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公开(公告)号：US5476752A
公开(公告)日：1995-12-19
申请号：US415574
申请日：1995-04-03
CPC分类号： G03F7/032 , Y10S525/922
摘要： An active energy ray-curing resin composition comprises:(i) a linear polymer having a glass transition temperature of 50.degree. C. or higher and a weight average molecular weight of about 3.0.times.10.sup.4 or higher;(ii) a monomer having an ethylenically unsaturated bond;(iii) an epoxy resin comprising at least one compound having one or more epoxy groups in the molecule; and(iv) a polymerization initiator capable of generating a Lewis acid by irradiation with an active energy ray.
摘要翻译： 活性能量射线固化树脂组合物包括：（i）玻璃化转变温度为50℃或更高，重均分子量为约3.0×10 4或更高的线性聚合物; （ii）具有烯属不饱和键的单体; （iii）包含至少一种在分子中具有一个或多个环氧基的化合物的环氧树脂; 和（iv）能够通过用活性能量射线照射产生路易斯酸的聚合引发剂。
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公开(公告)号：US5696177A
公开(公告)日：1997-12-09
申请号：US240502
申请日：1994-05-10
IPC分类号： C08F2/46 , C08F2/50 , C08F290/06 , C08F299/02 , C08G59/16 , C08L63/10 , G03F7/027 , G03F7/033 , G03F7/038
CPC分类号： G03F7/0385 , C08F290/064 , C08F299/028 , C08G59/1461 , C08L63/10 , G03F7/027 , G03F7/033
摘要： An active energy ray-curable resin composition comprises: (i) a linear polymer having a glass transition temperature at least equal to 50.degree. C. and a weight-average molecular weight of at least about 3.0.times.10.sup.4 ; and (ii) a resin obtained by esterifying, with an unsaturated carboxylic acid, a part of epoxy groups present in an epoxy resin comprising at least one compound having at least two epoxy groups in a molecule.
摘要翻译： 活性能量射线固化树脂组合物包含：（i）玻璃化转变温度至少等于50℃，重均分子量至少约为3.0×10 4的直链聚合物; 和（ii）通过不饱和羧酸与存在于包含分子中至少具有两个环氧基的化合物的环氧树脂中的一部分环氧基酯化而获得的树脂。
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公开(公告)号：US5043363A
公开(公告)日：1991-08-27
申请号：US581084
申请日：1990-09-12
IPC分类号： G02F1/1337 , C08F2/48 , C08F2/50 , C08F265/10 , G02F1/133 , G03F7/004 , G03F7/027 , G03F7/033 , G03F7/038
CPC分类号： G03F7/033 , C08F265/10 , Y10S430/107 , Y10S430/12
摘要： An active energy ray-curing resin composition comprises (i) a heat-crosslinkable linear copolymer comprising 5 to 30 mol % of a monomer represented by the general formula I shown below and 5 to 50 mol % of a monomer represented by the general formula II shown below as the copolymer constituents: ##STR1## (wherein R.sup.1 is hydrogen or alkyl or hydroxyalkyl group having 1 to 3 carbon atoms; R.sup.2 is hydrogen or alkyl or acyl group having 1 to 4 carbon atoms which may have a hydroxyl group; R.sup.3 is hydrogen or alkyl group having 1 to 3 carbon atoms; R.sup.4 is a divalent hydrocarbon group which may have internally an ether bond and may also be substituted with halogen atoms; and R.sup.5 is alkyl having 3 to 12 carbon atoms or phenylalkyl group or phenyl group), and (ii) a monomer having an ethylenically unsaturated bond.
摘要翻译： 活性能量射线固化树脂组合物包含（i）包含5至30mol％由下述通式I表示的单体和5至50mol％由通式II表示的单体的热交联线性共聚物 （I）（II）（其中R 1是氢或具有1至3个碳原子的烷基或羟基烷基; R 2是氢或具有1至4个碳原子的烷基或酰基） 其可以具有羟基; R 3是氢或具有1至3个碳原子的烷基; R 4是可以具有内部醚键并且也可以被卤素原子取代的二价烃基;并且R 5是具有3至12个碳原子的烷基 碳原子或苯基烷基或苯基），和（ii）具有烯属不饱和键的单体。
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公开(公告)号：US5585221A
公开(公告)日：1996-12-17
申请号：US205146
申请日：1994-03-02
IPC分类号： C08F285/00 , C08F299/02 , G03F7/032 , G03C1/725
CPC分类号： C08F299/026 , C08F285/00 , G03F7/032
摘要： An active energy ray-curing resin composition comprises a graft copolymerized polymer and at least one of a monomer having an ethylenically unsaturated bond and a partially esterified epoxy resin.
摘要翻译： 活性能量射线固化树脂组合物包含接枝共聚聚合物和具有烯键式不饱和键的单体和部分酯化的环氧树脂中的至少一种。
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公开(公告)号：US5543266A
公开(公告)日：1996-08-06
申请号：US415168
申请日：1995-03-13
IPC分类号： C08F283/10 , C08F285/00 , C08L51/00 , C08L63/00 , G03F7/038 , G03C1/725
CPC分类号： G03F7/0388 , C08F283/10 , C08F285/00 , C08L51/003 , C08L63/00
摘要： An active energy ray-curing resin composition comprises (i) a graft copolymerized polymer, (iii) an epoxy resin comprising at least one compound having one or more epoxy groups in the molecule and (iv) a polymerization initiator capable of generating a Lewis acid by irradiation of an active energy ray.
摘要翻译： 活性能量射线固化树脂组合物包含（i）接枝共聚聚合物，（iii）包含至少一种在分子中具有一个或多个环氧基的化合物的环氧树脂和（iv）能够产生路易斯酸的聚合引发剂 通过照射活性能量射线。
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6.发明授权Liquid jet recording head having a layer of a resin composition curable with an active energy ray 失效具有可用活性能量射线固化的树脂组合物层的液体喷射记录头
公开(公告)号：US4688056A
公开(公告)日：1987-08-18
申请号：US881821
申请日：1986-07-03
IPC分类号： C08F265/00 , C09D4/06 , G03F7/032 , G03F7/033 , G01D15/18
CPC分类号： G03F7/033 , C08F265/00 , C09D4/06 , G03F7/032
摘要： A liquid jet recording head, having a liquid passage communicated to the discharging outlet of the liquid provided on a substrate surface, said passage being formed by subjecting a layer of a resin composition curable with an active energy ray to a predetermined pattern exposure with the use of said active energy ray to thereby form a cured region of said resin composition and removing the uncured region from said layer, said resin composition comprising (i) a graft copolymerized polymer, (iii) an epoxy resin comprising at least one compound having one or more epoxy groups in the molecule and (iv) a polymerization initiator capable of generating a Lewis acid by irradiation of an active energy ray.
摘要翻译： 一种液体喷射记录头，具有连通到设置在基板表面上的液体的排出口的液体通道，所述通道是通过使用可用活性能量射线固化的树脂组合物层进行预定图案曝光而形成的， 的所述活性能量射线，从而形成所述树脂组合物的固化区域并从所述层去除未固化区域，所述树脂组合物包含（i）接枝共聚聚合物，（iii）环氧树脂，其包含至少一种具有一个或多个 分子中有更多的环氧基，（iv）能通过活性能量射线的照射产生路易斯酸的聚合引发剂。
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7.发明授权Liquid jet recording head having a layer of a resin composition curable with an active energy ray 失效具有可用活性能量射线固化的树脂组合物层的液体喷射记录头
公开(公告)号：US4688053A
公开(公告)日：1987-08-18
申请号：US883155
申请日：1986-07-08
CPC分类号： C09D4/06
摘要： A liquid jet recording head having a liquid passage communicated to a liquid discharging outlet provided on a substrate surface is obtained, said passage being formed by subjecting a layer of a resin composition curable with an active energy ray to a predetermined pattern exposure with the use of said active energy ray to thereby form a cured region of said resin composition and removing the uncured region from said layer, said resin composition comprising:(i) a linear polymer having a glass transition temperature of 50.degree. C. or higher and a weight average molecular weight of about 3.0.times.10.sup.4 or higher;(ii) a monomer having an ethylenically unsaturated bond;(iii) an epoxy resin comprising at least one compound having one or more epoxy groups in the molecule; and(iv) a polymerization initiator capable of generating a Lewis acid by irradiation with an active energy ray.
摘要翻译： 获得具有与设置在基板表面上的液体排出口连通的液体通道的液体喷射记录头，所述通道是通过使用可活化能量射线固化的树脂组合物层进行预定图案曝光而形成的， 所述活性能量射线从而形成所述树脂组合物的固化区域并从所述层去除未固化区域，所述树脂组合物包含：（i）玻璃化转变温度为50℃或更高的直链聚合物和重均分子量 分子量约3.0×10 4以上; （ii）具有烯属不饱和键的单体; （iii）包含至少一种在分子中具有一个或多个环氧基的化合物的环氧树脂; 和（iv）能够通过用活性能量射线照射产生路易斯酸的聚合引发剂。
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8.发明授权Liquid jet recording head having a layer of a resin composition curable with an active energy ray 失效具有可用活性能量射线固化的树脂组合物层的液体喷射记录头
公开(公告)号：US4688055A
公开(公告)日：1987-08-18
申请号：US881620
申请日：1986-07-03
CPC分类号： C09D4/06
摘要： A liquid jet recording head has a liquid passage communicated to the discharging outlet of the liquid which is formed with a resin composition cured with an active energy ray. The resin composition to be cured comprises (i) a heat-crosslinkable linear copolymer containing 5-30 mol % of a monomer of formula I and 5-50 mol % of a monomer of formula II ##STR1## and (ii) a monomer having an ethylenically unsaturated bond.
摘要翻译： 液体喷射记录头具有连通到液体的排出口的液体通道，液体通过用活性能量射线固化的树脂组合物形成。 待固化的树脂组合物包含（i）含有5-30mol％式I单体和5-50mol％式II单体的热交联线性共聚物（I）（图） II）和（ii）具有烯属不饱和键的单体。
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公开(公告)号：US4688054A
公开(公告)日：1987-08-18
申请号：US880210
申请日：1986-06-30
IPC分类号： C08F283/10 , C08F285/00 , C09D4/06 , G03F7/032 , G03F7/033 , G01D15/18
CPC分类号： G03F7/033 , C08F283/10 , C08F285/00 , C09D4/06 , G03F7/032
摘要： A liquid jet recording head has a liquid passage communicated to the discharging outlet of the liquid provided on a substrate surface, said passage being formed by subjecting a layer of a resin composition curable with an active energy ray to a predetermined pattern exposure with the use of said active energy ray to thereby form a cured region of said resin composition and removing the uncured region from said layer, said resin composition comprising the component (i) shown below and at least one of the components (ii) and (iii) shown below:(i) a graft copolymerized polymer comprising a trunk chain composed mainly of structural units derived from at least one monomer selected from the group consisting of alkyl methacrylate, acrylonitrile and styrene, having graft chains composed mainly of structural units derived from at least one monomer selected from the group consisting of (A) hydroxyl containing acrylic monomers, (B) amino or alkylamino containing acrylic monomers, (C) carboxylic containing acrylic or vinyl monomers, (D) N-vinylpyrrolidone or its derivatives, (E) vinylpyridine or its derivatives and (F) acrylamide derivatives represented by the following general formula I: ##STR1## (wherein R.sup.1 represents hydrogen or an alkyl or hydroxyalkyl group having 1 to 3 carbon atoms, and R.sup.2 represents hydrogen or an alkyl or acyl group having 1 to 4 carbon atoms which may have one or more hydroxy groups) added to said trunk chain;(ii) an epoxy resin comprising at least one compound having two or more epoxy groups in the molecule, the epoxy groups existing in said epoxy resin being partially esterified with an unsaturated carboxylic acid; and(iii) a monomer having an ethylenically unsaturated bond.
摘要翻译： 液体喷射记录头具有连通到设置在基板表面上的液体的排出口的液体通道，所述通道通过使用可用活性能量射线固化的树脂组合物层进行预定图案曝光而形成， 所述活性能量射线从而形成所述树脂组合物的固化区域并从所述层去除未固化区域，所述树脂组合物包含下述组分（i）和至少一种如下所示的组分（ii）和（iii） （i）接枝共聚聚合物，其包括主要由衍生自至少一种选自甲基丙烯酸烷基酯，丙烯腈和苯乙烯的单体的结构单元组成的主链，其具有主要由衍生自至少一种单体的结构单元组成的接枝链 选自（A）含羟基的丙烯酸单体，（B）氨基或含烷基氨基的丙烯酸单体，（C）羧酸 含有丙烯酸或乙烯基单体，（D）N-乙烯基吡咯烷酮或其衍生物，（E）乙烯基吡啶或其衍生物和（F）丙烯酰胺衍生物，由以下通式I表示：其中R1表示氢或烷基或羟烷基 具有1至3个碳原子的基团，并且R 2表示氢或可具有一个或多个羟基的具有1至4个碳原子的烷基或酰基）; （ii）包含至少一种在分子中具有两个或更多个环氧基的化合物的环氧树脂，所述环氧树脂中存在的环氧基被不饱和羧酸部分酯化; 和（iii）具有烯属不饱和键的单体。
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10.发明授权Liquid jet recording head having a layer of a resin composition curable with an active energy ray 失效具有可用活性能量射线固化的树脂组合物层的液体喷射记录头
公开(公告)号：US4688052A
公开(公告)日：1987-08-18
申请号：US883349
申请日：1986-07-08
IPC分类号： C08L63/00 , C09D4/06 , C09D125/04 , C09D133/06 , C09D133/20 , G01D15/18
CPC分类号： C09D133/06 , C09D125/04 , C09D133/20 , C09D4/06 , C08L63/00
摘要： A light jet recording head has a liquid passage communicated to the discharging outlet of the liquid provided on a substrate surface, said passage being formed by subjecting a layer of a resin composition curable with an active energy ray to a predetermined pattern exposure with the use of said active energy ray to thereby form a cured region of said resin composition and removing the uncured region from said layer, said resin composition comprising:(i) a linear polymer having a glass transition temperature of 50.degree. C. or higher and a weight-average molecular weight of about 3.0.times.10.sup.4 or more; and(ii) an epoxy resin comprising at least one compound having two or more epoxy groups in the molecule, the epoxy groups existing in said epoxy resin being partially esterified with an unsaturated carboxylic acid.
摘要翻译： 一种喷墨记录头具有连通到设置在基板表面上的液体的排出口的液体通道，所述通道是通过使用可用活性能量射线固化的树脂组合物层进行预定图案曝光而形成的， 所述活性能量射线从而形成所述树脂组合物的固化区域并从所述层去除未固化区域，所述树脂组合物包含：（i）玻璃化转变温度为50℃或更高的直链聚合物， 平均分子量约3.0×10 4以上; 和（ii）包含至少一种在分子中具有两个或更多个环氧基的化合物的环氧树脂，存在于所述环氧树脂中的环氧基被不饱和羧酸部分酯化。
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