摘要:
A production method of an electrode for a lithium-ion secondary battery includes: (A) a step of providing a current collector 11 having a plurality of bumps 12 on a surface thereof; (B) a step of allowing an evaporated source material to strike from a direction E which is tilted with respect to the normal of the surface of the current collector 11 to form a corresponding plurality of pillar-like members 14 on the plurality of bumps 12; and (C) a step of oxidizing the plurality of pillar-like members 14 to form a plurality of active material members 18 containing an oxide of the source material.
摘要:
In a charge/discharge method for a positive-electrode active material in a lithium secondary battery, the lithium secondary battery includes a positive electrode containing a positive-electrode active material capable of occluding and releasing lithium ions, a negative electrode containing a negative-electrode active material capable of occluding and releasing lithium ions, a separator located between the positive electrode and the negative electrode, and an electrolyte having a lithium ion conductivity; and the positive-electrode active material contains a nickel-type lithium-containing complex oxide. The positive electrode, which has been charged, is discharged until having a first potential VDp1 which is no less than 2.7 V and no more than 3.4 V on a lithium metal basis, and then the discharge is finished. Owing to this, the charge/discharge cycle life can be improved while the capacity of the lithium secondary battery is secured.
摘要:
A battery pack includes at least a lithium ion secondary battery, a voltage sensor, and a control unit. The control unit controls discharge of the battery by a relatively high end-of-discharge voltage when the use frequency of the battery is relatively low during discharge of the battery. On the other hand, the control unit controls discharge of the battery by a relatively low end-of-discharge voltage when the use frequency of the battery is relatively high. Consequently, it is possible to prevent the utilizable capacity from decreasing more than a practical decrease in the capacity due to increase in the use frequency.
摘要:
A lithium secondary battery according to the present invention includes: a positive electrode having a positive-electrode active material capable of occluding and releasing lithium ions; a negative electrode having a negative-electrode active material capable of occluding and releasing lithium ions; a separator interposed between the positive electrode and the negative electrode; and an electrolyte having lithium-ion conductivity. The positive-electrode active material contains a nickel-type lithium-containing complex oxide. The negative-electrode active material contains a graphite-type material having a reversible capacity of 350 mAh/g or more and an irreversible capacity of 30 mAh/g or less. A ratio Qc/Qa between an irreversible capacity Qc per unit area in a portion of the positive electrode that opposes the negative electrode and an irreversible capacity Qa per unit area in a portion of the negative electrode that opposes the positive electrode is equal to or greater than 0.50 but less than 1. As a result, the charge-discharge cycle characteristics can be improved while ensuring a high capacity.
摘要:
A battery pack 1 of the present invention includes: a secondary battery 2; a molded body 11 configured to store therein the secondary battery; a temperature increase suppressing layer 13 provided between the secondary battery and an inner surface of the molded body to suppress a temperature increase of an outer surface of the molded body; and a block layer 12 provided between the secondary battery and the temperature increase suppressing layer to block leakage from the secondary battery. With this, if a malfunction, such as a case where contents, such as a molten material, flows out from the secondary battery, occurs, the contents are prevented from flowing out to the outside of the battery pack, and the temperature increase of the surface of the battery pack is suppressed.
摘要:
A portable electronic device of the present invention includes a package, an electronic device body, a battery housing portion including a battery fitting portion for fitting a secondary battery therein, a foaming agent-containing layer provided on a surface of the battery housing portion, and a secondary battery to be fitted in the battery fitting portion. The foaming agent-containing layer is normally thin and, in the event of the battery generating heat, the layer turns into a thicker foamed layer which exhibits superior thermal insulation properties. Thus, it is possible to provide a portable electronic device having the degree of freedom in design for size and thickness reduction achieved at a high level, while offering high-level safety and reliability.
摘要:
A negative electrode for a non-aqueous electrolyte secondary battery including: a current collector; and an active material layer including at least two alloy-based active materials selected from the group consisting of silicon, tin, a silicon oxide, and a tin oxide. The active material layer includes a first portion supported on a surface of the current collector, a second portion supported on a surface of the first portion, and a third portion supported on a surface of the second portion. The first portion includes the silicon oxide or the tin oxide, and the oxygen content in the silicon oxide or the tin oxide in the first portion decreases continuously or stepwise as approaching the second portion. The second portion includes silicon or tin. The third portion includes the silicon oxide or the tin oxide, and the oxygen content in the silicon oxide or the tin oxide in the third portion increases continuously or stepwise with distance from the second portion.
摘要:
A lithium secondary battery according to the present invention includes: a positive electrode having a positive-electrode active material capable of occluding and releasing lithium ions; a negative electrode having a negative-electrode active material capable of occluding and releasing lithium ions; a separator interposed between the positive electrode and the negative electrode; and an electrolyte having lithium-ion conductivity. The positive-electrode active material contains a nickel-type lithium-containing complex oxide. The negative-electrode active material contains a graphite-type material having a reversible capacity of 350 mAh/g or more and an irreversible capacity of 30 mAh/g or less. A ratio Qc/Qa between an irreversible capacity Qc per unit area in a portion of the positive electrode that opposes the negative electrode and an irreversible capacity Qa per unit area in a portion of the negative electrode that opposes the positive electrode is equal to or greater than 0.50 but less than 1.13. As a result, the charge-discharge cycle characteristics can be improved while ensuring a high capacity.
摘要:
Provided is a highly safe portable electronic device having a secondary battery as a power source, and including a housing, an electronic device body housed in the housing, and a battery housing portion housed in the housing, in which a surface is inhibited from being locally heated to high temperature. In the portable electronic device, the battery housing portion is a molding with a battery fitting portion for fitting the secondary battery therein, and the battery fitting portion has provided on its surface a heat-insulating layer having a thickness of from 500 to 3000 μm and a thermal conductivity of 0.2 W/m·K or lower.
摘要:
Provided is a highly safe portable electronic device having a secondary battery as a power source, and including a package, an electronic device body housed in the package, and a battery housing portion housed in the package, in which even if the content melts due to an extremely significant impact applied thereto, discharge of a melt is inhibited. In the portable electronic device, the battery housing portion is a molding with a battery fitting portion for fitting the secondary battery therein, and the battery fitting portion has a covering layer, which includes a temperature suppression layer and a block layer, provided on its surface.