公开(公告)号：US5380843A

公开(公告)日：1995-01-10

申请号：US63594

申请日：1993-05-19

Applicant: Yoichi Kanda ,  Hideo Arabori

Inventor： Yoichi Kanda ,  Hideo Arabori

IPC: C07D251/14 ,  C07D251/16 ,  C07D251/18 ,  C07D251/22 ,  C07D251/44 ,  C07D251/46 ,  C07D251/50 ,  C07D251/52 ,  C07D251/54 ,  C07D251/70 ,  C07D251/40 ,  C07D251/48

CPC classification number: C07D251/46

Abstract: Phenyl (1,3,5-triazin-2-yl)carbamates of the formula (I): ##STR1## wherein R.sup.1 is H, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy, R.sup.2 and R.sup.3 are independently H, halogen atom, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 haloalkylthio, C.sub.2 -C.sub.4 alkoxyalkyl or NR.sup.7 R.sup.8 (R.sup.7, R.sup.8 : H or C.sub.1 -C.sub.4 alkyl, independently), and R.sup.4, R.sup.5 and R.sup.6 are independently H, halogen atom, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy, are prepared by reacting a 2-amino-1,3,5-triazine of the formula (II): ##STR2## with a diphenyl carbonate of the formula (III): ##STR3## in the presence of an alkali metal hydride in an acrotic polar solvent. An parotic polar solvent mixture of the phenyl (1,3,5-triazin-2-yl)carbamate of the formula (I) and an alkali metal phenoxide is also disclosed.

Abstract translation: 式（I）的苯基（1,3,5-三嗪-2-基）氨基甲酸酯：其中R 1是H，C 1 -C 4烷基或C 1 -C 4烷氧基，R 2和R 3独立地是H， 卤素原子，C1-C4烷基，C1-C4烷氧基，C1-C4烷硫基，C1-C4卤代烷基，C1-C4卤代烷氧基，C1-C4卤代烷硫基，C2-C4烷氧基烷基或NR7R8（R7，R8：H或C1-C4烷基， 独立地），R4，R5和R6独立地是H，卤素原子，C1-C4烷基或C1-C4烷氧基，通过使式（II）的2-氨基-1,3,5-三嗪： （II）与式（III）的碳酸二苯酯：在碱性金属氢化物存在下，在丙烯酸极性溶剂中反应。 还公开了式（I）的苯基（1,3,5-三嗪-2-基）氨基甲酸酯和碱金属酚盐的极性溶剂混合物。

公开(公告)号：US5094684A

公开(公告)日：1992-03-10

申请号：US554986

申请日：1990-07-17

Applicant: Takafumi Shida ,  Hideo Arabori ,  Takeo Watanabe ,  Shiro Yamazaki ,  Hiroyasu Shinkawa

Inventor： Takafumi Shida ,  Hideo Arabori ,  Takeo Watanabe ,  Shiro Yamazaki ,  Hiroyasu Shinkawa

IPC: A01N43/653 ,  C07C65/21 ,  C07C67/14 ,  C07C69/734 ,  C07C235/42 ,  C07D249/10 ,  C07D263/42 ,  C07D263/48

CPC classification number: C07C65/21 ,  A01N43/653 ,  C07D249/10 ,  C07D263/48

Abstract: Disclosed herein is a derivative of 1,5-diphenyl-1H-1,2,4-triazole-3-carboxamide represented by the following formula (I): ##STR1## wherein R represents an alkyl group of 2 to 10 carbon atoms, which is substituted by fluorine atom(s), and X represents a hydrogen atom or a fluorine atom, a process for producing the derivative and herbicidal compositions containing the derivative of 1,5-diphenyl-1H-1,2,4-triazole-3-carboxamide as an active ingredient.

公开(公告)号：US5362885A

公开(公告)日：1994-11-08

申请号：US081945

申请日：1993-06-25

Applicant: Hideo Arabori ,  Shiro Yamazaki ,  Masato Arahira ,  Aiko Murakami

Inventor： Hideo Arabori ,  Shiro Yamazaki ,  Masato Arahira ,  Aiko Murakami

IPC: C07D403/12 ,  A01N47/36 ,  C07D207/32 ,  C07D207/333 ,  C07D207/337 ,  C07D207/44 ,  C07D207/452 ,  C07D231/12 ,  C07D521/00 ,  C07D207/325

CPC classification number: C07D207/333 ,  A01N47/36 ,  C07D207/337 ,  C07D207/452 ,  C07D231/12 ,  C07D233/56 ,  C07D249/08 ,  C07D521/00

Abstract: Disclosed herein are N-substituted-3-(nitrogen-containing 5-membered ring)benzenesulfonamide derivatives of the formula (I): ##STR1## R.sup.1 is H, Cl, C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.4 alkoxycarbonyl; Z is CH or N; X.sup.1 is C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxyl or Cl; and X.sup.2 is C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkoxyl, a process for the preparation thereof, and herbicidal compositions containing the N-substituted-3-(nitrogen-containing 5-membered ring)benzenesulfonamide derivatives as active ingredients.

Abstract translation: 本文公开了式（I）的N-取代-3-（含氮五元环）苯磺酰胺衍生物：其中， Z是CH或N; X1是C1-C3烷基，C1-C3烷氧基或C1; X2是C1-C3烷基或C1-C3烷氧基，其制备方法和含有N-取代-3-（含氮五元环）苯磺酰胺衍生物作为活性成分的除草组合物。

公开(公告)号：US4624697A

公开(公告)日：1986-11-25

申请号：US597451

申请日：1984-04-06

Applicant: Katsumichi Aoki ,  Takafumi Shida ,  Hideo Arabori ,  Satoru Kumazawa ,  Susumu Shimizu ,  Takeo Watanabe ,  Yohichi Kanda ,  Keigo Satake ,  Shiro Yamazaki ,  Hiroyasu Shinkawa ,  Tsuneaki Chida

Inventor： Katsumichi Aoki ,  Takafumi Shida ,  Hideo Arabori ,  Satoru Kumazawa ,  Susumu Shimizu ,  Takeo Watanabe ,  Yohichi Kanda ,  Keigo Satake ,  Shiro Yamazaki ,  Hiroyasu Shinkawa ,  Tsuneaki Chida

IPC: A01N43/78 ,  A01N43/82 ,  C07D233/00 ,  C07D271/00 ,  C07D277/00 ,  C07D417/04

CPC classification number: C07D417/04 ,  A01N43/78 ,  A01N43/82

Abstract: Disclosed herein are a derivative of tetrahydrobenzothiazole represented by the formula (I): ##STR1## wherein R represents a methyl group, ethyl group or propyl group; R.sup.1 represents a hydrogen atom, a hydroxyl group methoxy group, acetoxy group, propionyloxy group, butylyloxy group, chloroacetoxy group, methoxyacetoxy group, C.sub.1 to C.sub.4 -alkylamino group or di(C.sub.1 to C.sub.4)-alkylamino group, or represents O.dbd.together with R.sup.2 ; R.sup.2 represents a hydrogen atom or represents O.dbd.together with R.sup.1 ; and X represents a methylene group, hydroxymethylene group, carbonyl group or --O--, and a herbicidal composition containing the same as an active ingredient.

Abstract translation: 本文公开了由式（I）表示的四氢苯并噻唑的衍生物：其中R表示甲基，乙基或丙基; R1表示氢原子，羟基甲氧基，乙酰氧基，丙酰氧基，丁酰氧基，氯乙酰氧基，甲氧基乙酰氧基，C1〜C4烷基氨基或二（C1〜C4） - 烷基氨基，或表示O = R2; R2代表氢原子或代表O =与R1一起; X表示亚甲基，羟基亚甲基，羰基或-O-，以及含有该活性成分的除草组合物。

公开(公告)号：US4549902A

公开(公告)日：1985-10-29

申请号：US597269

申请日：1984-04-06

Applicant: Katsumichi Aoki ,  Takafumi Shida ,  Hideo Arabori ,  Satoru Kumazawa ,  Susumu Shimizu ,  Takeo Watanabe ,  Yohichi Kanda ,  Keigo Satake ,  Shiro Yamazaki ,  Hiroyasu Shinkawa ,  Tsuneaki Chida

Inventor： Katsumichi Aoki ,  Takafumi Shida ,  Hideo Arabori ,  Satoru Kumazawa ,  Susumu Shimizu ,  Takeo Watanabe ,  Yohichi Kanda ,  Keigo Satake ,  Shiro Yamazaki ,  Hiroyasu Shinkawa ,  Tsuneaki Chida

IPC: A01N47/36 ,  C07D277/82

CPC classification number: A01N47/36 ,  C07D277/82

Abstract: Disclosed herein are a salt of a derivative of N-(tetrahydrobenzothiazolylcarbamoyl)oxamic acid, represented by the formula: ##STR1## wherein R.sup.1 represents a straight-chain alkyl group having one to six carbon atoms, branched-chain alkyl group having up to and including six carbon atoms, cyclic alkyl group having up to and including six carbon atoms or a phenyl group; R.sup.2 represents a hydrogen atom or a methyl group; M represents an alkali metal atom or an alkaline earth metal atom; n is 1 when M is an alkali metal atom and n is 1/2 when M is an alkaline earth metal atom and M' is a hydrogen atom or the same as M, and a herbicidal composition containing the same as an active ingredient.

Abstract translation: 本文公开了由下式表示的N-（四氢苯并噻唑基氨基甲酰基）氧杂恶唑酸的衍生物的盐：其中R 1表示具有1至6个碳原子的直链烷基，支链烷基具有 直到并包括6个碳原子，具有至多且包括6个碳原子的环状烷基或苯基; R2表示氢原子或甲基; M表示碱金属原子或碱土金属原子; 当M为碱金属原子时，n为1，当M为碱土金属原子且M为氢原子或与M相同时，n为1/2，和含有该活性成分的除草组合物。

公开(公告)号：US4398944A

公开(公告)日：1983-08-16

申请号：US273313

申请日：1981-06-15

Applicant: Katsumichi Aoki ,  Hideo Arabori ,  Keigo Satake ,  Hiroyasu Shinkawa

Inventor： Katsumichi Aoki ,  Hideo Arabori ,  Keigo Satake ,  Hiroyasu Shinkawa

IPC: A01N37/18 ,  C07C67/00 ,  C07C231/00 ,  C07C231/12 ,  C07C233/18

CPC classification number: A01N37/18

Abstract: A herbicidal composition comprising a herbicidally effective amount of a compound of the formula ##STR1## wherein R is methoxy, ethoxy, propoxy, isopropoxy or allyloxy and an agriculturally acceptable carrier and a method for inhibiting growth of weeds comprising applying the herbicidal composition to soil medium to inhibit the growth of weeds is disclosed.

Abstract translation: 一种除草组合物，其包含除草有效量的下式化合物，其中R是甲氧基，乙氧基，丙氧基，异丙氧基或烯丙氧基和农业上可接受的载体，以及抑制杂草生长的方法，包括将除草组合物施用于土壤培养基 以抑制杂草的生长。

公开(公告)号：US5683964A

公开(公告)日：1997-11-04

申请号：US504862

申请日：1995-07-20

Applicant: Yoichi Kanda ,  Hideo Arabori ,  Masato Arahira ,  Tsutomu Sato

Inventor： Yoichi Kanda ,  Hideo Arabori ,  Masato Arahira ,  Tsutomu Sato

IPC: C07D491/18 ,  A01N47/36 ,  C07D403/12 ,  C07D521/00 ,  A01N43/54 ,  A01N43/66 ,  A01N43/68 ,  C07D251/42

CPC classification number: C07D521/00 ,  A01N47/36

Abstract: An N-(substituted amino)imide derivative represented by the formula (I) is a novel compound which can be utilized as an effective ingredient of herbicidal compositions. ##STR1## wherein, R.sup.1 is hydrogen atom, C.sub.1 -C.sub.4 alkyl group, C.sub.7 -C.sub.9 aralkyl group, C.sub.1 -C.sub.4 haloalkyl group, (C.sub.1 -C.sub.4 alkyl)carbonyl group or (C.sub.1 -C.sub.4 alkyl)sulfonyl group; A represents a structure selected from the group consisting of the following formulas (A-1), (A-2), (A-3), (A-4) and (A-5) ##STR2## wherein R.sup.2 and R.sup.3 in the formula (A-1) are independently hydrogen atom or C.sub.1 -C.sub.4 alkyl group, but not R.sup.2 =R.sup.3 =H, R.sup.4 in the formula (A-4) is halogen atom, C.sub.1 -C.sub.4 alkyl group and/or nitro group, m is an integer of 0-4, the substituents of m not less than 2 being same or different; X.sup.1 and X.sup.2 are independently hydrogen atom, halogen atom, C.sub.1 -C.sub.4 alkyl group, C.sub.1 -C.sub.4 alkoxy group, C.sub.1 -C.sub.4 alkylthio group, C.sub.1 -C.sub.4 haloalkyl group, C.sub.1 -C.sub.4 haloalkoxy group, C.sub.1 -C.sub.4 haloalkylthio group, C.sub.2 -C.sub.4 alkoxyalkyl group, C.sub.2 -C.sub.4 thioalkoxyalkyl group or NR.sup.7 R.sup.8, wherein R.sup.7 and R.sup.8 are independently hydrogen atom, C.sub.1 -C.sub.4 alkyl group or C.sub.1 -C.sub.4 alkoxy group; and Z is nitrogen atom or CH.

Abstract translation: 由式（I）表示的N-（取代氨基）酰亚胺衍生物是可用作除草组合物的有效成分的新型化合物。 （Ⅰ）其中R1是氢原子，C1-C4烷基，C7-C9芳烷基，C1-C4卤代烷基，（C1-C4烷基）羰基或（C1-C4烷基）磺酰基; （A-1），（A-2），（A-3），（A-4）和（A-5）（A-1） （A-2）（A-3）（A-4）（A-4）（A-5）其中式（A-1）中的R 2和R 3独立地为氢原子或C 1 -C4烷基，但不是R2 = R3 = H，式（A-4）中的R4是卤素原子，C1-C4烷基和/或硝基，m是0-4的整数，m的取代基 不少于2个相同或不同; X1和X2独立地为氢原子，卤素原子，C1-C4烷基，C1-C4烷氧基，C1-C4烷硫基，C1-C4卤代烷基，C1-C4卤代烷氧基，C1-C4卤代烷硫基，C2-C4 烷氧基烷基，C 2 -C 4硫代烷氧基烷基或NR 7 R 8，其中R 7和R 8独立地为氢原子，C 1 -C 4烷基或C 1 -C 4烷氧基; Z是氮原子或CH。

公开(公告)号：US5604178A

公开(公告)日：1997-02-18

申请号：US323413

申请日：1994-10-14

Applicant: Yoichi Kanda ,  Hideo Arabori ,  Masato Arahira ,  Tsutomu Sato

Inventor： Yoichi Kanda ,  Hideo Arabori ,  Masato Arahira ,  Tsutomu Sato

IPC: C07D403/12 ,  A01N43/50 ,  A01N43/64 ,  A01N47/36 ,  C07D207/50 ,  C07D403/04 ,  C07D521/00 ,  A01N43/66 ,  C07D251/42

CPC classification number: C07D521/00 ,  A01N47/36 ,  C07D207/50 ,  C07D403/04

Abstract: This invention is to provide an N-(substituted amino)pyrrole derivative represented by the formula (I): which is used as an effective ingredient of herbicidal compositions: ##STR1## wherein R.sup.2, R.sup.3, R.sup.4 and R.sup.5 is independently hydrogen atom, halogen atom, C.sub.1 -C.sub.4 alkyl group, (C.sub.1 -C.sub.4 alkyl)carbonyl group, (C.sub.3 -C.sub.6 cycloalkyl) carbonyl group, (C.sub.1 -C.sub.4 haloalkyl)carbonyl group, (C.sub.3 -C.sub.5 alkenyl)carbonyl group, benzoyl group which may be substituted with 1-3 halogen atoms and/or C.sub.1 -C.sub.4 alkyl groups, N,N-[(di-C.sub.1 -C.sub.4 alkyl)amino]carbonyl group, (C.sub.1 -C.sub.4 alkoxy)carbonyl group, etc., X.sup.1 and X.sup.2 are independently hydrogen atom, halogen atom, C.sub.1 -C.sub.4 alkyl group, C.sub.1 -C.sub.4 alkoxy group, etc., and Z is nitrogen atom or CH.

Abstract translation: 本发明提供由式（I）表示的N-（取代氨基）吡咯衍生物：其用作除草组合物的有效成分：其中R2，R3，R4和R5独立地为氢 原子，卤素原子，C1-C4烷基，（C1-C4烷基）羰基，（C3-C6环烷基）羰基，（C1-C4卤代烷基）羰基，（C3-C5烯基）羰基，苯甲酰基 可以被1-3个卤素原子和/或C 1 -C 4烷基，N，N - [（二-C 1 -C 4烷基）氨基]羰基，（C 1 -C 4烷氧基）羰基等取代，X 1和 X2独立地为氢原子，卤素原子，C1-C4烷基，C1-C4烷氧基等，Z为氮原子或CH。

公开(公告)号：US5129942A

公开(公告)日：1992-07-14

申请号：US667617

申请日：1991-03-08

Applicant: Hideo Arabori ,  Shiro Yamazaki ,  Masato Arahira ,  Aiko Murakami

Inventor： Hideo Arabori ,  Shiro Yamazaki ,  Masato Arahira ,  Aiko Murakami

IPC: A01N47/36 ,  C07D207/50 ,  C07D403/12 ,  C07D521/00

CPC classification number: C07D521/00 ,  A01N47/36 ,  C07D207/50 ,  C07D403/12

Abstract: Disclosed herein are N-substituted-3-[(2,3-dimethylmaleimido)amino]benzenesulfonamide derivatives of the formula (I): ##STR1## wherein R is Cl, C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.4 alkoxycarbonyl; Z is CH or N; X.sup.1 is Cl or C.sub.1 -C.sub.3 alkoxyl; and X.sup.2 is C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkoxyl, a process for the preparation thereof, and herbicidal compositions containing the N-substituted-3-[(2,3-dimethylmaleimido)amino]benzenesulfonamide derivatives as active ingredients.

公开(公告)号：US4973353A

公开(公告)日：1990-11-27

申请号：US162699

申请日：1988-03-01

Applicant: Takafumi Shida ,  Hideo Arabori ,  Takeo Watanabe ,  Yoshikazu Kubota ,  Isao Ichinose ,  Yoichi Kanda ,  Shiro Yamazaki ,  Hiroyasu Shinkawa

Inventor： Takafumi Shida ,  Hideo Arabori ,  Takeo Watanabe ,  Yoshikazu Kubota ,  Isao Ichinose ,  Yoichi Kanda ,  Shiro Yamazaki ,  Hiroyasu Shinkawa

IPC: A01N43/653 ,  C07C205/34 ,  C07C205/35 ,  C07C217/76 ,  C07D249/10

CPC classification number: C07C205/34 ,  A01N43/653 ,  C07C205/35 ,  C07C217/76 ,  C07D249/10

Abstract: Disclosed herein is a derivative of 1,5-diphenyl-1H-1,2,4-triazole-3-carboxamide represented by the formula (I): ##STR1## wherein R is a straight-chain alkyl group having 1 to 10 carbon atoms which is non-substituted or substituted with 1 to 19 fluorine atoms, a branched alkyl group having 3 to 10 carbon atoms which is non-substituted or substituted with 1 to 19 fluorine atoms, a cyclic alkyl group having 3 to 10 carbon atoms, an alkyl group having 1 to 3 carbon atoms which is substituted with an alicyclic structure having 3 to 7 carbon atoms, a phenyl group or an aralkyl group having 7 to 9 carbon atoms; X.sup.1 is a halogen or an alkyl group having 1 to 3 carbon atoms; X.sup.2 is a hydrogen, a halogen or an alkyl group having 1 to 3 carbon atoms; Y.sup.1 is a hydrogen or a fluorine; and Y.sup.2 is a hydrogen or a fluorine, and the herbicidal compositions containing said derivatives as active ingredient therefor.The derivative of 1,5-diphenyl-1H-1,2,4-triazole-3-carboxamide represented by the formula (I) of the present invention is the compound having high herbicidal activity and also showing excellent selectivity for killing weeds alone without doing any serious harm to the crops such as rice, wheat and corn.