公开(公告)号：US4624697A

公开(公告)日：1986-11-25

申请号：US597451

申请日：1984-04-06

申请人： Katsumichi Aoki ,  Takafumi Shida ,  Hideo Arabori ,  Satoru Kumazawa ,  Susumu Shimizu ,  Takeo Watanabe ,  Yohichi Kanda ,  Keigo Satake ,  Shiro Yamazaki ,  Hiroyasu Shinkawa ,  Tsuneaki Chida

发明人： Katsumichi Aoki ,  Takafumi Shida ,  Hideo Arabori ,  Satoru Kumazawa ,  Susumu Shimizu ,  Takeo Watanabe ,  Yohichi Kanda ,  Keigo Satake ,  Shiro Yamazaki ,  Hiroyasu Shinkawa ,  Tsuneaki Chida

IPC分类号： A01N43/78 ,  A01N43/82 ,  C07D233/00 ,  C07D271/00 ,  C07D277/00 ,  C07D417/04

CPC分类号： C07D417/04 ,  A01N43/78 ,  A01N43/82

摘要： Disclosed herein are a derivative of tetrahydrobenzothiazole represented by the formula (I): ##STR1## wherein R represents a methyl group, ethyl group or propyl group; R.sup.1 represents a hydrogen atom, a hydroxyl group methoxy group, acetoxy group, propionyloxy group, butylyloxy group, chloroacetoxy group, methoxyacetoxy group, C.sub.1 to C.sub.4 -alkylamino group or di(C.sub.1 to C.sub.4)-alkylamino group, or represents O.dbd.together with R.sup.2 ; R.sup.2 represents a hydrogen atom or represents O.dbd.together with R.sup.1 ; and X represents a methylene group, hydroxymethylene group, carbonyl group or --O--, and a herbicidal composition containing the same as an active ingredient.

摘要翻译： 本文公开了由式（I）表示的四氢苯并噻唑的衍生物：其中R表示甲基，乙基或丙基; R1表示氢原子，羟基甲氧基，乙酰氧基，丙酰氧基，丁酰氧基，氯乙酰氧基，甲氧基乙酰氧基，C1〜C4烷基氨基或二（C1〜C4） - 烷基氨基，或表示O = R2; R2代表氢原子或代表O =与R1一起; X表示亚甲基，羟基亚甲基，羰基或-O-，以及含有该活性成分的除草组合物。

公开(公告)号：US4549902A

公开(公告)日：1985-10-29

申请号：US597269

申请日：1984-04-06

申请人： Katsumichi Aoki ,  Takafumi Shida ,  Hideo Arabori ,  Satoru Kumazawa ,  Susumu Shimizu ,  Takeo Watanabe ,  Yohichi Kanda ,  Keigo Satake ,  Shiro Yamazaki ,  Hiroyasu Shinkawa ,  Tsuneaki Chida

发明人： Katsumichi Aoki ,  Takafumi Shida ,  Hideo Arabori ,  Satoru Kumazawa ,  Susumu Shimizu ,  Takeo Watanabe ,  Yohichi Kanda ,  Keigo Satake ,  Shiro Yamazaki ,  Hiroyasu Shinkawa ,  Tsuneaki Chida

IPC分类号： A01N47/36 ,  C07D277/82

CPC分类号： A01N47/36 ,  C07D277/82

摘要： Disclosed herein are a salt of a derivative of N-(tetrahydrobenzothiazolylcarbamoyl)oxamic acid, represented by the formula: ##STR1## wherein R.sup.1 represents a straight-chain alkyl group having one to six carbon atoms, branched-chain alkyl group having up to and including six carbon atoms, cyclic alkyl group having up to and including six carbon atoms or a phenyl group; R.sup.2 represents a hydrogen atom or a methyl group; M represents an alkali metal atom or an alkaline earth metal atom; n is 1 when M is an alkali metal atom and n is 1/2 when M is an alkaline earth metal atom and M' is a hydrogen atom or the same as M, and a herbicidal composition containing the same as an active ingredient.

摘要翻译： 本文公开了由下式表示的N-（四氢苯并噻唑基氨基甲酰基）氧杂恶唑酸的衍生物的盐：其中R 1表示具有1至6个碳原子的直链烷基，支链烷基具有 直到并包括6个碳原子，具有至多且包括6个碳原子的环状烷基或苯基; R2表示氢原子或甲基; M表示碱金属原子或碱土金属原子; 当M为碱金属原子时，n为1，当M为碱土金属原子且M为氢原子或与M相同时，n为1/2，和含有该活性成分的除草组合物。

公开(公告)号：US4551168A

公开(公告)日：1985-11-05

申请号：US596928

申请日：1984-04-05

申请人： Katsumichi Aoki ,  Takafumi Shida ,  Satoru Kumazawa ,  Susumu Shimizu ,  Yohichi Kanda ,  Keigo Satake ,  Shiro Yamazaki ,  Hiroyasu Shinkawa ,  Tsuneaki Chida ,  Hideo Arabori ,  Takeo Watanabe

发明人： Katsumichi Aoki ,  Takafumi Shida ,  Satoru Kumazawa ,  Susumu Shimizu ,  Yohichi Kanda ,  Keigo Satake ,  Shiro Yamazaki ,  Hiroyasu Shinkawa ,  Tsuneaki Chida ,  Hideo Arabori ,  Takeo Watanabe

IPC分类号： A01N43/78 ,  C07D417/04 ,  A01N43/64

CPC分类号： C07D417/04 ,  A01N43/78

摘要： Disclosed herein are a derivative of tetrahydrobenzothiazole represented by the formula (I): ##STR1## wherein R.sup.1 and R.sup.2 represent respectively a straight chain alkyl group having 1 to 6 carbon atoms or a branched chain alkyl group having 1 to 6 carbon atoms, and a herbicidal composition containing the same as an active ingredient.

摘要翻译： 本文公开了由式（I）表示的四氢苯并噻唑的衍生物：其中R 1和R 2分别代表具有1至6个碳原子的直链烷基或具有1至6个碳原子的支链烷基 ，以及含有该活性成分的除草组合物。

公开(公告)号：US4919707A

公开(公告)日：1990-04-24

申请号：US42321

申请日：1987-04-24

申请人： Takafumi Shida ,  Hideo Arabori ,  Takeo Watanabe ,  Yohichi Kanda ,  Shiro Yamazaki ,  Hiroyasu Shinkawa

发明人： Takafumi Shida ,  Hideo Arabori ,  Takeo Watanabe ,  Yohichi Kanda ,  Shiro Yamazaki ,  Hiroyasu Shinkawa

IPC分类号： A01N43/653 ,  C07D249/10

CPC分类号： C07D249/10 ,  A01N43/653

摘要： Disclosed herein are a derivative of 1,5-diphenyl-1H-1,2,4-triazole-3-carboxamide represented by the formula (I): ##STR1## wherein R.sup.1 represents a straight-chain alkyl group of 2 to 10 carbon atoms; a branched-chain alkyl group or cycloalkyl group of 3 to 10 carbon atoms; a (cycloalkyl)alkyl group of 4 to 10 carbon atoms; a non-substituted- or halogen-substituted phenyl group; an aralkyl group of 7 to 9 carbon atoms; an alkenyl group of 3 to 6 carbon atoms or an alkyl group of 2 to 10 carbon atoms, which has been substituted by 1 to 19 fluorine atoms, and R.sup.2 represents a fluorine atom, a chlorine atom, a methyl group or a methoxy group and a herbicidal composition containing the derivative represented by the formula (I) as an active ingredient.

公开(公告)号：US4561877A

公开(公告)日：1985-12-31

申请号：US596927

申请日：1984-04-05

申请人： Katsumichi Aoki ,  Takafumi Shida ,  Hideo Arabori ,  Satoru Kumazawa ,  Susumu Shimizu ,  Takeo Watanabe ,  Yohichi Kanda ,  Keigo Satake ,  Shiro Yamazaki ,  Hiroyasu Shinkawa ,  Tsuneaki Chida

发明人： Katsumichi Aoki ,  Takafumi Shida ,  Hideo Arabori ,  Satoru Kumazawa ,  Susumu Shimizu ,  Takeo Watanabe ,  Yohichi Kanda ,  Keigo Satake ,  Shiro Yamazaki ,  Hiroyasu Shinkawa ,  Tsuneaki Chida

IPC分类号： A01N43/78 ,  A01N43/88 ,  C07D417/04 ,  A01N43/54 ,  A01N43/66

CPC分类号： C07D417/04 ,  A01N43/78 ,  A01N43/88

摘要： Disclosed herein are a derivative of tetrahydrobenzothiazole represented by the formula (I): ##STR1## wherein R represents a hydrogen atom, a hydroxyl group or a lower acyloxy group such as acetoxy group and propionyloxy group and X represents a methylene group, C.sub.1 to C.sub.4 -alkylamino group, benzylamino group or --O--, and a herbicidal composition containing the same as an active ingredient.

摘要翻译： 本文公开的是由式（I）表示的四氢苯并噻唑的衍生物：其中R表示氢原子，羟基或低级酰氧基如乙酰氧基和丙酰氧基，X表示亚甲基， C1〜C4烷基氨基，苄基氨基或-O-，以及含有该活性成分的除草组合物。

公开(公告)号：US4973353A

公开(公告)日：1990-11-27

申请号：US162699

申请日：1988-03-01

申请人： Takafumi Shida ,  Hideo Arabori ,  Takeo Watanabe ,  Yoshikazu Kubota ,  Isao Ichinose ,  Yoichi Kanda ,  Shiro Yamazaki ,  Hiroyasu Shinkawa

发明人： Takafumi Shida ,  Hideo Arabori ,  Takeo Watanabe ,  Yoshikazu Kubota ,  Isao Ichinose ,  Yoichi Kanda ,  Shiro Yamazaki ,  Hiroyasu Shinkawa

IPC分类号： A01N43/653 ,  C07C205/34 ,  C07C205/35 ,  C07C217/76 ,  C07D249/10

CPC分类号： C07C205/34 ,  A01N43/653 ,  C07C205/35 ,  C07C217/76 ,  C07D249/10

摘要： Disclosed herein is a derivative of 1,5-diphenyl-1H-1,2,4-triazole-3-carboxamide represented by the formula (I): ##STR1## wherein R is a straight-chain alkyl group having 1 to 10 carbon atoms which is non-substituted or substituted with 1 to 19 fluorine atoms, a branched alkyl group having 3 to 10 carbon atoms which is non-substituted or substituted with 1 to 19 fluorine atoms, a cyclic alkyl group having 3 to 10 carbon atoms, an alkyl group having 1 to 3 carbon atoms which is substituted with an alicyclic structure having 3 to 7 carbon atoms, a phenyl group or an aralkyl group having 7 to 9 carbon atoms; X.sup.1 is a halogen or an alkyl group having 1 to 3 carbon atoms; X.sup.2 is a hydrogen, a halogen or an alkyl group having 1 to 3 carbon atoms; Y.sup.1 is a hydrogen or a fluorine; and Y.sup.2 is a hydrogen or a fluorine, and the herbicidal compositions containing said derivatives as active ingredient therefor.The derivative of 1,5-diphenyl-1H-1,2,4-triazole-3-carboxamide represented by the formula (I) of the present invention is the compound having high herbicidal activity and also showing excellent selectivity for killing weeds alone without doing any serious harm to the crops such as rice, wheat and corn.

公开(公告)号：US5094684A

公开(公告)日：1992-03-10

申请号：US554986

申请日：1990-07-17

申请人： Takafumi Shida ,  Hideo Arabori ,  Takeo Watanabe ,  Shiro Yamazaki ,  Hiroyasu Shinkawa

发明人： Takafumi Shida ,  Hideo Arabori ,  Takeo Watanabe ,  Shiro Yamazaki ,  Hiroyasu Shinkawa

IPC分类号： A01N43/653 ,  C07C65/21 ,  C07C67/14 ,  C07C69/734 ,  C07C235/42 ,  C07D249/10 ,  C07D263/42 ,  C07D263/48

CPC分类号： C07C65/21 ,  A01N43/653 ,  C07D249/10 ,  C07D263/48

摘要： Disclosed herein is a derivative of 1,5-diphenyl-1H-1,2,4-triazole-3-carboxamide represented by the following formula (I): ##STR1## wherein R represents an alkyl group of 2 to 10 carbon atoms, which is substituted by fluorine atom(s), and X represents a hydrogen atom or a fluorine atom, a process for producing the derivative and herbicidal compositions containing the derivative of 1,5-diphenyl-1H-1,2,4-triazole-3-carboxamide as an active ingredient.

公开(公告)号：US5130475A

公开(公告)日：1992-07-14

申请号：US798007

申请日：1991-11-26

申请人： Takafumi Shida ,  Hideo Arabori ,  Takeo Watanabe ,  Shiro Yamazaki ,  Hiroyasu Shinkawa

发明人： Takafumi Shida ,  Hideo Arabori ,  Takeo Watanabe ,  Shiro Yamazaki ,  Hiroyasu Shinkawa

IPC分类号： A01N43/653 ,  C07C65/21 ,  C07C67/14 ,  C07C69/734 ,  C07C235/42 ,  C07D249/10 ,  C07D263/42 ,  C07D263/48

CPC分类号： C07C65/21 ,  A01N43/653 ,  C07D249/10 ,  C07D263/48

摘要： Disclosed herein is a derivative of 1,5-diphenyl-1H-1,2,4-triazole-3-carboxamide represented by the following formula (I): ##STR1## wherein R represents an alkyl group of 2 to 10 carbon atoms, which is substituted by fluorine atom(s), and X represents a hydrogen atom or a fluorine atom, a process for producing the derivative and a herbicidal compositions containing the derivative of 1,5-diphenyl-1H-1,2,4-triazole-3-carboxamide as an active ingredient.

公开(公告)号：US5162583A

公开(公告)日：1992-11-10

申请号：US588996

申请日：1990-09-27

申请人： Takafumi Shida ,  Hideo Arabori ,  Takeo Watanabe ,  Yoshikazu Kubota ,  Isao Ichinose ,  Yoichi Kanda ,  Shiro Yamazaki ,  Hiroyasu Shinkawa

发明人： Takafumi Shida ,  Hideo Arabori ,  Takeo Watanabe ,  Yoshikazu Kubota ,  Isao Ichinose ,  Yoichi Kanda ,  Shiro Yamazaki ,  Hiroyasu Shinkawa

IPC分类号： A01N43/653 ,  C07C201/12 ,  C07C205/33 ,  C07C205/34 ,  C07C205/35 ,  C07C217/76 ,  C07D249/10

CPC分类号： A01N43/653 ,  C07C205/33 ,  C07C205/34 ,  C07C205/35 ,  C07C217/76 ,  C07D249/10

摘要： Disclosed herein are the derivative of benzyl ether represented by the formula (I) ##STR1## which is useful as an intermediate compound of the derivatives of 1,5-diphenyl-1H-1,2,4- triazole-3-carboxamide represented by the formula (II), ##STR2## wherein R is a straight-chain alkyl group having 1 to 10 carbon atoms which is non-substituted or substituted with 1 to 19 fluorine atoms, a branched alkyl group having 3 to 10 carbon atoms which is non-substituted or substituted with 1 to 19 fluorine atoms, a cyclic alkyl group having 3 to 10 carbon atoms, an alkyl group having 1 to 3 carbon atoms which is substituted with an alicyclic structure having 3 to 7 carbon atoms, a phenyl group or an aralkyl group having 7 to 9 carbon atoms; X.sup.1 is a halogen or an alkyl group having 1 to 3 carbon atoms; X.sup.2 is a hydrogen, a halogen or an alkyl group having 1 to 3 carbon atoms; Y.sup.1 is a hydrogen or a fluorine; Y.sup.2 is a hydrogen or a fluorine; and Z is a nitro group or an amino group.

摘要翻译： 本文公开了由式（I）表示的苄基醚衍生物，其可用作1,5-二苯基-1H-1,2,4-三唑-3-基的衍生物的中间体化合物， 由式（II）表示的羧酰胺，其中R是未取代或被1〜19个氟原子取代的碳原子数为1〜10的直链烷基，具有3个 未取代或被1〜19个氟原子取代的10个碳原子，碳原子数3〜10的环状烷基，碳原子数1〜3的被碳数3〜7的脂环结构取代的烷基 原子，苯基或碳原子数为7〜9的芳烷基; X1是卤素或具有1至3个碳原子的烷基; X 2是氢，卤素或具有1至3个碳原子的烷基; Y1是氢或氟; Y2是氢或氟; Z为硝基或氨基。

公开(公告)号：US4968345A

公开(公告)日：1990-11-06

申请号：US162934

申请日：1988-03-02

申请人： Takafumi Shida ,  Hideo Arabori ,  Takeo Watanabe ,  Yoichi Kanda ,  Shiro Yamazaki ,  Hiroyasu Shinkawa

发明人： Takafumi Shida ,  Hideo Arabori ,  Takeo Watanabe ,  Yoichi Kanda ,  Shiro Yamazaki ,  Hiroyasu Shinkawa

IPC分类号： A01N37/52 ,  C07C67/00 ,  C07C239/00 ,  C07C257/20 ,  C07C257/22

CPC分类号： A01N37/52

摘要： Disclosed herein is a phenylhydrazone derivative of oxamide represented by the formula (I): ##STR1## wherein R.sup.1 is straight-chain alkyl group having 2 to 10 carbon atoms, branched alkyl group or cyclic alkyl group having 3 to 10 carbon atoms, alkyl group having 1 to 3 carbon atoms which is substituted with an alicyclic structure having 3 to 7 carbon atoms, phenyl group, halogen-substituted phenyl group, aralkyl group having 7 to 9 carbon atoms, alkenyl group having 3 to 6 carbon atoms, alkyl group having 2 to 4 carbon atoms which is substituted with alkoxy group having 1 to 4 carbon atoms, or alkyl group having 2 to 10 carbon atoms which is substituted with 1 to 19 fluorine atoms; and R.sup.2 is hydrogen, fluorine, chlorine, methyl group or methoxy group, and a herbicidal composition containing the derivative as active ingredient. The phenylhydrazone derivative of oxamide represented by the formula (I) of the present invention shows a high herbicidal activity and also have an excellent selectivity allowing killing of weeds alone without doing any practical harm to the crops such as rice, wheat and corn.