monomolecular film by the flow of condensation of the organic solvent formed on the surface of the base material during the vapor washing.

摘要翻译： 一种制造洗涤液效率高，排列单分子膜分子的取向性优异的取向化学吸附单分子膜的方法。 该方法包括通过使亲水表面与具有碳链或硅氧烷键合链的硅烷类表面活性剂接触而使基材的亲水性表面上化学吸附而形成单分子膜的步骤，从而引起化学反应 从而将表面活性剂分子的一端粘合到亲水性表面，使基材以规定的取向取向，然后在有机溶剂的蒸气中对基材进行蒸气洗涤，并且通过冷凝流动使构成单分子膜的分子 在蒸气洗涤期间在基材表面形成的有机溶剂。

公开(公告)号：US5324543A

公开(公告)日：1994-06-28

申请号：US20534

申请日：1993-02-22

申请人： Kazufumi Ogawa ,  Tadashi Ootake ,  Mamoru Soga

发明人： Kazufumi Ogawa ,  Tadashi Ootake ,  Mamoru Soga

IPC分类号： B05D1/20 ,  B05D1/18 ,  B32B7/02 ,  B32B9/00 ,  C08J7/04 ,  C09D4/00 ,  C09K3/00 ,  C09K3/18 ,  B05D5/08

CPC分类号： B82Y30/00 ,  B05D1/185 ,  B82Y40/00 ,  B82Y5/00 ,  C09D4/00 ,  Y10T428/261 ,  Y10T428/3154 ,  Y10T428/31663

摘要： The invention provides a method of forming a monomolecular film of fluorine-containing molecules on a substrate surface such that the film has a uniform thickness with minimal surface irregularities and is substantially pin hole free. The invention also provides for a substrate obtained by using the same method which has excellent water- and oil-repelling, anti-fogging, and anti-contaminating properties. The monomolecular film is formed on the substrate surface either directly or via a given protective film. The monomolecular film coating is characterized by a plurality of different chlorosilane-based surface active materials which are different in molecular length and have a fluorine group. The surface irregularities of the film are generally confined to the molecular level.

摘要翻译： 本发明提供了在基板表面上形成含氟分子的单分子膜的方法，使得该膜具有均匀的厚度，具有最小的表面不规则性并且基本上无针孔。 本发明还提供了通过使用具有优异的防水和防油，防雾和抗污染性能的相同方法获得的基材。 单分子膜直接或通过给定的保护膜形成在基板表面上。 单分子膜涂层的特征在于分子长度不同且具有氟基团的多种不同的氯硅烷系表面活性物质。 膜的表面不规则性通常限于分子水平。

公开(公告)号：US5225274A

公开(公告)日：1993-07-06

申请号：US804668

申请日：1991-12-10

申请人： Kazufumi Ogawa ,  Tadashi Ootake ,  Mamoru Soga

发明人： Kazufumi Ogawa ,  Tadashi Ootake ,  Mamoru Soga

IPC分类号： B05D1/20 ,  B05D1/18 ,  B32B7/02 ,  B32B9/00 ,  C08J7/04 ,  C09D4/00 ,  C09K3/00 ,  C09K3/18

CPC分类号： B82Y30/00 ,  B05D1/185 ,  B82Y40/00 ,  B82Y5/00 ,  C09D4/00 ,  Y10T428/261 ,  Y10T428/3154 ,  Y10T428/31663

摘要： The invention seeks to provide a method of forming a monomolecular film of fluorine-containing molecules on a substrate surface such that the film has a uniform thickness with minimal surface irregularities and is substantially pin hole free. The invention also provides for a substrate obtained by using the same method which has excellent water- and oil-repelling, anti-fogging, and anti-contaminating properties. The monomolecular film is formed on the substrate surface either directly or via a given protective film. The monomolecular film coating is characterized by a plurality of different chlorosilane-based surface active materials which are different in molecular length and have a fluorine group. The surface irregularities of the film are generally confined to the molecular level.

公开(公告)号：US07468206B1

公开(公告)日：2008-12-23

申请号：US08992049

申请日：1997-12-17

申请人： Tadashi Ootake ,  Yasuo Takebe ,  Norihisa Mino ,  Hiroaki Takezawa

发明人： Tadashi Ootake ,  Yasuo Takebe ,  Norihisa Mino ,  Hiroaki Takezawa

IPC分类号： G11B5/64 ,  B05D1/18

CPC分类号： B82Y30/00 ,  B05D1/185 ,  B82Y40/00 ,  Y10T428/26 ,  Y10T428/261 ,  Y10T428/265 ,  Y10T428/31504

摘要： The present invention provides an organic ultra-thin film firmly fixed to a substrate with the film thickness ranging from tens of nm to hundreds of nm. The organic ultra-thin film comprises polymers fixed on a substrate by M2—O—A— bond in which A represents an Si, Ge, Ti, Sn or Zr atom in the polymer, and M2 represents an atom in the substrate) or by a coordinate bond, the polymers are combined with each other by —A1—O—A1′— bond in which A1 and A1′ are Si, Ge, Ti, Sn, Zr or S or by a coordinate bond.

摘要翻译： 本发明提供一种牢固地固定在基板上的有机超薄膜，其膜厚度为数十nm至数百nm。 有机超薄膜包括通过M2-OA-键固定在基材上的聚合物，其中A表示聚合物中的Si，Ge，Ti，Sn或Zr原子，M2表示基材中的原子）或通过坐标 通过-A1-O-A1'-键将聚合物彼此组合，其中A1和A1'是Si，Ge，Ti，Sn，Zr或S或通过配位键。

公开(公告)号：US06985132B2

公开(公告)日：2006-01-10

申请号：US09995511

申请日：2001-11-27

申请人： Noboru Nomura ,  Tohru Nakagawa ,  Masahiro Nagasawa ,  Tadashi Ootake

发明人： Noboru Nomura ,  Tohru Nakagawa ,  Masahiro Nagasawa ,  Tadashi Ootake

IPC分类号： G09G3/34

CPC分类号： G09F9/372

摘要： A display device using a cylinder-shaped pixel having a large dipole moment and high response speed and a method for manufacturing the same. In the display device, an organic film is bonded and fixed to a part of or an entire surface of a base material having a volume of less than 1 cm3 via —A—O— bond, where A denotes Si, Ge, Sn, Ti or Zr, or via —A—N— bond, where A denotes Si, Ge, Sn, Ti or Zr, in the former, the side of O is bonded to the substrate and in the latter, the side of N is bonded to the substrate; the surface region of the base material is divided into two regions in accordance with the kind of organic films or the presence or absence of the organic film, and each of the two regions accounting for 40% or more and 60% or less of the surface area of the base material, a plurality of charged substances in different charged states or with opposite polarities in the two regions. The plurality of charged substances are dipped in liquid between a pair of substrates each having an electrode, and voltage is applied to the electrode, thereby enabling the charged substances to be rotated.

摘要翻译： 使用具有大偶极矩和高响应速度的圆柱形像素的显示装置及其制造方法。 在显示装置中，有机膜通过-AO键键合并固定在体积小于1cm 3的基材的一部分或整个表面上，其中A表示Si ，Ge，Sn，Ti或Zr，或通过-AN-键，其中A表示Si，Ge，Sn，Ti或Zr，在前者中，O的一面与基底结合，而在后者中， N结合到基底上; 基材的表面区域根据有机膜的种类或有机膜的有无分为两个区域，两个区域中的每一个占表面积的40％以上且60％以下 基底材料的面积，在两个区域中具有不同充电状态或具有相反极性的多个带电物质。 将多个带电物质浸渍在各自具有电极的一对基板之间的液体中，并且向电极施加电压，从而使带电物质能够旋转。

公开(公告)号：US06203919B1

公开(公告)日：2001-03-20

申请号：US08980749

申请日：1997-12-01

申请人： Yasuo Takebe ,  Tadashi Ootake ,  Norihisa Mino ,  Hiroaki Takezawa

发明人： Yasuo Takebe ,  Tadashi Ootake ,  Norihisa Mino ,  Hiroaki Takezawa

IPC分类号： B32B1508

CPC分类号： H01B3/30 ,  Y10T428/31529 ,  Y10T428/31533 ,  Y10T428/31536 ,  Y10T428/31605 ,  Y10T428/31681 ,  Y10T428/31692 ,  Y10T428/31786 ,  Y10T428/31855 ,  Y10T428/31909

摘要： An electrically insulating film capable of maintaining a preferable insulating property even with a film thickness of only some &mgr;and a method for preparing the same are disclosed. The insulating film comprises a first layer formed on a surface of a conductor substrate of a transition metal and comprised of molecules fixed on the surface of the conductor substrate through chemical bonds such as transition metal-sulfur bonds or chelate bonds, and a second layer formed on the first layer and comprised of a resin bonded to the molecules of the first layer through covalent bonds.

摘要翻译： 公开了一种甚至即使膜厚仅有一些保持优选绝缘性能的电绝缘膜及其制备方法。 绝缘膜包括形成在过渡金属的导体基板的表面上的第一层，并且由通过诸如过渡金属 - 硫键或螯合键的化学键固定在导体基板的表面上的分子组成，第二层形成 在第一层上并且由通过共价键与第一层的分子键合的树脂组成。