公开(公告)号：US5162583A

公开(公告)日：1992-11-10

申请号：US588996

申请日：1990-09-27

申请人： Takafumi Shida ,  Hideo Arabori ,  Takeo Watanabe ,  Yoshikazu Kubota ,  Isao Ichinose ,  Yoichi Kanda ,  Shiro Yamazaki ,  Hiroyasu Shinkawa

发明人： Takafumi Shida ,  Hideo Arabori ,  Takeo Watanabe ,  Yoshikazu Kubota ,  Isao Ichinose ,  Yoichi Kanda ,  Shiro Yamazaki ,  Hiroyasu Shinkawa

IPC分类号： A01N43/653 ,  C07C201/12 ,  C07C205/33 ,  C07C205/34 ,  C07C205/35 ,  C07C217/76 ,  C07D249/10

CPC分类号： A01N43/653 ,  C07C205/33 ,  C07C205/34 ,  C07C205/35 ,  C07C217/76 ,  C07D249/10

摘要： Disclosed herein are the derivative of benzyl ether represented by the formula (I) ##STR1## which is useful as an intermediate compound of the derivatives of 1,5-diphenyl-1H-1,2,4- triazole-3-carboxamide represented by the formula (II), ##STR2## wherein R is a straight-chain alkyl group having 1 to 10 carbon atoms which is non-substituted or substituted with 1 to 19 fluorine atoms, a branched alkyl group having 3 to 10 carbon atoms which is non-substituted or substituted with 1 to 19 fluorine atoms, a cyclic alkyl group having 3 to 10 carbon atoms, an alkyl group having 1 to 3 carbon atoms which is substituted with an alicyclic structure having 3 to 7 carbon atoms, a phenyl group or an aralkyl group having 7 to 9 carbon atoms; X.sup.1 is a halogen or an alkyl group having 1 to 3 carbon atoms; X.sup.2 is a hydrogen, a halogen or an alkyl group having 1 to 3 carbon atoms; Y.sup.1 is a hydrogen or a fluorine; Y.sup.2 is a hydrogen or a fluorine; and Z is a nitro group or an amino group.

摘要翻译： 本文公开了由式（I）表示的苄基醚衍生物，其可用作1,5-二苯基-1H-1,2,4-三唑-3-基的衍生物的中间体化合物， 由式（II）表示的羧酰胺，其中R是未取代或被1〜19个氟原子取代的碳原子数为1〜10的直链烷基，具有3个 未取代或被1〜19个氟原子取代的10个碳原子，碳原子数3〜10的环状烷基，碳原子数1〜3的被碳数3〜7的脂环结构取代的烷基 原子，苯基或碳原子数为7〜9的芳烷基; X1是卤素或具有1至3个碳原子的烷基; X 2是氢，卤素或具有1至3个碳原子的烷基; Y1是氢或氟; Y2是氢或氟; Z为硝基或氨基。

公开(公告)号：US4983209A

公开(公告)日：1991-01-08

申请号：US169465

申请日：1988-03-17

申请人： Takafumi Shida ,  Yoshikazu Kubota ,  Isao Ichinose ,  Takeo Watanabe ,  Shiro Yamazaki ,  Hiroyasu Shinkawa

发明人： Takafumi Shida ,  Yoshikazu Kubota ,  Isao Ichinose ,  Takeo Watanabe ,  Shiro Yamazaki ,  Hiroyasu Shinkawa

IPC分类号： A01N43/50 ,  A01N43/653 ,  C07D249/08 ,  C07D249/10

CPC分类号： A01N43/653 ,  C07D249/10

摘要： Disclosed herein is a 4,5-dihydro-1H-1,2,4-triazole-3-carboxamide derivative represented by the formula (I): ##STR1## wherein R represents a straight-chain alkyl group having 1 to 10 carbon atoms which is non-substituted or substituted with 1 to 19 fluorine atoms or a branched alkyl group having 3 to 10 carbon atoms which is non-substituted or substituted with 1 to 19 fluorine atoms; X.sup.1 represents a halogen atom or an alkyl group having 1 to 3 carbon atoms; X.sup.2 represents hydrogen atom, a halogen atom or an alkyl group having 1 to 3 carbon atoms; Y.sup.1 represents hydrogen atom or fluorine atom; and Y.sup.2 represents hydrogen atom or fluorine atom. The derivatives of the formula (I) have high herbicidal activities and also show a excellent selectivity in their actions for killing weeds alone while doing any practical harm to the crops such as rice, wheat and corn.

公开(公告)号：US4968345A

公开(公告)日：1990-11-06

申请号：US162934

申请日：1988-03-02

申请人： Takafumi Shida ,  Hideo Arabori ,  Takeo Watanabe ,  Yoichi Kanda ,  Shiro Yamazaki ,  Hiroyasu Shinkawa

发明人： Takafumi Shida ,  Hideo Arabori ,  Takeo Watanabe ,  Yoichi Kanda ,  Shiro Yamazaki ,  Hiroyasu Shinkawa

IPC分类号： A01N37/52 ,  C07C67/00 ,  C07C239/00 ,  C07C257/20 ,  C07C257/22

CPC分类号： A01N37/52

摘要： Disclosed herein is a phenylhydrazone derivative of oxamide represented by the formula (I): ##STR1## wherein R.sup.1 is straight-chain alkyl group having 2 to 10 carbon atoms, branched alkyl group or cyclic alkyl group having 3 to 10 carbon atoms, alkyl group having 1 to 3 carbon atoms which is substituted with an alicyclic structure having 3 to 7 carbon atoms, phenyl group, halogen-substituted phenyl group, aralkyl group having 7 to 9 carbon atoms, alkenyl group having 3 to 6 carbon atoms, alkyl group having 2 to 4 carbon atoms which is substituted with alkoxy group having 1 to 4 carbon atoms, or alkyl group having 2 to 10 carbon atoms which is substituted with 1 to 19 fluorine atoms; and R.sup.2 is hydrogen, fluorine, chlorine, methyl group or methoxy group, and a herbicidal composition containing the derivative as active ingredient. The phenylhydrazone derivative of oxamide represented by the formula (I) of the present invention shows a high herbicidal activity and also have an excellent selectivity allowing killing of weeds alone without doing any practical harm to the crops such as rice, wheat and corn.

公开(公告)号：US4919707A

公开(公告)日：1990-04-24

申请号：US42321

申请日：1987-04-24

申请人： Takafumi Shida ,  Hideo Arabori ,  Takeo Watanabe ,  Yohichi Kanda ,  Shiro Yamazaki ,  Hiroyasu Shinkawa

发明人： Takafumi Shida ,  Hideo Arabori ,  Takeo Watanabe ,  Yohichi Kanda ,  Shiro Yamazaki ,  Hiroyasu Shinkawa

IPC分类号： A01N43/653 ,  C07D249/10

CPC分类号： C07D249/10 ,  A01N43/653

摘要： Disclosed herein are a derivative of 1,5-diphenyl-1H-1,2,4-triazole-3-carboxamide represented by the formula (I): ##STR1## wherein R.sup.1 represents a straight-chain alkyl group of 2 to 10 carbon atoms; a branched-chain alkyl group or cycloalkyl group of 3 to 10 carbon atoms; a (cycloalkyl)alkyl group of 4 to 10 carbon atoms; a non-substituted- or halogen-substituted phenyl group; an aralkyl group of 7 to 9 carbon atoms; an alkenyl group of 3 to 6 carbon atoms or an alkyl group of 2 to 10 carbon atoms, which has been substituted by 1 to 19 fluorine atoms, and R.sup.2 represents a fluorine atom, a chlorine atom, a methyl group or a methoxy group and a herbicidal composition containing the derivative represented by the formula (I) as an active ingredient.

公开(公告)号：US4561877A

公开(公告)日：1985-12-31

申请号：US596927

申请日：1984-04-05

申请人： Katsumichi Aoki ,  Takafumi Shida ,  Hideo Arabori ,  Satoru Kumazawa ,  Susumu Shimizu ,  Takeo Watanabe ,  Yohichi Kanda ,  Keigo Satake ,  Shiro Yamazaki ,  Hiroyasu Shinkawa ,  Tsuneaki Chida

发明人： Katsumichi Aoki ,  Takafumi Shida ,  Hideo Arabori ,  Satoru Kumazawa ,  Susumu Shimizu ,  Takeo Watanabe ,  Yohichi Kanda ,  Keigo Satake ,  Shiro Yamazaki ,  Hiroyasu Shinkawa ,  Tsuneaki Chida

IPC分类号： A01N43/78 ,  A01N43/88 ,  C07D417/04 ,  A01N43/54 ,  A01N43/66

CPC分类号： C07D417/04 ,  A01N43/78 ,  A01N43/88

摘要： Disclosed herein are a derivative of tetrahydrobenzothiazole represented by the formula (I): ##STR1## wherein R represents a hydrogen atom, a hydroxyl group or a lower acyloxy group such as acetoxy group and propionyloxy group and X represents a methylene group, C.sub.1 to C.sub.4 -alkylamino group, benzylamino group or --O--, and a herbicidal composition containing the same as an active ingredient.

摘要翻译： 本文公开的是由式（I）表示的四氢苯并噻唑的衍生物：其中R表示氢原子，羟基或低级酰氧基如乙酰氧基和丙酰氧基，X表示亚甲基， C1〜C4烷基氨基，苄基氨基或-O-，以及含有该活性成分的除草组合物。

公开(公告)号：US5094684A

公开(公告)日：1992-03-10

申请号：US554986

申请日：1990-07-17

申请人： Takafumi Shida ,  Hideo Arabori ,  Takeo Watanabe ,  Shiro Yamazaki ,  Hiroyasu Shinkawa

发明人： Takafumi Shida ,  Hideo Arabori ,  Takeo Watanabe ,  Shiro Yamazaki ,  Hiroyasu Shinkawa

IPC分类号： A01N43/653 ,  C07C65/21 ,  C07C67/14 ,  C07C69/734 ,  C07C235/42 ,  C07D249/10 ,  C07D263/42 ,  C07D263/48

CPC分类号： C07C65/21 ,  A01N43/653 ,  C07D249/10 ,  C07D263/48

摘要： Disclosed herein is a derivative of 1,5-diphenyl-1H-1,2,4-triazole-3-carboxamide represented by the following formula (I): ##STR1## wherein R represents an alkyl group of 2 to 10 carbon atoms, which is substituted by fluorine atom(s), and X represents a hydrogen atom or a fluorine atom, a process for producing the derivative and herbicidal compositions containing the derivative of 1,5-diphenyl-1H-1,2,4-triazole-3-carboxamide as an active ingredient.

公开(公告)号：US4820334A

公开(公告)日：1989-04-11

申请号：US918111

申请日：1986-10-14

申请人： Takafumi Shida ,  Shiro Yamazaki ,  Hiroyasu Shinkawa

发明人： Takafumi Shida ,  Shiro Yamazaki ,  Hiroyasu Shinkawa

IPC分类号： A01N43/653 ,  C07D249/10 ,  C07D263/48

CPC分类号： C07D263/48 ,  A01N43/653 ,  C07D249/10

摘要： A 1,2,4-triazole-3-carboxamide compound represented by the formula (I): ##STR1## wherein R represents a straight-chain or branched-chain saturated (C.sub.2 -C.sub.10)alkyl group which is unsubstituted or substituted by fluorine atom(s); a cyclic saturated (C.sub.3 -C.sub.10)alkyl group which is unsubstituted or substituted by fluorine atom(s); a straight-chain, branched-chain or cyclic unsaturated (C.sub.3 -C.sub.10)-alkyl group which is unsubstituted or substituted by fluorine atom(s); a group represented by the formula (II): ##STR2## wherein R.sup.1 represents a halogen atom, a (C.sub.1 -C.sub.3)alkyl group, a (C.sub.1 -C.sub.3)alkoxy group or a fluorine-substituted (C.sub.1 -C.sub.3)alkyl group, m is an integer of from 0 to 5 and n is 0 or 1; a straight-chain or branched-chain saturated (C.sub.1 -C.sub.8)alkoxy(C.sub.2 14 C.sub.10)alkyl group; a straight-chain or branched-chain unsaturated (C.sub.1 -C.sub.8)alkoxy(C.sub.2 -C.sub.10)alkyl group; a phenoxy(C.sub.2 -C.sub.6)alkyl group; an aralkoxy(C.sub.2 1-C.sub.6)alkyl group; a phenoxy(C.sub.2 -C.sub.6)alkyl group having phenyl group(s) substituted by halogen atom(s) or (C.sub.1 -C.sub.3)alkyl group(s); an aralkoxy(C.sub.2 -C.sub.6)alkyl group having phenyl group(s) substituted by halogen atom(s) or (C.sub.1 -C.sub.3)alkyl group(s); a [(C.sub.1 -C.sub.8)alkoxy(C.sub.2 -C.sub.10)alkoxy](C.sub.2 -C.sub.10)alkyl group; or a group represented by the formula (III): ##STR3## wherein p is an integer of from 1 to 8, a process for producing the same compound, and a herbicidal composition containing the 1,2,4-triazole-3-carboxamide compound as an active ingredient.

摘要翻译： 由式（I）表示的1,2,4-三唑-3-甲酰胺化合物：其中R表示未取代的直链或支链饱和（C 2 -C 10）烷基， 被氟原子取代; 未被取代或被氟原子取代的环状饱和（C 3 -C 10）烷基; 未被取代或被氟原子取代的直链，支链或环状不饱和（C 3 -C 10） - 烷基; 式（II）表示的基团：其中R1表示卤素原子，（C1-C3）烷基，（C1-C3）烷氧基或氟取代的（C1-C3） 烷基，m为0〜5的整数，n为0或1; 直链或支链饱和（C1-C8）烷氧基（C214 C10）烷基; 直链或支链不饱和（C1-C8）烷氧基（C2-C10）烷基; 苯氧基（C 2 -C 6）烷基; 芳烷氧基（C 21 -C 6）烷基; 具有被卤素原子或（C1-C3）烷基取代的苯基的苯氧基（C2-C6）烷基; 具有被卤素原子或（C1-C3）烷基取代的苯基的芳烷氧基（C2-C6）烷基; [（C 1 -C 8）烷氧基（C 2 -C 10）烷氧基]（C 2 -C 10）烷基; 或由式（III）表示的基团：其中p是1至8的整数，其中相同化合物的制备方法和含有1,2,4-三唑-2-酮的除草组合物， 3-甲酰胺化合物作为活性成分。

公开(公告)号：USRE33132E

公开(公告)日：1989-12-19

申请号：US940721

申请日：1986-12-09

申请人： Katsumichi Aoki ,  Yoichi Kanda ,  Keigo Satake ,  Hiroyasu Shinkawa

发明人： Katsumichi Aoki ,  Yoichi Kanda ,  Keigo Satake ,  Hiroyasu Shinkawa

IPC分类号： A01N43/653 ,  C07D249/10

CPC分类号： C07D249/10 ,  A01N43/653

摘要： A compound of 1,5-disubstituted .Iadd.-1H-.Iaddend.1,2,4-triazole-3-carboxamide represented by the general formula; ##STR1## wherein R.sup.1 is alkyl of one to three carbon atoms, chloro, fluoro, iodo, trifluoromethyl or nitro, R.sup.2 is hydrogen, methyl or chloro, R.sup.3 is hydrogen or methyl is provided in the invention, which shows an excellent herbicidal activity.

公开(公告)号：US4795484A

公开(公告)日：1989-01-03

申请号：US858531

申请日：1986-04-24

申请人： Katsumichi Aoki ,  Takafumi Shida ,  Takeo Watanabe ,  Keigo Satake ,  Hiroyasu Shinkawa ,  Shiro Yamazaki

发明人： Katsumichi Aoki ,  Takafumi Shida ,  Takeo Watanabe ,  Keigo Satake ,  Hiroyasu Shinkawa ,  Shiro Yamazaki

IPC分类号： A01N43/653 ,  C07D249/10

CPC分类号： A01N43/653 ,  C07D249/10

摘要： Disclosed herein is herbicidal composition comprising a derivative of 1,2,4-triazole as an active ingredient, represented by the general formula (I): ##STR1## wherein R.sup.1 represents a hydrogen atom, a halogen atom or a C.sub.1 -C.sub.2) alkyl group; R.sup.2 represents a hydrogen atom, a halogen atom, a (C.sub.1 -C.sub.2) alkyl group fluoromethyl group (--CH.sub.2 F),3,3,3-trifluoropopyl group, methoxy group, cyano group, methoxymethyl group, methylthio group, methoxycarbonyl group or isopropoxycarbonyl group and R.sup.3 represents a thiocarbamoyl group or a group represented by the general formula (II): ##STR2## wherein R.sup.4 represents a hydrogen atom, a (C.sub.1 -C.sub.2) alkyl group or a hydroxy (C.sub.1 -C.sub.2) alkyl group and R.sup.5 represents a hydrogen atom, a C.sub.1 -C.sub.2) alkyl group, halogeno (C.sub.1 -C.sub.2) alkyl group, hydroxy (C.sub.1 -C.sub.2) alkyl group, cyanomethyl group, acetyl group, halogenoacetyl group, methoxyacetyl group, amino group, phenyl group, methoxy group, hydroxyl group, (C.sub.2 -C.sub.3) alkenyl group, halogeno (C.sub.2 -C.sub.3) alkenyl group, isopropylcarbonyl group, methylthiocarbamoyl group or 2-methoxyethyl group, the proviso that R.sup.2 is not a hydrogen atom, halogen atom or (C.sub.1 -C.sub.2) alkyl group when both of R.sup.4 and R.sup.5 represent hydrogen atoms, and herbicidally acceptable carrier(s) or diluent(s).

摘要翻译： 本文公开了包含由通式（I）表示的1,2,4-三唑衍生物作为活性成分的除草组合物：其中R1表示氢原子，卤素原子或C1- C2）烷基; R2表示氢原子，卤素原子，（C1-C2）烷基氟甲基（-CH2F），3,3,3-三氟戊酰基，甲氧基，氰基，甲氧基甲基，甲硫基，甲氧基羰基或异丙氧基羰基 基团，R 3表示硫代氨基甲酰基或由通式（II）表示的基团：其中R 4表示氢原子，（C 1 -C 2）烷基或羟基（C 1 -C 2）烷基） R5为氢原子，C1-C2）烷基，卤代（C1-C2）烷基，羟基（C1-C2）烷基，氰基甲基，乙酰基，卤代乙酰基，甲氧基乙酰基，氨基，苯基 ，甲氧基，羟基，（C2-C3）烯基，卤代（C2-C3）烯基，异丙基羰基，甲硫基氨基甲酰基或2-甲氧基乙基，条件是R2不是氢原子，卤素原子或（C1 -C 2）烷基，当R4和R5都表示氢原子，除草可接受的载体或稀释剂（ s）。

公开(公告)号：US4650515A

公开(公告)日：1987-03-17

申请号：US673590

申请日：1984-11-21

申请人： Katsumichi Aoki ,  Takafumi Shida ,  Yoichi Kanda ,  Keigo Satake ,  Hiroyasu Shinkawa ,  Shiro Yamazaki

发明人： Katsumichi Aoki ,  Takafumi Shida ,  Yoichi Kanda ,  Keigo Satake ,  Hiroyasu Shinkawa ,  Shiro Yamazaki

IPC分类号： A01N43/78 ,  A01N47/06 ,  C07D277/82 ,  C07D417/04 ,  C07D417/14

CPC分类号： C07D417/04 ,  A01N43/78 ,  A01N47/06 ,  C07D277/82 ,  C07D417/14

摘要： Disclosed herein are the derivatives of tetrahydrobenzothiazole represented by the general formula (I): ##STR1## wherein R.sup.1 represents a hydrogen atom, a straight-chain alkyl group having 1 to 6 carbon atoms or branched-chain alkyl group having 1 to 6 carbon atoms, a cycloalkyl group having 3 to 6 carbon atoms or a phenyl group and R.sup.2 represents a chemical group selected from the group consisting of: ##STR2## wherein R.sup.3 represents a hydrogen atom, a methyl group or an acetyl group and R.sup.4 represents a hydrogen atom, a hydroxyl group, methoxy group or acetoxy group and herbicidal compositions containing at least one of the derivatives of tetrahydrobenzothiazole as an active ingredient.

摘要翻译： 本文公开了由通式（I）表示的四氢苯并噻唑的衍生物：其中R 1表示氢原子，具有1至6个碳原子的直链烷基或支链烷基，其具有1至 6个碳原子，具有3至6个碳原子的环烷基或苯基，R 2表示选自以下的化学基团：其中R 3表示氢原子，甲基或 乙酰基，R4表示氢原子，羟基，甲氧基或乙酰氧基，以及含有至少一种四氢苯并噻唑衍生物作为有效成分的除草组合物。